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3D laser photosensitive printing solder resist ink for integrated circuit and preparation method thereof

An integrated circuit and photosensitive technology, which is applied in the field of 3D laser photosensitive printing solder resist ink and its preparation, can solve the problems of aggravated processing, foaming, abnormal edges of solder resist graphics, etc., and achieve the improvement of glass transition temperature, reduction of VOC content, Effect of improving solder resist performance

Active Publication Date: 2021-08-31
SHENZHEN SAPIENCE TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004]However, when the traditional solder resist green oil requires porous pad solder resist, there are many problems as follows: 1) The traditional solder resist green oil contains VOC solvents, which need to be used A large amount of liquid medicine is used for water treatment, and the high VOC content requires waste gas treatment, which is not environmentally friendly; 2) The traditional solder mask green oil can only use exposure and development technology, and there is insufficient development, so it is difficult to withstand the high temperature of reflow soldering (280-290 ℃ ), the tolerance to acid and alkali and various liquid medicines (such as isopropanol) is also poor, which will cause the pad position to be damaged by side erosion, and the solder mask will lift, bubble or fall off, resulting in resistance The edge of the solder pattern is abnormal, and it is difficult to guarantee the reliability in the production process; 3) The traditional solder mask green oil has no selectivity, and the places that need solder mask and those that do not need to be soldered will be exposed and developed, which not only wastes materials, but also aggravates the problem. Treatment where solder mask is required

Method used

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  • 3D laser photosensitive printing solder resist ink for integrated circuit and preparation method thereof
  • 3D laser photosensitive printing solder resist ink for integrated circuit and preparation method thereof
  • 3D laser photosensitive printing solder resist ink for integrated circuit and preparation method thereof

Examples

Experimental program
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Effect test

preparation example 1

[0037] Preparation examples 1-5 provide a maleic anhydride-modified polyimide photosensitive oligomer, and preparation example 1 is taken as an example below for illustration.

[0038] The maleic anhydride modified polyimide photosensitive oligomer that preparation example 1 provides, its preparation steps are:

[0039] (1) Mix 198g (0.8mol) diaminodiphenyl sulfone (CAS No. 80-08-0) and 40g (0.2mol) 4,4-diaminodiphenyl ether (CAS No. 101-80-4) Then add 10L of N-methylpyrrolidone, stir at 600rpm, add 229g (1.05mol) of pyromellitic anhydride under stirring, and react at 25°C for 3h to obtain reaction solution 1;

[0040] (2) Add dropwise 0.5mL isoquinoline and 2mL toluene to the reaction solution 1, N 2 Under the atmosphere, the temperature was raised to 160°C, and after the azeotrope of toluene and water was removed by distillation, the reaction was carried out at 160°C for 3 hours to obtain the reaction solution 2;

[0041] (3) Cool the reaction solution 2 to 50°C, add 9.8g ...

Embodiment 1

[0047] Embodiments 1-18 provide a 3D laser photosensitive printing solder resist ink for integrated circuits, which will be described below by taking Embodiment 1 as an example.

[0048] The preparation steps of the 3D laser photosensitive printing solder resist ink for integrated circuits provided in Example 1 are:

[0049] Mix 5g of ethyleneoxy acrylate and 10g of polycyclic acrylate, stir evenly at a stirring speed of 500rpm, then add 1g of sensitizer, mix, continue to stir evenly at a stirring speed of 500rpm, then add 20g of maleic anhydride to modify Polyimide photosensitive oligomer, stirred at a stirring speed of 800rpm to completely dissolve the maleic anhydride-modified polyimide photosensitive oligomer, then add 1g of photoinitiator, stir evenly, and finally add 0.1g of interface agent and 0.1g of fluorescent recognition agent, stirred evenly at a stirring speed of 500rpm, then allowed to stand for 30min, filtered with a 1 micron filter element, and the filtrate was...

Embodiment 2-5

[0057] Examples 2-5 are the same as Example 1, except that the quality of the raw materials used for the preparation of the 3D laser photosensitive printing solder resist ink for integrated circuits is different, see Table 2 for details.

[0058] Table 2 embodiment 1-5 prepares the quality of raw material

[0059]

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PUM

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Abstract

The invention relates to the technical field of integrated circuit printing, in particular to 3D laser photosensitive printing solder resist ink for an integrated circuit and a preparation method thereof. The 3D laser photosensitive printing solder resist ink for an integrated circuit is prepared from the following raw materials in parts by weight: 20-80 parts of a maleic anhydride modified polyimide photosensitive oligomer, 5-30 parts of vinyloxy acrylate, 10-60 parts of polycyclic acrylate, 0.1-1 part of a fluorescent recognition agent, 1-5 parts of a sensitizer, 1-5 parts of a photoinitiator and 0.1-1 part of an interface agent. The 3D laser photosensitive printing solder resist ink for an integrated circuit provided by the invention is good in solder resist performance and good in tolerance to acid, alkali and isopropanol, the solder resist ink has excellent adhesion fastness on a Cu substrate, and a solder resist ink coating film is relatively high in hardness and low in VOC (Volatile Organic Compounds) content.

Description

technical field [0001] The present application relates to the technical field of integrated circuit printing, in particular to a 3D laser photosensitive printing solder resist ink for integrated circuits and a preparation method thereof. Background technique [0002] Solder resist ink is an insulating material, which is printed on the circuit board to form a solder resist layer. The solder resist layer is formed by a permanent polymer solder resist coating material. The solder resist layer covers most of the printed circuits. The solder resist The layer provides permanent protection for the copper traces of the printed circuit board, and the solder mask layer can prevent the solder from bridging between the conductors, which can effectively prevent short circuits. [0003] The traditional solder mask green oil is a kind of acrylic oligomer, which is coated on the circuit and substrate of the printed circuit board that do not need to be soldered to prevent the physical discon...

Claims

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Application Information

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IPC IPC(8): C09D11/101C09D11/107C09D11/03B33Y70/10
CPCC09D11/101C09D11/107C09D11/03B33Y70/10
Inventor 王继宝周翠苹周子良
Owner SHENZHEN SAPIENCE TECH CO LTD
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