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Temperature-responsive well cementation cement slurry and preparation method thereof

A cementing slurry, temperature responsive technology, applied in chemical instruments and methods, materials for heat exchange, composition of drilling holes, etc. Application value and other issues, to avoid thermal decomposition, timely and efficient control, and promote the development of low-temperature mechanical properties

Inactive Publication Date: 2021-06-04
XI'AN POLYTECHNIC UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, it is not difficult to find that the use of low-heat-of-hydration cementitious materials, inert materials, and heat-absorbing agents to adjust the hydration heat release and hydration temperature rise of the cement slurry system are reflected in irreversible inhibition, and the low temperature at the bottom of the well further delays the cement slurry. The mechanical properties of the slurry system are developed; in addition, the melted PCMs have caused great damage to the compressive strength and flexural strength of the cured cement stone, causing the cement stone to lose its original application value

Method used

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  • Temperature-responsive well cementation cement slurry and preparation method thereof
  • Temperature-responsive well cementation cement slurry and preparation method thereof
  • Temperature-responsive well cementation cement slurry and preparation method thereof

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preparation example Construction

[0042] A method for preparing a temperature-responsive cementing cement slurry of the present invention is specifically implemented according to the following steps:

[0043] Step 1, preparing bidirectional intelligent temperature control materials, specifically:

[0044] Step 1.1, first, weigh respectively according to mass percentage: urea 10-12%, melamine 3-5%, formaldehyde 34-38%, deionized water 45-50%, triethanolamine 0.5-1.0%, the mass percentage of the above components The sum is 100%; secondly, urea, melamine and formaldehyde are dissolved in deionized water and placed in a three-necked flask with a stirring and condensing reflux device, and triethanolamine is used to adjust the pH of the system to 8-9; finally, the constant temperature Raise the temperature of the water bath to 60-65°C and react for 1.5 hours at a speed of 200-300r / min to obtain the organic resin prepolymer;

[0045] Step 1.2, weighing according to mass percentage: organic resin prepolymer 10-15%, m...

Embodiment 1

[0057] A method for preparing a temperature-responsive cementing cement slurry of the present invention is specifically implemented according to the following steps:

[0058] Step 1.1, at first, weigh respectively according to mass percentage: urea 10%, melamine 3%, formaldehyde 34%, deionized water balance, triethanolamine 0.5%, the sum of above component mass percentage is 100%; Secondly, urea , melamine and formaldehyde were dissolved in deionized water and placed in a three-necked flask with a stirring and condensing reflux device, and the pH of the system was adjusted to 8 with triethanolamine; finally, the temperature of the constant temperature water bath was raised to 60°C, and the speed of 200r / min After reacting for 1.5h, the organic resin prepolymer can be obtained;

[0059] Step 1.2, weighed according to mass percentage: organic resin prepolymer 15%, silicon nitride 0.2%, low melting point paraffin 26%, graphene oxide (GO) 0.05, deionized water balance styrene-male...

Embodiment 2

[0067] A method for preparing a temperature-responsive cementing cement slurry of the present invention is specifically implemented according to the following steps:

[0068] Step 1.1, at first, weigh respectively according to mass percentage: urea 12%, melamine 5%, formaldehyde 38%, deionized water balance, triethanolamine 1.0%, the sum of above component mass percentage is 100%; Secondly, urea , melamine and formaldehyde were dissolved in deionized water and placed in a three-necked flask with a stirring and condensing reflux device, and the pH of the system was adjusted to 9 with triethanolamine; finally, the temperature of the constant temperature water bath was raised to 65°C, and the speed of 300r / min The organic resin prepolymer can be obtained after 1.5 hours of reaction;

[0069] Step 1.2, weighed according to mass percentage: organic resin prepolymer 15%, silicon nitride 0.2%, low melting point paraffin 26%, graphene oxide (GO) agent 0.05%, deionized water 47%, styre...

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Abstract

The invention discloses temperature-responsive well cementation cement slurry which comprises the following components in percentage by mass: 63-67% of oil well cement, 3.3-9.4% of a bidirectional intelligent temperature control material, 27.3-29.4% of mixing water, 0.1% of a dispersing agent and 0.2% of a filtrate reducer, and the sum of the mass percentages of the components is 100%. The invention further discloses a preparation method of the well cementation cement slurry; wherein the temperature-responsive well cementation cement slurry is constructed by taking oil well cement as a base material and a bidirectional intelligent temperature control material as an auxiliary material and being supplemented with other additives. The bidirectional intelligent temperature control material has the characteristics of bidirectional and intelligent temperature control, and realizes reversible, timely and efficient control of the hydration temperature rise of the deepwater natural gas hydrate layer well cementation cement slurry. In the cement hydration acceleration period, the cement slurry hydration temperature rise is reduced through phase change heat absorption of the bidirectional intelligent temperature control material core material, thermal decomposition of metastable state hydrate is avoided, in the deceleration period, the cement slurry temperature reduction rate is reduced through phase change heat release, and therefore, low-temperature mechanical property development is promoted.

Description

technical field [0001] The invention belongs to the technical field of oil and gas well cementing, and in particular relates to a temperature-responsive cementing cement slurry and a preparation method of the temperature-responsive cementing cement slurry. Background technique [0002] Today, the contradictions between global food, resource and energy supply shortages and rapid population growth are becoming more and more prominent. Exploitation and utilization of marine resources is an inevitable trend of resource exploration and development in countries all over the world. The global marine oil and gas reserves are huge. According to incomplete statistics, the global marine oil and gas reserves are 100-250 billion tons, accounting for about 34% of the total proven reserves. my country's offshore oil and gas resources are also very rich. There are four offshore oil and gas production areas in the Bohai Sea, the South Yellow Sea, the East China Sea and the South China Sea. H...

Claims

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Application Information

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IPC IPC(8): C09K8/467C09K5/06C08G12/38C04B28/00
CPCC09K8/467C09K5/063C08G12/38C04B28/00C04B2103/408C04B24/24C04B2103/0071C04B2103/40C04B2103/0094
Inventor 霍锦华车远军张驰刘宏臣左维余柏松
Owner XI'AN POLYTECHNIC UNIVERSITY
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