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Environment-friendly dynamically vulcanized thermoplastic elastomer and processing technology thereof

A thermoplastic elastomer and dynamic vulcanization technology, applied in the field of thermoplastic elastomers, can solve the problems of excessive toxic substance content and odor level, reduction of mechanical properties such as elastomer tensile strength and elastic modulus, and non-compliance with green environmental protection. Achieving good fluidity, increased fluidity and processability, and low cohesion

Inactive Publication Date: 2021-01-22
安徽绿谷新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The existing dynamic vulcanized thermoplastic elastomer and its processing technology have the following technical problems: a large amount of filler oil, plasticizer and softener need to be added to reduce the viscosity of the system, which will not only reduce the tensile strength of the elastomer, elastic modulus, etc. The mechanical properties are reduced, and the content of toxic substances and odor levels will exceed the standard, which does not meet the requirements of green environmental protection

Method used

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  • Environment-friendly dynamically vulcanized thermoplastic elastomer and processing technology thereof

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Experimental program
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Effect test

Embodiment 1

[0029] The environment-friendly dynamic vulcanized thermoplastic elastomer of this embodiment is prepared from the following components by weight: 56 parts of polyolefin resin, 86 parts of EPDM rubber, 106 parts of atactic polypropylene, 18 parts of nano filler, thermal conductivity enhancing auxiliary 17 parts of antioxidant, 4 parts of antioxidant; the thermal conductivity enhancement additive is prepared from the following components by weight: 53 parts of petroleum resin, 22 parts of aluminum nitride, 15 parts of silica airgel, titanate coupling agent 20 servings.

[0030] Among them, the petroleum resin is C9 petroleum resin, the molecular weight is between 300-3000; the polyolefin resin is polyolefin resin homopolymer; [β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester; the melt index of atactic polypropylene is 1200-1800g / 10min (230℃, 2.16kg); the moisture content is 2 -3wt%, the propylene content is 84-92wt%.

[0031] The processing technology o...

Embodiment 2

[0037] The environment-friendly dynamic vulcanized thermoplastic elastomer of this embodiment is prepared from the following components by weight: 60 parts of polyolefin resin, 86 parts of EPDM rubber, 106 parts of atactic polypropylene, 22 parts of nano filler, thermal conductivity enhancement auxiliary 18 parts of anti-oxidant, 3 parts of antioxidant; the thermal conductivity enhancement additive is prepared from the following components by weight: 45 parts of petroleum resin, 24 parts of aluminum nitride, 13 parts of silica airgel, titanate coupling agent 20 servings.

[0038] Among them, the petroleum resin is C9 petroleum resin with a molecular weight between 300-3000; the polyolefin resin is a polyolefin resin copolymer; the nano-filler is nano-silica with a particle size range of 1000-2000 mesh; Triethylene glycol bis[β-3-tert-butyl-4-hydroxy-5-methylphenyl)propionate]. The melt index of the random polypropylene is 1200-1800g / 10min (230°C, 2.16kg); the moisture content...

Embodiment 3

[0045] The environment-friendly dynamic vulcanized thermoplastic elastomer of this embodiment is prepared from the following ingredients in parts by weight: 72 parts of polyolefin resin, 88 parts of EPDM rubber, 116 parts of atactic polypropylene, 23 parts of nano-fillers, thermal conductivity enhancing auxiliary 17 parts of antioxidant, 4 parts of antioxidant; the thermal conductivity enhancing additive is prepared from the following components by weight: 56 parts of petroleum resin, 24 parts of aluminum nitride, 12 parts of silica airgel, titanate coupling agent 18 servings.

[0046] Among them, the petroleum resin is C9 petroleum resin with a molecular weight of 300-3000; the polyolefin resin is a polyolefin resin copolymer; the nano-filler is nano-titanium dioxide with a particle size range of 1000-2000 mesh; the antioxidant is 2,6- Di-tert-butyl-4-methylphenol. The melt index of the random polypropylene is 1200-1800g / 10min (230°C, 2.16kg); the moisture content is 2-3wt%,...

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Abstract

The invention provides an environment-friendly dynamically vulcanized thermoplastic elastomer and a processing technology thereof, and relates to the technical field of thermoplastic elastomers. According to the environment-friendly dynamically vulcanized thermoplastic elastomer disclosed by the invention, the polyolefin resin is used as a continuous phase, the ethylene propylene diene monomer isused as a dispersion phase, the random polypropylene has good compatibility due to a common olefinic bond with the polyolefin resin, and the tensile strength, the elasticity modulus and the thermal conductivity of the elastomer are improved by the thermal conductivity enhancing aid; filling oil, a softener and a plasticizer are not added into the elastomer system, so that the elastomer system is low in toxicity, small in odor, environment-friendly and suitable for serving as an elastomer component of sports flooring; in the dynamic vulcanization granulation step of the processing technology, the non-return polypropylene with good fluidity is added from a feeding port, so that the fluidity and the processability of the mixture are improved, the extrusion granulation of the mixture is facilitated, and the processability of the dynamically vulcanized thermoplastic elastic finished product is improved.

Description

technical field [0001] The invention relates to the technical field of thermoplastic elastomers, in particular to an environment-friendly dynamic vulcanized thermoplastic elastomer and its processing technology. Background technique [0002] Dynamic vulcanization thermoplastic elastomer, also known as polyolefin alloy thermoplastic elastomer, or TPV for short, is a kind of thermoplastic elastomer (TPE). TPV is mainly composed of two parts. One is plastic as the continuous phase, and the other is rubber as the dispersed phase. It usually requires filler oil or plasticizer to cooperate with it. It is a high-performance thermoplastic elastomer prepared by dynamic vulcanization reaction blending technology. TPV has both the high elasticity of traditional vulcanized rubber and the reprocessability and recycling performance of thermoplastics. It is an important type of "green" new chemical materials. [0003] The existing dynamic vulcanized thermoplastic elastomer and its process...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/16C08L23/00C08L57/02C08K13/04C08K7/26C08K3/28C08K5/10C08K3/34C08K3/36C08K3/22C08K3/26
CPCC08L23/12C08L2207/04C08L2207/14C08L2205/025C08L2205/035C08K2003/282C08K2201/011C08K2003/2241C08K2003/265C08L23/16C08L23/00C08L57/02C08K13/04C08K7/26C08K3/28C08K5/10C08K3/346C08K3/36C08K3/22C08K3/26
Inventor 俞海燕
Owner 安徽绿谷新材料有限公司