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In-situ generated aluminum nitride-silicon carbide solid solution multiphase ceramic and preparation method thereof

A technology of in-situ generation and composite ceramics, which is applied in the field of aluminum nitride-silicon carbide solid solution composite ceramics, can solve the problem of difficult control of phase dispersion and uniformity in composite ceramics, change of material chemical composition and material properties Difficult regulation and other issues, to achieve excellent oxidation resistance and hydration resistance, uniform and compact structure, and improve oxidation resistance and hydration resistance

Inactive Publication Date: 2020-09-25
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The preparation of AlN / SiC solid solution composite ceramics by the above method usually uses a variety of raw materials to be mechanically mixed and then sintered at high temperature. It will cause its hydrolysis, thereby changing the chemical composition of the material, resulting in a reduction in the performance of the material
[0005] In addition, "An AlN-SiC solid solution whisker and its preparation method" (CN 201710875873.0) also uses a single ternary carbide Al 4 SiC 4 AlN / SiC solid solution whiskers are prepared as raw materials, but for bulk dense samples, the whiskers are only formed on the surface of the sample. Whether the inside of the sample completely reacts to form AlN / SiC solid solution, the patent technology does not specify

Method used

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Experimental program
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Effect test

preparation example Construction

[0020] The binder used in the preparation method provided by the present invention is not limited, as long as it can be uniformly mixed with the powder material and can be prepared into a block sample, it can be applicable. The present invention will be further described and illustrated below in conjunction with specific embodiments. It should be understood that the following specific examples are only used to illustrate the present invention rather than limit its protection scope.

[0021] In this specific implementation manner:

[0022] The Al 4 SiC 4 Powder purity ≥ 98.0wt%, particle size ≤ 150μm;

[0023] The purity of the nitrogen is ≥98.5%;

[0024] The binder is more than one of phenolic resin, epoxy resin, acrylic acid, silica sol and aluminum dihydrogen phosphate.

Embodiment 1

[0026] An in-situ formed aluminum nitride-silicon carbide solid solution composite ceramic and a preparation method thereof.

[0027] Step 1, according to Al 4 SiC 4 The mass ratio of powder: binder is 100:3, and the Al 4 SiC 4 The powder is mixed with the binder to obtain the mixture;

[0028] Step 2. Prepress the mixture under the condition of 5MPa, then isostatically press it under the condition of 200MPa, then place it in a constant temperature drying oven, and dry it at 110°C for 1 hour to obtain the prefabricated body;

[0029] Step 3: Put the prefabricated body into a graphite crucible, then place the graphite crucible in a hot-press furnace, heat it from room temperature to 1100°C at a rate of 10°C / min under vacuum ≤ 0.1mbar, and keep it warm Charge N under condition 2 To 2MPa, reheat to 1900°C at a rate of 5°C / min under pressure holding conditions, hold pressure for 2 hours, and cool naturally to room temperature to obtain in-situ aluminum nitride-silicon carbide...

Embodiment 2

[0032] An in-situ formed aluminum nitride-silicon carbide solid solution composite ceramic and a preparation method thereof.

[0033] Step 1, according to Al 4 SiC 4 The mass ratio of powder: binder is 100:2, and the Al 4 SiC 4 The powder is mixed with the binder to obtain the mixture;

[0034] Step 2: Prepress the mixture under the condition of 20MPa, then isostatically press it under the condition of 240MPa, then place it in a constant temperature drying oven, and dry it at 110°C for 3 hours to obtain the prefabricated body;

[0035] Step 3: Put the prefabricated body into a graphite crucible, then place the graphite crucible in a hot-press furnace, heat it from room temperature to 1200°C at a rate of 6°C / min under vacuum ≤ 0.1mbar, and keep it warm Charge N under condition 2To 8MPa, reheat to 2000°C at a rate of 2°C / min under pressure holding conditions, hold pressure for 3h, and cool naturally to room temperature to obtain in-situ formed aluminum nitride-silicon carbi...

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Abstract

The invention discloses in-situ generated aluminum nitride-silicon carbide solid solution multiphase ceramic and a preparation method thereof. The technical scheme is as follows: the preparation method comprises the following steps: mixing Al4SiC4 powder and a binder, pre-pressing and molding the mixture under the condition of 5-50 MPa, carring out isostatic pressing molding under the condition of100-300 MPa, and drying the molded product at 110 DEG C to obtain a prefabricated blank; putting the prefabricated blank into a graphite crucible, then putting the graphite crucible into a hot pressing furnace, heating the crucible from room temperature to 1100-1200 DEG C at a rate of 5-10 DEG C / min under the condition of less than or equal to 0.1 mbar; and filling the furnace with N2 to 2-10 MPaunder a heat preservation condition, heating the furnace to 1900-2200 DEG C at a rate of 1-5 DEG C / min under a pressure maintaining condition, maintaining the pressure and preserving the heat for 2-5hours, and naturally cooling the product to room temperature to obtain the in-situ generated aluminum nitride-silicon carbide solid solution composite ceramic. The preparation method is simple in process and convenient to operate, and the prepared in-situ generated aluminum nitride-silicon carbide solid solution composite ceramic is low in density, light in weight, uniform and compact in structure, resistant to high temperature, resistant to oxidation, resistant to hydration and high in strength.

Description

technical field [0001] The invention belongs to the technical field of aluminum nitride-silicon carbide solid solution composite ceramics. Specifically, it relates to an in-situ formed aluminum nitride-silicon carbide solid solution composite ceramic and a preparation method thereof. Background technique [0002] AlN materials have high thermal conductivity, good electrical insulation, high strength, high hardness, corrosion resistance, wear resistance and low thermal expansion coefficient. They are widely used in the fields of semiconductor materials, microwave electronic attenuation materials and refractory materials. SiC has a small thermal expansion coefficient, high hardness, high mechanical strength, chemical corrosion resistance, excellent wear resistance and stable chemical properties, and is widely used in many fields such as high-temperature ceramics and aerospace. Although aluminum nitride and silicon carbide are ceramic materials with excellent performance, they...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/565C04B35/581C04B35/622
CPCC04B35/565C04B35/581C04B35/622C04B2235/6562C04B2235/6567C04B2235/661C04B2235/77C04B2235/96
Inventor 余超郑永翔邓承继丁军祝洪喜吴欣欣
Owner WUHAN UNIV OF SCI & TECH