UV (ultraviolet) photocuring multifunctional epoxy reactive diluent and preparation method thereof

A multifunctional epoxy, reactive diluent technology, applied in epoxy resin coatings, silicone compounds, coatings, etc., can solve problems such as poor compatibility, poor cured film state, and poor curing effect. Achieve the effects of good compatibility, overcoming poor curing effect, and simple and efficient preparation method

Pending Publication Date: 2021-04-30
安徽格林开思茂光电科技股份有限公司
View PDF6 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] There are many types of epoxy-based reactive diluents on the market, but the existing epoxy-based reactive diluents have poor compatibility with epoxy-containing organic silicon or organic fluorine-silicon photocurable r

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • UV (ultraviolet) photocuring multifunctional epoxy reactive diluent and preparation method thereof
  • UV (ultraviolet) photocuring multifunctional epoxy reactive diluent and preparation method thereof
  • UV (ultraviolet) photocuring multifunctional epoxy reactive diluent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0035]Example 1

[0036]Prepare UV photocuring polyfunctional epoxy active diluent:

[0037]S1, under a nitrogen gas conditions, 1 mol of tetramethyltrinylcyclic tetra siloxane, 100 ml of n-hexane, 200 μgspeier catalyst were mixed and uniformly added to the reactor, add 4 mol of tetramethylene silicon oxygen at 60 ° C. After the dropwise addition, the reaction was stirred at 60 ° C for 5 h;

[0038]S2, under a nitrogen gas conditions, 4 mol allyl glycidyl ether was added dropwise to the reaction system obtained by step S1. After the dropwise addition, the reaction was stirred at 60 ° C for 5 h, then at 100 ° C, -0.1MPa decompression Distillation 1 h, it is obtained.

[0039]The prepared UV photocurable polyfunctional epoxy active diluent structure is as follows:

[0040]

[0041]Preparation of photocurable coating: silicone containing epoxy groups, HPF6The UV photocuring polyfunctional epoxy active diluent is mixed in mass than 100: 5: 20, i.e., UV photocurable coatings.

[0042]Among them, an epoxy gro...

Example Embodiment

[0044]Example 2

[0045]Prepare UV photocuring polyfunctional epoxy active diluent:

[0046]S1, under a nitrogen gas conditions, 1 mol tetramethyltrinylcyclic tetrahydiloxane, 100 ml of n-hexane, 200 μgspeier catalyst were mixed and uniformly added to the reactor, add 4 mol end hydrogen-containing oil, drip at 60 ° C. After completion, the reaction was stirred at 60 ° C for 5 h;

[0047]S2, under a nitrogen gas conditions, 4 mol allyl glycidyl ether was added dropwise to the reaction system obtained by step S1. After the dropwise addition, the reaction was stirred at 60 ° C for 5 h, then at 100 ° C, -0.1MPa decompression Distillation 1 h, that is,

[0048]In S1, the structural formula of end-containing silicone oil is as follows:

[0049]

[0050]In the formula, N is 1 to 1000.

[0051]The prepared UV photocurable polyfunctional epoxy active diluent structure is as follows:

[0052]

[0053]In the formula, N is 1 to 1000.

[0054]Preparation of photocurable coating: silicone containing epoxy groups, HPF6The UV p...

Example Embodiment

[0057]Example 3

[0058]Prepare UV photocuring polyfunctional epoxy active diluent:

[0059]S1, under a nitrogen gas conditions, 1 mol of tetramethyltrinylcyclo tetra siloxane, 100 ml of n-hexane, 200 μgspeier catalyst were mixed and uniformly added to the reactor, adding 4 mol of hydrofluorofluorine oil at 60 ° C, After the dropwise addition, the reaction was stirred at 60 ° C for 5 h;

[0060]S2, under a nitrogen gas conditions, 4 mol allyl glycidyl ether was added dropwise to the reaction system obtained by step S1. After the dropwise addition, the reaction was stirred at 60 ° C for 5 h, then at 100 ° C, -0.1MPa decompression Distillation 1 h, that is,

[0061]In S1, the structural formula containing hydrofluorine oil is as follows:

[0062]

[0063]In the formula, N is 1 to 1000.

[0064]The prepared UV photocurable polyfunctional epoxy active diluent structure is as follows:

[0065]

[0066]In the formula, N is 1 to 1000.

[0067]Preparation of photocurable coating: silicone containing epoxy groups, HPF6Th...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a UV photocuring multifunctional epoxy reactive diluent and a preparation method thereof. The preparation method comprises the following steps: under the protection of inert gas, mixing tetramethyl tetravinyl cyclotetrasiloxane, an organic silicon end-capping reagent and a catalyst to carry out hydrosilylation reaction, and after the reaction is finished, adding allyl glycidyl ether to carry out hydrosilylation reaction to obtain the UV photocuring multifunctional epoxy reactive diluent. The preparation method has the advantages that the preparation method is simple and efficient, and the prepared UV photocuring multifunctional epoxy reactive diluent can greatly improve the curing rate of cationic photocuring and is particularly suitable for a photocuring system taking epoxy group-containing organic silicon or organic fluorine-silicon photocuring resin as a main component.

Description

technical field [0001] The invention relates to the technical field of organic synthesis, in particular to a UV photocurable multifunctional epoxy reactive diluent and a preparation method thereof. Background technique [0002] UV-curable coating is an environmentally friendly coating based on ultraviolet radiation curing technology. Under the irradiation of ultraviolet light, it can be cross-linked and cured in a short time to form a coating with excellent mechanical properties. Compared with traditional solvent-based coatings, UV-curable coatings have less emission of organic volatile components, and have the advantages of environmental protection and energy saving. [0003] At present, UV curing methods can be roughly divided into two categories: free radical photocuring and cationic photocuring according to the curing mechanism. Among them, compared with the free radical photocurable system, the cationic photocurable system has the advantages of being less susceptible t...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08G77/38C09D183/06C09D163/00C07F7/21
CPCC08G77/38C09D183/06C09D163/00C07F7/21C08L2205/025
Inventor 江逸民钟永旺
Owner 安徽格林开思茂光电科技股份有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap