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A kind of manganese oxide ore fluidized reduction device and method

A manganese oxide ore, fluidized technology, applied in the field of chemical metallurgy, can solve the problems of complex structure of the fluidized bed reduction furnace, unexplained utilization of the reduction tail gas gas composition, unfavorable heat exchange, etc., so as to save equipment costs and reduce energy consumption. , the effect of improving cooling efficiency

Active Publication Date: 2022-08-05
中科南京绿色制造产业创新研究院 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages of this method are: 1) a heat exchanger is installed in the reduction furnace, which makes the structure of the fluidized bed reduction furnace complicated; Heat exchange; 3) The remaining gas components in the reduction tail gas do not explain how to use them

Method used

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  • A kind of manganese oxide ore fluidized reduction device and method

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Embodiment 1

[0079] This embodiment provides a fluidized reduction device for manganese oxide ore, and the schematic structural diagram of the device is as follows: figure 1 As shown, it includes a reduction roasting unit, a combustion unit and a fluidized cooling unit; the fluidized cooling unit includes an indirect fluidized cooler 5; the indirect fluidized cooler 5 is provided with a heat pipe;

[0080] The solid outlet of the reduction roasting unit is connected to the heat source inlet of the indirect fluidized cooler 5, and the indirect fluidized cooler 5 is provided with a fluidization gas inlet and a fluidization gas outlet. The reduction roasting unit The gas outlet is connected to the inlet of the combustion unit.

[0081] The reduction roasting unit includes a fluidized reduction furnace 1; a first gas-solid separator 1-1 is arranged between the reduction roasting unit and the combustion unit, and the gas outlet of the reduction roasting unit is connected to the first gas-solid ...

Embodiment 2

[0092] This embodiment provides a fluidized reduction device for manganese oxide ore. The device includes a reduction roasting unit, a combustion unit, and a fluidized cooling unit; the fluidized cooling unit includes an indirect fluidized cooler 5; The indirect fluidized cooler 5 is provided with a heat pipe;

[0093]The solid outlet of the reduction roasting unit is connected to the heat source inlet of the indirect fluidized cooler 5, and the indirect fluidized cooler 5 is provided with a fluidization gas inlet and a fluidization gas outlet. The reduction roasting unit The gas outlet is connected to the inlet of the combustion unit.

[0094] The reduction roasting unit includes a fluidized reduction furnace 1; a first gas-solid separator 1-1 is arranged between the reduction roasting unit and the combustion unit, and the gas outlet of the reduction roasting unit is connected to the first gas-solid separator 1 -1 is connected to the inlet, and the gas outlet of the first ga...

Embodiment 3

[0102] The present embodiment provides a method for the fluidized reduction of manganese oxide ore. The method is carried out by using the device in Embodiment 1, and includes the following steps:

[0103] (1) The manganese oxide ore raw material with a total manganese grade of 35wt% is ground, and the fineness reaches 100 mesh and the sieve residue is less than 20%. After grinding, it is fed into the raw material preheater 3. After preheating, it enters the fluidized reduction furnace. In 1, a fluidized reduction reaction occurs with coal gas, the reaction temperature is 700 ° C, and the reaction time is 20 minutes. The solid product after the reaction enters the indirect fluidized cooler 5, and conducts direct heat exchange with the fluidizing gas and indirect heat with air. heat exchange, the fluidizing gas is coal gas; the temperature of the solid product after heat exchange is reduced to 100 ° C to obtain a manganese oxide product; the air temperature after heat exchange i...

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Abstract

The invention provides a fluidized reduction device and method for manganese oxide ore. The device includes a reduction roasting unit, a combustion unit and a fluidized cooling unit; the fluidized cooling unit includes an indirect fluidized cooler; The indirect fluidized cooler is provided with a heat pipe; the solid outlet of the reduction roasting unit is connected to the heat source inlet of the indirect fluidized cooler, and the indirect fluidized cooler is provided with a fluidization gas inlet and the fluidizing gas outlet, the gas outlet of the reduction roasting unit is connected with the inlet of the combustion unit. The invention improves the cooling capacity and cooling efficiency of the device through the setting of the indirect fluidized cooler, simplifies the process flow, saves the equipment cost, and at the same time makes full use of the waste heat of the system, and the waste heat utilization rate reaches more than 88%. , with good industrial application prospects.

Description

technical field [0001] The invention belongs to the technical field of chemical metallurgy, and particularly relates to a fluidized reduction device and method for manganese oxide ore. Background technique [0002] Manganese sulfate is the raw material of electrolytic manganese metal. Manganese salt is also one of the important trace element fertilizers in agriculture, which can promote crop growth and increase yield. The traditional method is to use manganese carbonate ore to react with acid to obtain manganese salt. However, manganese carbonate ore resources in my country are in short supply at present, and manganese oxide ore has been used to prepare manganese salt. In nature, manganese oxide ore is mainly composed of MnO 2 , Mn 2 O 3 They exist in the form of their hydrates, and their reactivity with acids is poor, making manganese salts difficult to obtain. Therefore, in order to obtain manganese salts, it is necessary to first convert MnO 2 , Mn 2 O 3 And its h...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B1/10C22B1/26C22B47/00
CPCC22B1/10C22B1/26C22B47/00
Inventor 谢朝晖朱庆山邵国强邹正孙昊延
Owner 中科南京绿色制造产业创新研究院