Flame retardant abs composite material and its preparation process
A composite material and flame-retardant technology, which is applied in the field of flame-retardant ABS composite materials and its preparation, can solve the problems of high cost of ionic liquid, large amount of flame retardant added, and carcinogenicity, and achieve excellent mechanical properties and flame-retardant properties Strong, odor-eliminating effect
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[0047] Wherein the preparation of the porous glass microbead flame retardant unit is as follows: 1) the porous glass microbead after the acidification treatment is mixed with the excess coupling agent KH550 solution, with triethylamine as the catalyst and acetonitrile as the reaction solvent, reflux, cleaning and drying Silanized porous glass beads are formed.
[0048] Wherein, the porous glass microspheres can be purchased directly from the market, or adopt the method disclosed in the patent literature of the application publication number CN110002725A, titled the preparation method of porous glass microspheres, the porous glass microspheres prepared by this method and its application. For preparation, the material is selected from a combination of common glass microsphere materials, including silica, alumina, zirconia, sodium silicate, etc., preferably, the particle size of porous glass microspheres is 50-70 μm, the pore size is 3-5 μm, and the density is preferably 0.7-0.8g...
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[0070] The preparation method is as follows in the embodiment:
[0071] 1) Prepare the porous glass microbead flame retardant unit, mix the porous glass microbead acidified according to the above method and the excess silane coupling agent KH550 solution in the reaction flask, use a small amount of triethylamine as the catalyst, and use acetonitrile as the reaction solvent , mechanically stirred and refluxed for 24h, after the reaction was stopped, suction filtered with acetonitrile, ethanol, deionized water, etc. and dried to form silanized porous glass beads;
[0072] The above-mentioned acid-treated montmorillonite has an ion-exchange capacity of 45mmol / 100g measured by titration, and the alkali-treated montmorillonite has an ion-exchange capacity of 54mmol / 100g. After mixing with BDP according to a mass ratio of 1:1:1, 80 Stir at ℃, and dry to obtain BDP modified acid-base treated montmorillonite.
[0073] The silanized porous glass beads are placed in a disc sealed with ...
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