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Nano heat-insulating PVB intermediate film for laminated glass and preparation method thereof

A technology of nano heat insulation and laminated glass, applied in chemical instruments and methods, glass/slag layered products, coatings, etc., can solve the problem of unsatisfactory anti-oxidation and anti-yellowing performance of PVB interlayer film, which affects the energy-saving performance of laminated glass , does not have heat insulation function and other problems, achieves excellent anti-oxidation performance and anti-yellowing performance, simple and reasonable preparation method, and good use effect

Inactive Publication Date: 2020-11-17
济源市舜峰纳米科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to solve the above-mentioned technical problems, the present invention provides a nano heat-insulating PVB interlayer film for laminated glass and its preparation method. Through optimization and improvement of the structure and formula, as well as process improvement of the preparation method, the existing PVB interlayer film is solved. There is no special heat insulation function, and the heat insulation performance is poor, which affects the energy-saving performance of laminated glass. At the same time, the anti-oxidation and anti-yellowing performance of PVB interlayer film is not ideal, and the influence of PVB interlayer film on the mechanical strength of laminated glass is also Issues to be further improved

Method used

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  • Nano heat-insulating PVB intermediate film for laminated glass and preparation method thereof
  • Nano heat-insulating PVB intermediate film for laminated glass and preparation method thereof
  • Nano heat-insulating PVB intermediate film for laminated glass and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0025] This embodiment discloses a nano thermal insulation PVB intermediate film for laminated glass, which includes a modified PVB base film and a thermal insulation coating compounded on at least one side of the modified PVB base film; the modified PVB The base film includes the following raw materials measured in parts by mass:

[0026]

[0027]

[0028] Wherein, the film-forming chain extender is an ester formed by a dibasic acid and an alcohol. The thickness of the modified PVB base film is 0.35-0.80 mm. The thermal insulation coating is coated on the outer surface or both inner and outer surfaces of the modified PVB base film. The thermal insulation coating is formed by coating nano thermal insulation PVB paint.

[0029] Specifically, the thermal insulation coating adopts the nano thermal insulation PVB coating and includes the following raw materials measured in parts by mass:

[0030]

[0031] Among them, the nano thermal insulation powder is nano tin oxide antimony powder...

Embodiment 2

[0037] This embodiment discloses a nano thermal insulation PVB intermediate film for laminated glass, which includes a modified PVB base film and a thermal insulation coating compounded on at least one side of the modified PVB base film; the modified PVB The base film includes the following raw materials measured in parts by mass:

[0038]

[0039] Wherein, the film-forming chain extender is an ester formed by a dibasic acid and an alcohol. The thickness of the modified PVB base film is 0.35-0.80 mm. The thermal insulation coating is coated on the outer surface or both inner and outer surfaces of the modified PVB base film. The thermal insulation coating is formed by coating nano thermal insulation PVB paint.

[0040] Specifically, the thermal insulation coating adopts the nano thermal insulation PVB coating and includes the following raw materials measured in parts by mass:

[0041]

[0042] Among them, the nano heat insulation powder is a mixed powder of nano tin oxide antimony ...

Embodiment 3

[0048] This embodiment discloses a nano thermal insulation PVB intermediate film for laminated glass, which includes a modified PVB base film and a thermal insulation coating compounded on at least one side of the modified PVB base film; the modified PVB The base film includes the following raw materials measured in parts by mass:

[0049]

[0050] Wherein, the film-forming chain extender is an ester formed by a dibasic acid and an alcohol. The thickness of the modified PVB base film is 0.35-0.80 mm. The thermal insulation coating is coated on the outer surface or both inner and outer surfaces of the modified PVB base film. The thermal insulation coating is formed by coating nano thermal insulation PVB paint.

[0051] Specifically, the thermal insulation coating adopts the nano thermal insulation PVB coating and includes the following raw materials measured in parts by mass:

[0052]

[0053] Among them, the nano thermal insulation powder is a mixed powder of nano cesium tungsten ...

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Abstract

The invention relates to a nanometer heat insulation PVB intermediate film for laminated glass and a preparation method thereof. The nanometer heat insulation PVB intermediate film comprises a modified PVB base film and a heat insulation coating at least compounded on the surface of one side of the modified PVB base film; wherein the modified PVB base film comprises the following raw materials inparts by mass: 200-260 parts of high-viscosity PVB resin, 3-8 parts of silicon dioxide nanoparticles, 4-18 parts of zirconium dioxide nanoparticles, 2-6 parts of nano zinc oxide powder, 20-40 parts ofa plasticizer, 2-8 parts of a film-forming chain extender and 1-5 parts of an antioxidant. The nanometer heat insulation PVB intermediate film prepared by the method has good heat insulation performance and sound insulation performance, the heat conductivity coefficient can be controlled below 0.8 W / (m*K), meanwhile, compared with a traditional PVB intermediate film, the hardness and toughness are improved, and the nanometer heat insulation PVB intermediate film has good light transmittance, good heat stability, excellent oxidation resistance and excellent yellowing resistance.

Description

Technical field [0001] The invention relates to the field of thin film materials, in particular to a nano thermal insulation PVB intermediate film for laminated glass and a preparation method thereof. Background technique [0002] Laminated glass is also called high penetration resistant laminated glass. This product consists of three layers, a layer of polyvinyl butyral (PVB) interlayer film is sandwiched between two pieces of glass, which is bonded at high temperature and high pressure to combine the toughness of plastic with the rigidity of glass. This kind of intermediate film improves the resistance to breakage, the thicker the intermediate film, the stronger the glass. Traditionally, the sandwich structure is reflected in its product name. For example, the 4+0.76+4 specification laminated glass is made of two pieces of 4mm thick glass and a layer of 0.76mm thick PVB interlayer. [0003] Laminated glass plastic film is a polymer formed by the condensation reaction of higher...

Claims

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Application Information

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IPC IPC(8): C08J7/04C08J5/18C08L29/14C08K13/02C08K3/36C08K3/22C09D129/14C09D7/61C03C27/12B32B17/10
CPCC08J7/0427C08J5/18C09D129/14C09D7/61B32B17/10C08J2329/14C08J2429/14C08K13/02C08K3/36C08K2201/011C08K2003/2296C08K2003/2244B32B2307/304
Inventor 蔡天聪姚曙光侯霄孔祥寅张亚军
Owner 济源市舜峰纳米科技有限公司
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