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Method for strengthening ferroboron separation and extraction of ferroboron-containing concentrate through suspension reduction roasting

A technology of ferroboron concentrate and ferroboron, which is applied in the field of suspension reduction roasting to strengthen the separation and extraction of boron-containing iron concentrate, can solve the problems of reduced production efficiency, high boron activity, low energy consumption, etc., and achieves improved reduction efficiency, The effect of high reaction temperature and simplified process

Active Publication Date: 2021-04-06
NORTHEASTERN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The molten boron-rich slag obtained by the above two methods needs to be cooled slowly to obtain high reactivity, which reduces production efficiency. To develop a comprehensive boron-containing iron concentrate with short process, low energy consumption and high boron activity It is important to use the method

Method used

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  • Method for strengthening ferroboron separation and extraction of ferroboron-containing concentrate through suspension reduction roasting

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Process such as figure 1 shown;

[0040] The boron-containing iron ore concentrate used contains TFe 54.51% by mass percentage, B 2 o 3 4.82%, SiO 2 3.88%, Al 2 o 3 0.31%, CaO 0.21%, MgO 9.97%, P 0.10%, S 1.33%;

[0041] Grinding the boron-containing iron ore concentrate to a particle size of ≤0.074mm accounts for 80% of the total mass and serves as a raw material;

[0042] The raw material is heated to 800°C, and the boronite is activated and decomposed into Suianite; then it is passed into a reduction reactor and mixed with a reducing gas. The reducing gas is a mixed gas of hydrogen and nitrogen, and the volume percentage of nitrogen in the mixed gas is 20%. ;

[0043] The raw material is in a suspended state under the action of the air flow, and undergoes a reduction reaction with the reducing gas, so that the iron oxide in the raw material is reduced to metallic iron, and the resulting reduced material is discharged from the discharge port of the reduction ...

Embodiment 2

[0049] The boron-containing iron ore concentrate used contains TFe 47.37% by mass percentage, B 2 o 3 6.73%, SiO 2 6.01%, Al 2 o 3 0.27%, CaO 0.31%, MgO 12.65%, P 0.08%, S 1.37%;

[0050] The method is the same as the embodiment, the difference is:

[0051] (1) Grinding the boron-containing iron ore concentrate to a particle size of ≤0.074mm accounts for 65% of the total mass;

[0052] (2) Raw material is heated to 850 ℃, then pass into reduction reactor; Reducing gas is the mixed gas of hydrogen, carbon monoxide and nitrogen, the volume percentage of nitrogen in the mixed gas is 15%, the volume percentage of carbon monoxide is 15%;

[0053] (3) The flow velocity of the reducing gas entering the reduction reactor is 0.18m / s, and the residence time of the raw material in the reduction reactor is 25min; the metallization rate of the reduction material is 91%

[0054] (4) The mass concentration of the pulp is 55%; the addition of sodium hydroxide is based on NaOH and Mg ...

Embodiment 3

[0059] The boron-containing iron ore concentrate used contains TFe 51.88% by mass percentage, B 2 o 3 5.82%, SiO 2 5.46%, Al 2 o 3 0.48%, CaO 0.53%, MgO 14.87%, P 0.09%, S 0.99%;

[0060] The method is the same as the embodiment, the difference is:

[0061] (1) Grinding the boron-containing iron ore concentrate to a particle size of ≤0.074mm accounts for 70% of the total mass;

[0062] (2) Raw materials are heated to 750° C., and then passed into a reduction reactor; the reducing gas is a mixed gas of hydrogen and nitrogen, and the volume percentage of nitrogen in the mixed gas is 15%;

[0063] (3) The superficial flow velocity of the reducing gas entering the reduction reactor is 0.12m / s, and the residence time of the raw material in the reduction reactor is 40min; the metallization rate of the reduction material is 89%

[0064] (4) The mass concentration of the pulp is 50%; the amount of sodium hydroxide added is based on NaOH and Mg 2 B 2 o 5 1.3 times of the the...

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Abstract

The invention relates to a method for strengthening ferroboron separation and extraction of ferroboron-containing concentrate through suspension reduction roasting. The method comprises the following steps that (1), the ferroboron-containing concentrate is ground to be used as a raw material; (2), the raw material is heated, introduced into a reduction reactor, and mixed with reducing gas, and reduction reaction is carried out in a suspension state; (3), water quenching is carried out on the reduction material to room temperature, and the water-quenched material is stirred with sodium hydroxide and water for size mixing; (4), an ore pulp is ground, and meanwhile, leaching is carried out to obtain leached ore pulp; (5), the leached ore pulp is filtered, a leachate and leached slag are separated, and the leachate is a solution containing sodium metaborate; and (6), the leached slag is prepared into secondary ore pulp, and then magnetic separation is carried out. The reduction main body equipment is a suspension furnace, so that the reduction efficiency is greatly improved; and ore grinding and leaching are carried out synchronously, boron minerals are fully leached out in the ore grinding process, and the method for strengthening ferroboron separation and extraction of the ferroboron-containing concentrate through suspension reduction roasting has the advantages that the leaching time is shortened, the process is simplified, and energy consumption is reduced.

Description

technical field [0001] The invention belongs to the technical fields of mineral processing and metallurgy, and in particular relates to a method for suspension reduction and roasting to strengthen the separation and extraction of boron-containing iron ore concentrate. Background technique [0002] Due to the close symbiotic relationship between iron and boron minerals in boronite, complex composition, and fine crystal size, the mineral processing method can only obtain TFe grades of 45-55%, B 2 o 3 4-6% boron-containing iron concentrate and B 2 o 3 The content of boron concentrate is 12-18%. The key to the further processing and utilization of boron-containing iron concentrate is the secondary separation of boron and iron. Otherwise, it can only be used as a blast furnace ore blending and boron minerals cannot be recovered, resulting in a huge waste of boron resources. [0003] At present, the method of comprehensive utilization of boron-containing iron ore concentrate is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/10B03C1/015C01B35/12
CPCC22B1/10B03C1/015C01B35/121Y02P10/20
Inventor 余建文韩跃新李佩昱李艳军高鹏孙永升
Owner NORTHEASTERN UNIV