Lithium-ion battery pole piece and preparation method thereof
A lithium ion battery and pole piece technology, which is applied in the field of lithium ion battery pole pieces with gradient porosity and its preparation, can solve the problems of poor pore-making effect and difficult penetration of pore-forming agents, and achieves good ion conduction rate, The effect of increased energy density and good hole-making effect
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[0058] Example 1
[0059] See Figure 1-Figure 3 According to the present invention, a lithium ion battery pole piece with gradient porosity is prepared according to the following method:
[0060] (1) Mix NMC, conductive agent Super-P, polyvinylidene fluoride PVDF at a mass ratio of 9.4:0.3:0.3 to prepare a mixture, and then mix the mixture with N-methylpyrrolidone at a mass ratio of 2:1, Prepared into electrode slurry;
[0061] (2) Divide the above-mentioned electrode slurry into two parts, add uniform and fine ammonium carbonate powder as the pore-forming agent, adjust the stirring speed to fully mix and disperse. Among them, the pore-forming agent and the active material in the first slurry The mass ratio is 0.3:1, and the mass ratio of the pore former to the active material in the second slurry is 0.6:1.
[0062] (3) Apply the first electrode slurry to the aluminum foil side of the current collector. After drying, the pore former decomposes and escapes, and no other substances re...
Example Embodiment
[0064] Example 2
[0065] The present invention prepares a lithium ion battery pole piece with gradient porosity according to the following method:
[0066] (1) Mix LFP, conductive agent Super-P, polyvinylidene fluoride PVDF at a mass ratio of 9.6:0.2:0.2 to prepare a mixture, and then mix the mixture with N-methylpyrrolidone at a mass ratio of 2:1, Prepared into electrode slurry;
[0067] (2) Divide the electrode slurry into two parts, add uniform and fine ammonium bicarbonate powder as the pore former, adjust the stirring speed to fully mix and disperse, among which, the pore former and active material in the first slurry The mass ratio of pore former is 0.4:1, and the mass ratio of pore former to active material in the second slurry is 0.8:1.
[0068] (3) Apply the first electrode slurry to the aluminum foil side of the current collector. After drying, the pore former decomposes and escapes, and no other substances remain; use a smooth surface pressure roller to perform the first ...
Example Embodiment
[0070] Example 3
[0071] The present invention prepares a lithium ion battery pole piece with gradient porosity according to the following method:
[0072] (1) Mix graphite, conductive agent Super-P, and adhesive LA133 at a mass ratio of 8.6:0.7:0.7 to prepare a mixture, and then mix the mixture with water solvent at a mass ratio of 3:1 to prepare electrode slurry material;
[0073] (2) Divide the above-mentioned electrode slurry into three parts, add uniform and fine ammonium bicarbonate powder as the pore former, adjust the stirring speed to fully mix and disperse, among which, the pore former and active material in the first slurry The mass ratio of pore former to active material is 0.2:1, the mass ratio of pore former to active material in the second slurry is 0.4:1, and the mass ratio of pore former to active material in the third slurry is 0.7:1.
[0074] (3) Apply the first electrode slurry to the copper foil side of the current collector. After drying, the pore former decomp...
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