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Low-temperature dyeing auxiliary agent of wool or cashmere reactive dye as well as preparation method and application of low-temperature dyeing auxiliary agent

A technology of low-temperature dyeing and reactive dyes, applied in the field of dyeing and finishing, which can solve the problems of poor dyeing levelness and color fastness, poor dyeing levelness, high equipment requirements, etc., achieve better color brightness and vividness, improve combing Spinning performance, the effect of lowering the dyeing temperature

Active Publication Date: 2021-10-01
XI'AN POLYTECHNIC UNIVERSITY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, low-temperature plasma technology has high requirements for equipment and high cost, and it is difficult to apply large-scale to the textile industry with relatively low added value of products; biological enzyme technology mainly uses enzymes to partially hydrolyze wool scales to reduce dye staining Fiber resistance, low temperature dyeing, biological enzymes damage the main structure of wool fiber, poor process controllability; urea method and thiourea method in the actual application process mainly have high urea usage, high cost, and production Low efficiency and other problems; in the actual application process of the formic acid method, there are mainly problems such as high formic acid consumption, large corrosion to equipment, large limitations of dyeing color, and poor dyeing levelness; glyoxal / hydrogen peroxide method in practice The main problem is that reducing agent and oxidizing agent are used at the same time, the production process is difficult to control, and the dyeing level and color fastness are not good; many problems in the above method limit its industrial application in actual production
The low-temperature dyeing auxiliaries method is a relatively systematic and mature technology at present, and has achieved certain results in the low-temperature dyeing research and application of wool mordant dyes and acid dyes, but the application of low-temperature dyeing auxiliaries method in the low-temperature dyeing of wool reactive dyes There are still few studies, mainly due to problems such as poor color fastness and unguaranteed dye exhaustion rate when dyeing dark colors. Although some low-temperature dyeing auxiliaries can increase the dye exhaustion rate by accelerating the dye uptake rate, it is easy to There is a problem of poor dyeing levelness

Method used

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  • Low-temperature dyeing auxiliary agent of wool or cashmere reactive dye as well as preparation method and application of low-temperature dyeing auxiliary agent
  • Low-temperature dyeing auxiliary agent of wool or cashmere reactive dye as well as preparation method and application of low-temperature dyeing auxiliary agent

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preparation example Construction

[0025] The invention provides a method for preparing a low-temperature dyeing auxiliary of wool or cashmere reactive dyes, the specific steps are as follows:

[0026] Step 1. Prepare cationic Pingpingjia O-10 solution, specifically follow the steps below:

[0027] Step 1.1, by mass percentage, weigh 17.0% of 3-chloro-2-hydroxypropyltrimethylammonium chloride (70% content), 3.0% of sodium hydroxide, 41.0% of Pingpingjia O-10, 0.5-1.0% organic acid, 38.0-38.5% water;

[0028] Step 1.2, mix the water weighed in step 1.1, 3-chloro-2-hydroxypropyltrimethylammonium chloride and sodium hydroxide in a stirring device, react at room temperature for 30-60min, remove hydrochloric acid, and obtain 2, 3-Epoxypropyltrimethylammonium chloride solution.

[0029] Step 1.3, add Pingpingjia O-10 to the 2,3-epoxypropyltrimethylammonium chloride solution obtained in step 1.2, raise the temperature to 80-95°C and keep it warm for 60-120 minutes, and add an appropriate amount of organic Adjust th...

Embodiment 1

[0044] Step 1. Prepare cationic Pingpingjia O-10 solution, specifically follow the steps below:

[0045] Step 1.1, in terms of mass percentage, 17.0% of 3-chloro-2-hydroxypropyltrimethylammonium chloride (70% content), 3.0% of sodium hydroxide and 38% of water are mixed in a stirring device , react at room temperature for 30 minutes, remove hydrochloric acid, and obtain 2,3-epoxypropyltrimethylammonium chloride solution.

[0046] Step 1.2: Add 41.0% Pingpinga O-10 into 2,3-epoxypropyltrimethylammonium chloride solution, raise the temperature to 80°C and keep it warm for 120 minutes, and add 1.0% organic acid to adjust the pH value to 6 ~8, to obtain a 50% cationic Pingpingjia O-10 solution.

[0047] Step 2. Add Pingpinga O-20 to the cationized Pingpinga O-10 solution obtained in step 1 and mix to prepare low-temperature dyeing auxiliaries. Specifically, follow the steps below:

[0048] Step 2.1. Weigh the following materials according to mass percentage: cationic Pingpingjia...

Embodiment 2

[0063] Step 1. Prepare cationic Pingpingjia O-10 solution, specifically follow the steps below:

[0064] Step 1.1, in terms of mass percentage, 17.0% of 3-chloro-2-hydroxypropyltrimethylammonium chloride (70% content), 3.0% of sodium hydroxide and 38% of water are mixed in a stirring device , react at room temperature for 45 minutes, remove hydrochloric acid, and obtain 2,3-epoxypropyltrimethylammonium chloride solution.

[0065] Step 1.2. Add 41% Pingpinga O-10 into the 2,3-epoxypropyltrimethylammonium chloride solution, raise the temperature to 90°C and keep it warm for 90 minutes, and add 1% organic acid to adjust the pH value to 6-8, to obtain a cationized Pingpingjia O-10 solution with a content of 50%.

[0066] Step 2. Add Pingpinga O-20 to the cationized Pingpinga O-10 solution obtained in step 1 and mix to prepare low-temperature dyeing auxiliaries. Specifically, follow the steps below:

[0067] Step 2.1. Weigh the following materials according to mass percentage: ca...

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Abstract

The invention discloses a low-temperature dyeing auxiliary agent of wool or cashmere reactive dye as well as a preparation method and application of the low-temperature dyeing auxiliary agent. The low-temperature dyeing auxiliary agent comprises the following raw materials by mass percentage of 20.0%-40.0% of a cationized peregal O-10 solution, 10.0%-20.0% of peregal O-20 and 40.0%-70.0% of water, and the sum of the content of the above components is 100% The invention further discloses a method for carrying out Lanasol reactive dye low-temperature dyeing on wool and cashmere fibers by adopting the low-temperature dyeing auxiliary agent, the low-temperature dyeing auxiliary has the functions of low-temperature dyeing acceleration, level dyeing and wetting permeability, the dyeing temperature is reduced, the dyeing damage of the fibers is reduced, the dyeing process of the wool and cashmere is simplified, and the combing and spinning performance of the dyed fiber and the quality of a dyed finished product are favorably improved.

Description

technical field [0001] The invention belongs to the technical field of dyeing and finishing, and in particular relates to a low-temperature dyeing auxiliary for wool or cashmere reactive dyes, a preparation method and application thereof. Background technique [0002] In the dyeing of wool and cashmere, reactive dyes for wool have been widely used in view of their bright color, excellent color fastness and convenient application. Due to the presence of a relatively dense scale layer on the surface of wool and cashmere fibers, it will hinder the adsorption and dyeing of dyes during the dyeing process. Therefore, the dyeing process of wool and cashmere fibers has always been dyed at high temperature. Most of the wool is dyed by boiling at 98°C, and the dyeing temperature of cashmere is generally 95°C. High-temperature dyeing not only consumes a lot of energy and costs, but also causes serious damage to wool and cashmere during long-term processing, such as reduced fiber stren...

Claims

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Application Information

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IPC IPC(8): D06P1/607D06P1/613D06P1/66D06P1/38D06P3/14
CPCD06P1/607D06P1/6133D06P1/38D06P3/148D06P1/0032Y02P70/62
Inventor 徐成书邢建伟欧阳磊王立任燕苏广召陆少锋
Owner XI'AN POLYTECHNIC UNIVERSITY
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