Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Epoxy neopentyl glycol oleate, synthesis method and application thereof

A technology of neopentyl glycol ester and epoxy oleic acid, which is applied in the synthesis field of epoxy neopentyl glycol oleate and epoxy oleic acid neopentyl glycol ester, and achieves good low-temperature impact embrittlement performance and UV blocking High efficiency, good aging resistance

Pending Publication Date: 2021-06-04
NANTONG HAIERMA TECH CO LTD
View PDF1 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In addition, neopentyl glycol oleate is mainly used as lubricating oil, and its further extended application is rarely reported

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Epoxy neopentyl glycol oleate, synthesis method and application thereof
  • Epoxy neopentyl glycol oleate, synthesis method and application thereof
  • Epoxy neopentyl glycol oleate, synthesis method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Synthesis of ethylene oleic acid neopentylene glycol esters were synthesized by oleic acid and neopad diol, and the synthesis steps include:

[0040] 1) Esterified reaction: In three round bottom flasks equipped with stirring, thermometer, reflow condenser, 513.24 g of oleic acid, 104g of neopentane glycol, 0.93 g of catalyst phosphoric acid, transfer nitrogen and stir up to 220 The temperature in ° C was held for 4 hours, and the reaction was charged for 4 hours at 250 ° C. During the intermittent feed, when the sample is less than 2.0, the reaction was completed, and the light yellow oil neopentylene glycol oleide was obtained, and the acid value was 1.93 mgKOH / g.

[0041] 2) Epoxidized reaction: 509 g of the neoplancanol oleetrate obtained in step 1), 22 g of formic acid, 0.5 g of catalyst concentrated sulfate, and four-port with stirring means, thermometer, liquid-liquid funnel, reflow contribution pipe In the round bottom flask, stir up to 60 ° C, slowly drop 50% bio...

Embodiment 2

[0054] Synthesis of ethylene oleic acid neopentylene glycol esters were synthesized by oleic acid and neopad diol, and the synthesis steps include:

[0055] 1) Esterified reaction: In three round bottom flasks equipped with a stirring device, a thermometer, a reflux condensation pipe, 549.9 g of oleic acid is sequentially added, and 104 g of pentanediol, and the catalyst titanate is 1.63 g, and nitrogen is introduced. The mixture was stirred to 160 ° C, 180 ° C, 200 ° C, 2 hours, 2 hours, 230 ° C, 2 hours, 250 ° C insulation reaction for 3 hours. When the sample was less than 2.0, the reaction was completed, and the reaction was completed to give a light yellow oily neopentylene glycol oleate, and the acid value was 1.85 mgKOH / g.

[0056] 2) Epoxidized reaction: 470 g of neopentyl glycol oleanate prepared in step 1), 28 g of formic acid, 1.40 g of catalyst phosphoric acid 1.40 g of a stirring apparatus, thermometer, separatory funnel, reflow condensed tube four rounds In the und...

Embodiment 3

[0058] Synthesis of ethylene oleic acid neopentylene glycol esters were synthesized by oleic acid and neopad diol, and the synthesis steps include:

[0059] 1) Esterified reaction: In three round bottom flasks equipped with stirring, thermometer, reflow condensation pipe, 624 g of oleic acid, 104g of new pentanediol, 2.76 g of catalyst, penta nitrogen, stir up to 170 EtOAc EtOAc EtOAc EtOAc. When the sample is less than 2.0, the reaction is completed, the reaction is completed, resulting in a light yellow oil, and is detected, the acid value of 1.90 mgKOH / g.

[0060] 2) Epoxidized reaction: 500g of neopentyl glycol oleanide obtained in step 1), 39g of formic acid, 1.05 g of catalyst phosphoric acid to add a stirring device, a thermometer, a fluid funnel, and reflow the four-port circle In the bottom flask, stir up to 60 ° C, slowly drop 50% diodehydrate 250g with stirring, after adding 10 hours at 65 ° C, washed out of the lower acid water, the upper oil ester water, was evapora...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Acid valueaaaaaaaaaa
Acid valueaaaaaaaaaa
Login to View More

Abstract

The invention discloses epoxy neopentyl glycol oleate with a structure as shown in a formula (I), wherein the epoxy neopentyl glycol oleate can be applied to plastics as a plasticizer and is synthesized by the following steps: 1) carrying out esterification reaction on oleic acid and neopentyl glycol to synthesize neopentyl glycol oleate; and 2) carrying out epoxidation reaction on the neopentyl glycol oleate and hydrogen peroxide to synthesize the epoxy neopentyl glycol oleate. According to the invention, the preparation process is simple, and the product is excellent in processability, relatively high in ultraviolet rejection rate and good in solvent precipitation resistance when being applied to plastics as a plasticizer; and when the epoxy neopentyl glycol oleate is especially applied to wire and cable materials, the product is good in aging resistance and low-temperature impact embrittlement performance, so that the epoxy neopentyl glycol oleate is a non-toxic plastic plasticizer with excellent properties and has a wide market prospect.

Description

Technical field [0001] The present invention relates to a plasticizer, and more particularly to an epoxy oalic acid neutral glycol ester, and the present invention also relates to a synthesis method and application of an epoxy oalic acid neopentylene glycol ester. Background technique [0002] In recent years, with the enhancement of people's environmental protection, plastic products such as medicine, food packaging, daily necessities, toys have put forward higher hygiene requirements for plasticizers. The plasticizer has mainly been mainly based on edible products, but it has found that the plasticizer has some poisonous side effects on the human body. To this end, EU food safety agencies (EFSA) specify octyl phthalate (DOP), limited amounts of adipate (DOA), so that non-toxic environmentally friendly plasticizers have become the focus of the current global plasticizer research. [0003] Since the epoxy vegetable oil has good heat resistance, light resistance, mutualepoot, low ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C07D301/12C07D303/44C08K5/1515C08L27/06
CPCC07D303/44C07D301/12C08K5/1515C08L27/06
Inventor 毋亭亭曹志亮李道斌邓健能张莉春
Owner NANTONG HAIERMA TECH CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com