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A laser preparation method of self-cleaning antibacterial glass

An antibacterial glass and self-cleaning technology, which is applied in glass manufacturing equipment, glass forming, glass reshaping, etc., can solve the problems of thermal damage on the glass surface, limited types of microstructures, and increased processing difficulty, so as to prevent thermal damage, Excellent self-cleaning effect, reducing cleaning difficulty

Active Publication Date: 2021-11-19
BEIHANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although it has been reported that ultrafast lasers can be used to fabricate microstructures on glass surfaces, due to the light transparency of glass, the types of microstructures processed are limited, and after the laser reaches the glass surface for material removal and structure induction, the remaining laser energy It will pass through the glass to generate heat on the processing platform, which is easy to cause thermal damage to the glass surface
In addition, in order to obtain the antibacterial function of the glass, it is necessary to add processes such as coating, which increases the difficulty of processing

Method used

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  • A laser preparation method of self-cleaning antibacterial glass
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  • A laser preparation method of self-cleaning antibacterial glass

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Step 1: Grinding and polishing the tempered glass and copper substrate surface, ultrasonic cleaning with alcohol and acetone for 10 minutes, and drying;

[0037] Step 2, configure AgNO 3 solution, the solubility is 1.5M;

[0038] Step 3, use a water gun to wash the prepared solution on the surface of the copper substrate, and at the same time slowly cover the tempered glass on the surface of the copper substrate;

[0039] Step 4, place the surface-treated tempered glass and the copper substrate sample under the femtosecond laser (wavelength 1064nm) to perform laser-induced surface micro-nano structure processing. The laser processing parameters are set as: power 8W, pulse width 500fs, The frequency is 400kHz, the scanning speed is 800mm / s, the scanning distance is 35μm, scanning 5 times, and the microcone structure covered with silver nanoparticles is obtained on the tempered glass surface;

[0040] Step five, move the glass vertically upward from the metal substrate;...

Embodiment 2

[0043] Step 1: Polish the surface of ordinary glass and titanium substrates, ultrasonically clean them with alcohol and acetone for 10 minutes, and dry them;

[0044] Step 2, configure AuCl 4 solution, the solubility is 0.5M;

[0045] Step 3: Use a water gun to wash the configured solution on the surface of the titanium substrate, and at the same time slowly cover the surface of the copper substrate with ordinary glass;

[0046] Step 4, place the surface-treated ordinary glass and the titanium substrate sample under a femtosecond laser (wavelength 1064nm) for laser-induced surface micro-nano structure processing. The laser processing parameters are set as follows: power 5W, pulse width 800fs, The frequency is 200kHz, the scanning speed is 1000mm / s, the scanning distance is 30μm, scanning 5 times, and the microcone structure covered with gold nanoparticles is obtained on the surface of ordinary glass;

[0047] Step five, move the glass vertically upward from the metal substra...

Embodiment 3

[0050] Step 1: Polish the surface of plexiglass and stainless steel substrate, ultrasonically clean with alcohol and acetone for 10 minutes, and dry;

[0051] Step 2, configure CuCl solution with a solubility of 1.0M;

[0052] Step 3: Use a water gun to wash the prepared solution on the surface of the stainless steel substrate, and at the same time slowly cover the surface of the copper substrate with plexiglass;

[0053] Step 4, place the surface-treated plexiglass and the stainless steel substrate sample under a femtosecond laser (wavelength 1064nm) for laser-induced surface micro-nanostructure processing. The laser processing parameters are set to: power 7W, pulse width 100fs, The frequency is 300kHz, the scanning speed is 1500mm / s, the scanning distance is 40μm, scanning 10 times, and the microcone structure covered with copper nanoparticles is obtained on the tempered glass surface;

[0054] Step five, move the glass vertically upward from the metal substrate;

[0055] ...

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Abstract

The invention discloses a laser preparation method of self-cleaning antibacterial glass. First, the prepared chemical solution is washed onto the surface of the metal substrate, and the bottom surface of the glass is covered with the metal substrate; thirdly, the ultrafast laser is used to penetrate the glass to irradiate the metal substrate, the glass at the interface is melted, and the microstructure on the metal is transferred to the glass. At the same time, the nanoparticles in the solution are reduced and adsorbed on the glass microstructure, and then the glass is annealed to form a double-sized micro-nanostructure covering the non-polar nanoparticles on the glass surface. The surface has an excellent self-cleaning super-hydrophobic function. It can remove oil stains on the glass surface with a small amount of water and labor, and there is almost no water stain residue, which reduces the difficulty of cleaning during use. Moreover, the superhydrophobic property can resist bacterial adhesion, and the nanoparticles can kill the adhered bacteria, thus making the glass surface have excellent antibacterial / bactericidal function. The preparation method of the invention is simple, has universal applicability, and is applicable to glasses of various materials. Moreover, the mechanical properties of the prepared glass are unchanged, the light transmittance is good, and the glass is suitable for large-scale commercial production.

Description

technical field [0001] The invention relates to a laser preparation method of self-cleaning antibacterial glass, which belongs to the technical field of glass manufacturing. Background technique [0002] With the gradual improvement of people's material and cultural life, people pay more and more attention to environmental sanitation and the cleanliness of human body contact surfaces. In the field of using glass as a countertop, such as coffee table worktops, dining table worktops, kitchen worktops and electronic scale covers installed on electronic scales, glass tables are easy to contact with various oils and other liquids. Wipe to clean, the user's work intensity is high, and the cleaning is not thorough. Most of the existing self-cleaning glass surfaces are super-hydrophilic coated glass, which requires a large impulse water flow to achieve a good cleaning effect. [0003] In addition, the glass platforms in these home areas are often in a humid environment and are oft...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C17/10C03B23/02
CPCC03B23/02C03C17/10C03C2217/253C03C2217/255C03C2217/256C03C2218/11C03C2218/32
Inventor 管迎春张佳茹
Owner BEIHANG UNIV
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