Application of biphenyl compound in resisting clinical drug-resistant fungi
A technology of compounds and fungi, applied in the direction of antifungal agents, active ingredients of hydroxyl compounds, plant/algae/fungus/moss components, etc., can solve the problem of being unable to curb the spread of drug-resistant fungi, and achieve the effect of great application potential
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Embodiment 1
[0029] Embodiment 1, the preparation of biphenyl compound
[0030] The preparation method of biphenyl compound is specifically as follows:
[0031] 1) Take 10kg of dried rowan suspension cells, extract by cold soaking with methanol at room temperature for 5 times, the amount of methanol is 20L / each time, the extraction time is 72h each time, combine the extracts, and decompress at 40°C and 0.08Mpa Concentrate the extract to obtain about 6 kg of extract;
[0032] 2) The obtained extract was dissolved in chloroform / methanol (1:1, v / v, 6L) and then adsorbed and mixed with 100-200 mesh silica gel (ca. Elution, followed by gradient washing with dichloromethane / methanol mixed solvent with a volume ratio of 100:0, 98:2, 95:5, 90:10, 80:20, 70:30, 50:50, 0:100 Take off, get 11 components, numbered as A 1 –A 11 ;
[0033] 3) The fifth component A 5 Further use normal phase silica gel column (filler is 100-200 mesh silica gel) to separate, the condition of separation is to adopt v...
Embodiment 2
[0039] Embodiment 2, antibacterial experiment
[0040] The compound shown in formula I obtained in Example 1 was used for MIC determination of a strain of clinical drug-resistant fungus, using the double dilution method, and the specific steps were as follows:
[0041] 1) Determination of MIC of clinical drug-resistant fungi: The obtained compound represented by formula I was prepared into a 10 mmol / mL stock solution with DMSO.
[0042]2) Prepare 500mL, 2×1640 medium, the specific operation is: take 10.4g RPMI Medium 1640powder (gibco, USA); 20g glucose (Shenggong, Shanghai); 34.53g MOPS (3-morpholinated propanesulfonic acid) dry powder (Shenggong, Shanghai); dissolve in 500mL distilled water; add 2.5g NaOH powder (Shenggong, Shanghai), and filter through a 0.22um membrane filter to sterilize. After filtration, it was stored at 4°C for use.
[0043] 3) Preparation of bacterial suspension: drug-resistant Candida glabrata (Candida glabrata) (preservation number: GDMCC NO: 6172...
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