Method for identifying and detecting bacteria based on platform of functionalized magnetic nano material and gold nanocluster broad-spectrum probe
A gold nanocluster and magnetic nanotechnology, which can be used in the analysis of materials, material excitation analysis, material analysis by optical means, etc., and can solve problems such as limiting applications.
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[0035] Preparation of FcMBL@AuNC;
[0036] Biotinylation of FcMBL was as follows. First, FcMBL protein was incubated with PLP solution at pH 6.4 for 12 hours at room temperature. The PLP-treated protein was dialyzed 4 times against 50 mM sodium phosphate at 4°C. The resulting protein was incubated with aminobiotin for 12 hours. Following the previously reported procedure, AuNCs were synthesized with streptavidin with a small modification of glutathione (31 mM, 8 mL) and HAuCl 4The solution (25mM, 1mL) was mixed, and the pH was adjusted to 8.0±0.2 with NaOH solution (1M), and sodium borohydride (1mg / mL, 2mL) was added, and reacted at room temperature for 24h. The carboxyl groups on glutathione-modified AuNCs were covalently bound to the primary amines of streptavidin using EDC / NHS. Briefly, 20 mg AuNCs were washed three times with 10 mm PBS. EDC (10mg / mL, 100μL) and NHS (10mg / mL, 100μL) were used to activate glutathione-modified AuNCs carboxy-terminus for 30min, and strept...
Embodiment 1
[0038] Example 1 A method for identifying and detecting methicillin-resistant Staphylococcus aureus based on a platform of functionalized magnetic nanomaterials and gold nanoclusters with broad-spectrum probes , the description is to explain rather than limit the present invention. The method for identifying and detecting methicillin-resistant Staphylococcus aureus based on a platform of functionalized magnetic nanomaterials and gold nanocluster broad-spectrum probes of the present invention comprises the following steps:
[0039] 1. Different concentrations of methicillin-resistant Staphylococcus aureus (10 2 、10 3 、10 4 、10 5 、10 6 、10 7 、10 8 and 10 9 CFU / mL, 100μL) in a centrifuge tube;
[0040] 2. Mix different concentrations of methicillin-resistant Staphylococcus aureus with APT-MB (1.25 μM, 50 μL), and incubate at 37°C for 10 minutes to complete the specific recognition of bacteria;
[0041] 3. The enriched bacteria were washed three times in PBS solution with...
Embodiment 2
[0052] Example 2 A method for identifying and detecting carbapenem-resistant Klebsiella pneumoniae based on a platform of functionalized magnetic nanomaterials and gold nanoclusters with broad-spectrum probes
[0053] The method for identifying and detecting carbapenem-resistant Klebsiella pneumoniae based on a platform of functionalized magnetic nanomaterials and gold nanocluster broad-spectrum probes of the present invention comprises the following steps: 1. Carbapenem-resistant Klebsiella pneumoniae (10 2 、10 3 、10 4 、10 5 、10 6 、10 7 、10 8 and 10 9 CFU / mL, 100μL) in a centrifuge tube;
[0054] 2. Different concentrations of carbapenem-resistant Klebsiella pneumoniae solutions were mixed with APT-MB (1.25 μM, 50 μL), and incubated at 37°C for 10 minutes to complete the specific recognition of bacteria;
[0055] 3. The enriched bacteria were washed three times in PBS solution with pH 7 to remove non-target molecules in the system;
[0056] 4. Add FcMBL@AuNC (0.25mg / ...
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