A kind of high-durability water-based polyurethane outdoor wood paint and preparation method thereof
A durable water-based, polyurethane technology
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Embodiment 1
[0025] 1. Preparation of mercapto-terminated aliphatic waterborne polyurethane
[0026] This embodiment sets 5 groups of treatment groups, labeled as treatment 1, treatment 2, treatment 3, treatment 4 and treatment 5 to prepare mercapto-terminated modified aliphatic water-based polyurethane respectively. At the same time, this embodiment also has a control treatment to prepare fat Aquatic polyurethane, the operation method of each treatment group is as follows.
[0027] 1.1 Processing 1
[0028] Step 1: Add 21.11g of polyether diol and 19.03g of isophorone diisocyanate in a four-necked flask equipped with a mechanical stirrer, a thermometer and a reflux condenser, stir evenly, and then add 0.1g of tributyl tin hydride;
[0029] Step 2: heating the mixed solution obtained in the step 1 to 70°C and keeping it warm for 5 hours;
[0030] Step 3: Add dimethylolpropionic acid (3.02g) / N-methylpyrrolidone (7g) solution to the mixed solution treated in step 2, so that the temperatur...
Embodiment 2
[0086] 1. Preparation of waterborne polyurethane outdoor wood paint
[0087] In the present embodiment, the adopted formula is shown in Table 3, and the raw material information involved in the formula is as follows:
[0088] The polyurethane dispersion A in the formula is the aliphatic waterborne polyurethane modified by mercapto-terminated modification prepared in the treatment 1 of Example 1.
[0089] Polyurethane dispersion B in the formula is the polyester type aliphatic aqueous polyurethane dispersion that the brand of Dongfang resin is 8201.
[0090] The water-based wetting agent in the formula is BYK-346 wetting agent.
[0091] The water-based defoamer in the formula includes defoamer A component and defoamer B component. The defoamer component A is Tego Chemical’s brand TEGO-810, and the defoamer component B is Corning The company's trademark is Dehydran 1293.
[0092] The water-based thickening rheology agent in the formula is the product of Mingling Company's bra...
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