A kind of highly elastic antibacterial eco-friendly dressing and preparation method thereof
A friendly and ecological technology, applied in filament/thread forming, bandage, fiber treatment, etc., can solve the problems of large stretching range, affecting ecological balance, high toxicity of microorganisms and aquatic organisms, and achieve the effect of stability
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Embodiment 1
[0027] A kind of high elastic antibacterial eco-friendly dressing and preparation method thereof, comprising the following steps:
[0028] 1. Wash and sun dry 5g of human nails, crush them, soak them in 20ml of liquid alkali solution with a mass concentration of 40% together with 0.35g of sodium sulfide at 90°C for 16h, filter them, and ultrafilter them with a molecular weight cut-off of 5000 to obtain a retentate. dry human nail keratin;
[0029] 2. Add 1 g of human nail keratin prepared in step 1, 12 g of zein, 4 g of polypyrrole with a conductivity of 30 S / cm, and 4 g of thermoplastic polyurethane elastomer with a glass transition temperature of 110 ° C into 100 ml of dimethyl ethyl acetate. In the amide, after fully stirring, the slurry is spray-dried to obtain the precursor powder;
[0030] 3. The precursor powder obtained in step 2 is heated and melted under a nitrogen atmosphere, and the temperature is 190° C., the voltage is 18kv, the distance is 18cm, and the injecti...
Embodiment 2
[0033] A kind of high elastic antibacterial eco-friendly dressing and preparation method thereof, comprising the following steps:
[0034] 1. Wash and sun dry 5g of human nails, crush them, soak them in 15ml of liquid alkali solution with a mass concentration of 40% together with 0.3g of sodium sulfide at 80°C for 12h, filter them, and use ultrafiltration with a molecular weight cut-off of 5000 to obtain a retentate. dry human nail keratin;
[0035] 2. Add 0.5 g of human nail keratin prepared in step 1, 10 g of zein, 3 g of polypyrrole with a conductivity of 10 S / cm, and 2 g of thermoplastic polyurethane elastomer with a glass transition temperature of 100 ° C into 100 ml of dimethyl In acetamide, after fully stirring, the slurry is spray-dried to obtain the precursor powder;
[0036] 3. The precursor powder obtained in step 2 is heated and melted under a nitrogen atmosphere, and the temperature is 180° C., the voltage is 15kv, the distance is 15cm, and the injection rate is ...
Embodiment 3
[0039] A kind of high elastic antibacterial eco-friendly dressing and preparation method thereof, comprising the following steps:
[0040] 1. Wash and sun dry 5g of human nails, crush them, soak them in 25ml of liquid alkali solution with a mass concentration of 40% together with 0.4g of sodium sulfide at 100°C for 18h, filter, and ultrafilter with a molecular weight cut-off of 5000 to obtain a retentate, spray dry human nail keratin;
[0041] 2. Add 2 g of human nail keratin prepared in step 1, 15 g of zein, 5 g of polypyrrole with a conductivity of 50 S / cm, and 5 g of thermoplastic polyurethane elastomer with a glass transition temperature of 125 ° C into 100 ml of dimethyl ethyl acetate. In the amide, after fully stirring, the slurry is spray-dried to obtain the precursor powder;
[0042] 3. The precursor powder obtained in step 2 is heated and melted under a nitrogen atmosphere, and the temperature is 200° C., the voltage is 20kv, the distance is 20cm, and the injection r...
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