Release film for leather and preparation method thereof

A release film and leather technology, applied in the field of release film for leather and its preparation, can solve the problems of complex hierarchical structure of the release paper, affecting the smoothness of the texture, complicated production process, etc. Good, good surface scratch resistance

Pending Publication Date: 2021-10-22
瑞泰铸纸东莞有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Due to the limitation of the physical strength of the base paper, the traditional release paper for artificial leather is prone to tearing due to the decrease in strength after repeated use, and the base paper will shrink during the high temperature process and is prone to curling problems. After repeated use, it may The flatness of the texture is affected by the deformation of the base paper
[0003] At present, most release papers have complex hierarchical structures and their preparation methods are cumbersome. For example, Chinese patent CN107722323A proposes a release film for the production of synthetic leather cured by UV, which utilizes UV resin, leveling agent and photosensitizer The mixed embossed layer paint is coated on a 100-200 μm PET film, and the embossed layer paint is embossed and UV-irradiated in a semi-cured state at 85-95°C to obtain a patterned release film , but this technology is limited by the limited energy density and irradiation of ultraviolet rays, which limits the thickness of the UV-cured coating, so the release film cured by ultraviolet rays is only suitable for flat or polar lines, and an embossed layer is required in the production process The coating is in a semi-cured state, and the production process is complicated

Method used

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  • Release film for leather and preparation method thereof

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Effect test

preparation example Construction

[0028] A kind of preparation method of release film for leather provided by the invention, its preparation method comprises the following steps:

[0029] Step 1, prepare pre-coat paint;

[0030] Step 2, preparing a release layer coating;

[0031] Step 3, utilizing corona treatment to prepare the base material;

[0032] Step 4, coating the pre-coating paint on the base material, forming a pre-coating layer after curing, and obtaining a pre-coating base material;

[0033] In step 5, the release layer coating is embossed and cured on the pre-coated substrate to form a release layer by means of slit coating with the aid of electron beams, and the release film for leather is obtained.

[0034] It should be noted that the steps 1 to 3 do not have a strict preparation sequence, and the preparation sequence of the release layer material, precoat material and substrate can be set according to actual production needs.

[0035] Preferably, in the step 1, the pre-coat paint consists of...

Embodiment 1

[0058] Embodiment 1: a kind of release film for leather provided in this embodiment and preparation method thereof, its preparation method comprises the following steps:

[0059] Step 1, prepare the pre-coat paint: 45 parts of deionized water, 30 parts of water-based acrylic emulsion, 2 parts of surfactant, and 2 parts of defoamer are put into the container in order to mix and stir to obtain a uniform pre-coat coating;

[0060] Step 2, prepare the release layer coating: by weight, 30 parts of urethane acrylate, 70 parts of modified epoxy acrylate, 10 parts of tripropylene glycol diacrylate, 10 parts of ethoxylated Trimethylolpropane triacrylate, 2 parts perfluoromethacrylate, 2 parts γ-methacryloxypropyl trimethylsilane, 1 part light curing silicone release agent, 5 parts lightweight Calcium carbonate is put into the container successively and mixes, stirs, to impel the solid component to fully dissolve, obtains the uniform described release layer coating, and adopts vacuum p...

Embodiment 2

[0064] Embodiment 2: A kind of release film for leather provided in this embodiment and its preparation method, its preparation method comprises the following steps:

[0065] Step 1, prepare the pre-coat paint: 50 parts of deionized water, 35 parts of water-based acrylic emulsion, 2 parts of surfactant, and 2 parts of defoamer are put into the container in order to mix and stir to obtain a uniform pre-coat coating;

[0066] Step 2, prepare the release layer coating: by weight, 50 parts of urethane acrylate, 50 parts of modified epoxy acrylate, 10 parts of tripropylene glycol diacrylate, 10 parts of ethoxylated Trimethylolpropane triacrylate, 2 parts perfluoromethacrylate, 2 parts gamma-methacryloxypropyltrimethylsilane, 3 parts photocurable silicone release agent, 5 parts lightweight Calcium carbonate is put into the container successively and mixes, stirs, to impel the solid component to fully dissolve, obtains the uniform described release layer coating, and adopts vacuum p...

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Abstract

The invention discloses a preparation method of a release film for leather. The preparation method comprises the following steps: preparing a pre-coating coating; preparing a release layer coating; preparing a base material through corona treatment; coating the base material with a pre-coating layer paint, and curing to form a pre-coating layer to obtain a pre-coated base material; and embossing and curing the release layer coating on the pre-coated base material by adopting a slit coating mode assisted by electron beams to form a release layer, and obtaining the release film for leather. The invention further discloses the release film for leather. The release film for the leather comprises a three-layer structure, namely the release layer synthesized by aliphatic polyurethane propionic acid resin, the pre-coating layer of water-based acrylic emulsion and the base material subjected to corona treatment; embossing and curing are cured by adopting an electron beam assisted direct rolling mode, so that embossing and curing are carried out at the same time, and the problem that a traditional release film is poor in flatness and texture fidelity due to limitation of the physical strength of a base material is solved; and the obtained product has the advantages of being vivid in texture, high in repeated utilization rate and good in solvent resistance, surface scratch resistance and flatness.

Description

technical field [0001] The invention relates to the field of release film production, in particular to a release film for leather and a preparation method thereof. Background technique [0002] Due to the limitation of the physical strength of the base paper, the traditional release paper for artificial leather is prone to tearing due to the decrease in strength after repeated use, and the base paper will shrink during the high temperature process and is prone to curling problems. After repeated use, it may The flatness of the texture is affected by the deformation of the base paper. [0003] At present, most release papers have complex hierarchical structures and their preparation methods are cumbersome. For example, Chinese patent CN107722323A proposes a release film for the production of synthetic leather cured by UV, which utilizes UV resin, leveling agent and photosensitizer The mixed embossed layer paint is coated on a 100-200 μm PET film, and the embossed layer paint...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/04C08J7/12C09D163/10C09D175/14C09D133/00C08L67/02
CPCC08J7/042C08J7/12C09D163/10C09D133/00C08J2367/02C08J2475/14C08J2433/00C08L75/14
Inventor 张初强
Owner 瑞泰铸纸东莞有限公司
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