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Preparation method and application of high-efficiency dispersing agent for water-based automobile coating

A dispersant, automotive technology, applied in the coating and other directions, can solve the problems of large pigment agglomerates and easy flocculation, and achieve the effect of strong dispersing ability, good fullness, and excellent pigment wetting and dispersing.

Inactive Publication Date: 2020-12-18
QINGYUAN HAOYU CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] With the rapid development of the automobile industry, there are currently countless cars of various brands on the market, so the space for users to choose products is increasing day by day, while the market competition is becoming more intense. In addition to brand and performance, it has gradually turned its attention to the color and appearance of the product. Decoration is also an important factor. Pigment is one of the indispensable main components in automotive coatings. It has very good color and decoration, high chroma, high coloring Intensive color development is more important in various coatings, especially high-end automotive coatings. Pigments with high pigmentation and high tinting strength seldom exist in the form of single particles, but are usually aggregates formed by multiple basic particles through strong chemical bonds. The secondary reversible structural agglomerates are formed between the pigments through the van der Waals force. However, the pigment agglomerates have large particles, which are difficult to disperse evenly in the coating to the nanometer or sub-nanometer level, and are prone to flocculation.

Method used

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  • Preparation method and application of high-efficiency dispersing agent for water-based automobile coating
  • Preparation method and application of high-efficiency dispersing agent for water-based automobile coating
  • Preparation method and application of high-efficiency dispersing agent for water-based automobile coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Embodiment 1: Preparation of high-efficiency dispersant for water-based automotive coatings

[0035] Step S1: Add 12 parts by weight of cyclohexanone, 1.5 parts by weight of macromolecular initiator PSt-C1, and 4 parts by weight of component A to the reactor, and stir evenly; in this example, component A is tertiary acrylic acid For butyl ester, the reactor is equipped with auxiliary reaction equipment such as stirring paddles, thermometers, and condensers;

[0036] Step S2: Add the catalytic system formed by mixing cuprous bromide and bipyridine into the reaction kettle of step S1 under nitrogen environment, stir evenly, heat up to 120°C for polymerization reaction, and continue the reaction for 15 hours;

[0037] Step S3: Add 30 parts by weight of amine acrylate to the reaction kettle of step S2, fully react for 3.5 hours and then cool to room temperature, wherein the amine acrylate in this embodiment is dimethylaminoethyl methacrylate;

[0038] Step S4: discharging ...

Embodiment 2

[0041] Embodiment 2: the use of product application embodiment (taking black as example) the preparation of water-based environment-friendly high-performance high-pigment automotive paint and its performance index.

[0042] The high-efficiency dispersant for water-based automotive coatings prepared in Example 1 is a wetting and dispersing agent, and a resin-free grinding system is adopted. Quantitative water-based high-pigment pigments, deionized water, and wetting and dispersing agents are weighed and mixed evenly, and then put into a sand mill for further preparation. After grinding until the fineness meets the requirements, select functional additives and water-based dispersions, configure them under dispersion conditions, and stir evenly to obtain component B, wherein the addition amount of each component (by weight) is as follows:

[0043] The following formulas are proportioned according to parts by weight:

[0044]

[0045] Hydrophilic modified polyisocyanate as comp...

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Abstract

The invention provides a preparation method and application of a high-efficiency dispersing agent for a water-based automobile coating. Compared with the prior art, according to special construction requirements of current water-based automobile surface new material, based on anchoring principle of high-molecular compound to high-pigment pigment, the efficient dispersing agent with plurality of anchoring ends and organic ends is designed and synthesized through controllable free radical polymerization. The efficient dispersing agent for the water-based automobile coating is applied to the water-based automobile coating, the prepared water-based environment-friendly high-performance high-pigment automobile coating has excellent pigment wetting dispersity, high dispersing capacity, good stability, high efficiency and energy conservation, a formed paint film is high in gloss and good in fullness, the leveling property and the appearance value of the paint film are effectively improved; and the defects such as pinholes and bubbles are effectively reduced, the operability is high, and the paint film has the advantages of no toxicity, difficulty in combustion, no environmental pollution,safety, reliability and the like.

Description

【Technical field】 [0001] The invention relates to the field of water-based automotive coatings, in particular to a preparation method and application of a high-efficiency dispersant for water-based automotive coatings. 【Background technique】 [0002] With the continuous improvement of people's living standards and the rapid development of the automobile industry, my country has become the largest automobile production and sales country in the world. The huge automobile production and sales market will surely drive the rapid development of automobile coatings and the sharp increase in the amount of automobile coatings. Although the huge number of automobiles provides a large development space for automotive coatings, the current domestic automotive coatings market, especially the automotive repair market, is still dominated by solvent-based systems, which contain a large amount of volatile organic compounds. During production and use, not only It is harmful to the human body ...

Claims

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Application Information

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IPC IPC(8): C08F293/00C08F220/18C08F220/34C09D7/65
CPCC08F293/005C08F220/1804C08F220/34C09D7/65
Inventor 郭逍遥赵果汤汉良郭伟杰蔡志军李树伟温伟洪刘玉萍
Owner QINGYUAN HAOYU CHEM TECH
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