The invention provides a flame-retardant PP (polypropylene) composite material and a preparation method thereof. The flame-retardant PP composite material comprises components as follows: 55-65 partsof PP resin, 15-25 parts of wollastonite, 5-10 parts of magnesium-aluminum hydrotalcite, 1-3 parts of phosphomolybdic acid, 3-6 parts of modified nano-zinc oxide, 5-10 parts of silicon rubber, 1-3 parts of a titanate coupling agent, 5-10 parts of a flexibilizer, 0.2-0.8 parts of an antioxidant and 0.5-1.5 parts of polyethylene wax. The preparation method comprises steps as follows: 1), firstly, wollastonite, the silicon rubber, the titanate coupling agent, the PP resin accounting for 30%-40% of total mass and the flexibilizer accounting for 10%-20% of total mass are mixed uniformly, and masterbatches are prepared by an internal mixer; 2), the masterbatches obtained in step 1) are mixed with magnesium-aluminum hydrotalcite, phosphomolybdic acid, modified nano-zinc oxide, the antioxidant, polyethylene wax, the remaining flexibilizer and the remaining PP resin, and a mixture is subjected to melt mixing and dispersing at 210-240 DEG C in a twin-screw extruder and subjected to extruded granulation. The composite material has good hydrophobic property, friction resistance and flame retardant performance.