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A 3D printing device and method for compounding continuous fiber and granular matrix material

A continuous fiber and matrix material technology, which is applied in the field of 3D printing devices combining continuous fiber and granular matrix materials, can solve the problems of short impregnation time, difficult polymer materials, and improved mechanical strength, so as to reduce equipment and operating costs, The effect of reducing void defects and simplifying the manufacturing process

Active Publication Date: 2021-12-24
SHANGHAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the currently commonly used 3D printing technology for continuous fiber reinforced composite materials adopts the dipping printing method at the nozzle of the two-way feeding wire, that is, the continuous fiber and the matrix material wire are fed into the nozzle, and the matrix material is melted and impregnated with the fiber under the internal heating of the nozzle, and finally combined with Continuous fiber co-extrusion, this method mainly has the following problems: 1. Because the existing method is to feed the matrix material filament through one side, it will cause the matrix material to be unable to fully and evenly cover the continuous fiber, resulting in easy to appear inside the printed part. The problem of uneven bonding between holes and fibers affects the improvement of its mechanical strength; 2. The existing method is to impregnate the polymer material into the continuous fiber at the nozzle, the impregnation time is short, and the matrix material is difficult to fully penetrate into the fiber bundle Internally, the bonding effect between some single fibers is poor, which affects the mechanical strength of the printed part, and even causes failure; 3. The common method cannot smoothly extrude the high-viscosity molten polymer due to the low extrusion pressure, which makes the fiber reinforced The application of high-viscosity polymers as matrix materials in printing is limited; 4. Since many polymer materials are mostly granular or powdery, and common methods require the use of filamentous materials, that is, the preparation of filaments is indispensable, which not only causes cumbersome processes 1. The manufacturing cost is high, and some polymer materials are difficult or even impossible to prepare filaments that can be used for printing. The limitation of the types of available materials further affects the application range of printed parts

Method used

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  • A 3D printing device and method for compounding continuous fiber and granular matrix material
  • A 3D printing device and method for compounding continuous fiber and granular matrix material
  • A 3D printing device and method for compounding continuous fiber and granular matrix material

Examples

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Embodiment 1

[0065] In this embodiment, the continuous fiber is continuous carbon fiber (T300B-1000-50C, 1000 pieces, fiber bundle diameter 0.5 mm, single carbon fiber diameter 8 μm); particle matrix material is polylactic acid (PLA, melting point 170 ° C, particle size is 15 mesh).

[0066] The 3D printing method of continuous fiber and particle matrix material composite of the present invention specifically comprises the following steps:

[0067] S1 pretreatment: heat the heating block 25 to 210°C, turn on the water pump switch at the same time, the water circulation fluid is provided by the external water tank and circulates through the spiral channel provided inside the heat dissipation sleeve 19 to take away the heat and realize the cooling and heat dissipation function ;

[0068] S2 Feeding: Start the wire feeding element 6 (fiber delivery speed is 10mm / s) to feed the continuous carbon fiber from the fiber delivery pipe 8, and reach the nozzle 7 through the screw 5. When the top of ...

Embodiment 2

[0074] In this embodiment, the continuous fiber is continuous flax fiber (200tex, fiber bundle diameter 0.5mm, single fiber diameter 15μm); matrix material is epoxy resin, powdery, particle size is 125 mesh, melting point is 65 ℃, doped 2.5% carbon nanotubes (CNTs, model XFM-18) are used as reinforcing fillers (carbon nanotubes ensure the stress transmission of the matrix material due to their high specific surface area and aspect ratio, and further improve the strength and toughness of the composite material) , the molten state of the matrix material is a high-viscosity fluid. Compared with thermoplastic materials, thermosetting materials need to be post-cured after printing, so a curing agent needs to be added to the epoxy resin. This embodiment uses a high-temperature curing agent. The high-temperature curing agent has excellent properties, fast curing speed, and strong operability. The curing process is divided into two stages. The first stage is pre-cured at a lower tempe...

Embodiment 3

[0084] In this example, the continuous fiber is continuous carbon fiber (T300B-1000-50C, 1000 pieces, fiber bundle diameter 0.5 mm, single carbon fiber diameter 8 μm), and the particle matrix material is polyether ether ketone (PEEK, melting point 343 ° C, particle size The number is 15 mesh)

[0085] The difference between this embodiment and embodiment 1 mainly lies in:

[0086] (1) In the S1 pretreatment step, the heating block 25 is heated to 370°C.

[0087] (2) Since the fluidity of molten PEEK is worse than that of PLA used in Example 1, it is more difficult to extrude under the conveying action of screw 5. At the same fiber delivery speed as in Example 1, S4 extrusion step The fiber content of the composite silk obtained in is 60wt%;

[0088] All the other are with embodiment 1.

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Abstract

The invention discloses a 3D printing device in which continuous fibers and granular matrix materials are compounded, comprising a nozzle, a hopper, a feeding pipe and a screw. The continuous fibers are transported in the middle. The molten matrix material is located around the continuous fibers, and the continuous fibers are surrounded by molten It is impregnated by the base material, which greatly improves the impregnation effect compared with the existing two-way feeding at the nozzle. The present invention also provides a 3D printing method in which continuous fibers and granular matrix materials are composited, which directly utilizes granular or powdery matrix materials for continuous fiber reinforced printing, which solves the limitation of the traditional wire extrusion process on the form and type of printable matrix materials. Problems, expanding the optional range of matrix materials in fiber reinforced printing; at the same time, there is no need to use a wire drawing machine to make the matrix material into a wire before printing, which simplifies the manufacturing process and reduces equipment and operating costs.

Description

technical field [0001] The invention relates to the technical field of 3D printing of continuous fiber reinforced composite materials, in particular to a 3D printing device and method for compounding continuous fiber and particle matrix materials. Background technique [0002] Composite materials refer to materials that combine two or more different substances through various processes. Among them, fiber-reinforced composite materials are the most widely used, that is, fibers are introduced into the matrix material as an additive to improve the performance of the material. In the field of 3D printing, especially the performance advantages of various continuous fibers (carbon fiber, glass fiber, natural fiber, etc.) are used to achieve reinforced polymer materials (polylactic acid, acrylonitrile-butadiene-styrene, epoxy resin, etc.) The purpose of performance, such as obtaining the required characteristics such as light weight, high specific strength, high specific stiffness ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C64/118B29C64/176B29C64/20B29C64/336B29C64/393B29C64/314B29C64/295B33Y30/00B33Y40/00B33Y40/10B33Y50/02B33Y70/10
CPCB29C64/118B29C64/176B29C64/20B29C64/336B29C64/393B29C64/314B29C64/295B33Y30/00B33Y40/00B33Y40/10B33Y50/02B33Y70/10
Inventor 张海光黄廷龙胡庆夕
Owner SHANGHAI UNIV
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