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Electronic-grade low-dielectric glass fiber cloth treating agent and preparation method thereof

A glass fiber cloth and low-dielectric technology, which is applied in the field of electronic-grade low-dielectric glass fiber cloth treatment agent and its preparation, can solve problems affecting the electrical performance of electronic cloth, achieve enhanced heat resistance, small molecular weight, and strengthened bonding Effect

Pending Publication Date: 2022-01-11
TAISHAN FIBERGLASS ZOUCHENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, the coupling agent hydrolysis process involved in the above-mentioned patent belongs to the conventional hydrolysis method of the coupling agent, and the surface active agent is used to reduce the surface tension of the solution and reduce the problem of foaming during use. However, for low-dielectric glass fiber cloth, adding fluorine Carbon-based surfactants or hydrocarbon-based surfactants will adsorb salt ions and affect the electronic distribution performance

Method used

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  • Electronic-grade low-dielectric glass fiber cloth treating agent and preparation method thereof
  • Electronic-grade low-dielectric glass fiber cloth treating agent and preparation method thereof
  • Electronic-grade low-dielectric glass fiber cloth treating agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Prepare electronic-grade low-dielectric glass fiber cloth treatment agent according to the following raw material ratio: 1.0% vinyltriethoxysilane, 0.7% vinylbenzyltriethoxysilane, sodium salt of butadiene and maleic anhydride copolymer (The molar ratio of butadiene and maleic anhydride is 6:4, the molecular weight is 4000) 1.5%, methanol 0.15%, acetic acid 0.25%, and the balance is pure water.

[0041] The preparation method is as follows:

[0042] (1) Accurately weigh the raw materials according to the formula, add pure water to the preparation tank, and start stirring;

[0043] (2) Methanol and acetic acid are mixed evenly with a stirrer, and then added to the preparation tank;

[0044] (3) Add vinyltriethoxysilane and vinylbenzyltriethoxysilane into the preparation tank in sequence, and stir until the aqueous solution is clear and transparent;

[0045] (4) Add the sodium salt of butadiene and maleic anhydride copolymer into the preparation tank, stir evenly to obtai...

Embodiment 2

[0047] Prepare electronic-grade low-dielectric glass fiber cloth treatment agent according to the following raw material ratio: vinyl tris (β-methoxyethoxy) silane 0.65%, β- (vinylbenzyl) propyl triethoxy silane 0.3% , butadiene and maleic anhydride copolymer amine salt (butadiene and maleic anhydride molar ratio is 6:4, molecular weight 7000) 0.4%, methanol 0.10%, acetic acid 0.50%, the balance is pure water.

[0048] The preparation method is as follows:

[0049] (1) Accurately weigh the raw materials according to the formula, add pure water to the preparation tank, and start stirring;

[0050] (2) Methanol and acetic acid are mixed evenly with a stirrer, and then added to the preparation tank;

[0051] (3) Add vinyltris(β-methoxyethoxy)silane and β-(vinylbenzyl)propyltriethoxysilane into the preparation tank in sequence, and stir until the aqueous solution is clear and transparent;

[0052] (4) Add the amine salt of butadiene and maleic anhydride copolymer into the prepar...

Embodiment 3

[0054] Prepare electronic-grade low-dielectric glass fiber cloth treatment agent according to the following raw material ratio: vinyl triethoxysilane 0.6%, vinyl benzyl triethoxysilane 0.3%, dimethyl diallyl and maleic anhydride copolymer The sodium salt of the product (the molar ratio of dimethyl diallyl and maleic anhydride is 6:4, the molecular weight is 5500) is 0.8%, ethanol is 0.1%, acetic acid is 0.3%, and the balance is pure water.

[0055] The preparation method is as follows:

[0056] (1) Accurately weigh the raw materials according to the formula, add pure water to the preparation tank, and start stirring;

[0057] (2) after ethanol and acetic acid are mixed evenly with agitator, join in the preparation tank;

[0058] (3) Add vinyltriethoxysilane and vinylbenzyltriethoxysilane into the preparation tank in sequence, and stir until the aqueous solution is clear and transparent;

[0059] (4) Add the sodium salt of dimethyl diallyl and maleic anhydride copolymer into ...

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Abstract

The invention belongs to the technical field of glass fiber treating agents, and particularly relates to an electronic-grade low-dielectric glass fiber cloth treating agent and a preparation method thereof. The electronic-grade low-dielectric glass fiber cloth treating agent is prepared from the following raw materials in percentage by weight of 0.6 to 1.2 percent of a coupling agent A, 0.3 to 0.8 percent of a coupling agent B, 0.01 to 1.5 percent of a coupling agent aid, 0.1 to 0.5 percent of alcohol, 0.1 to 0.5 percent of acid and the balance of water; the coupling agent A is a coupling agent containing vinyl; the coupling agent B is a coupling agent containing vinyl benzyl; and the coupling agent aid is salt of a maleic anhydride grafted modified copolymer. According to the treating agent, on the basis of meeting the low dielectric property, the bonding property of glass fiber cloth and low dielectric resin is improved, and meanwhile, the mechanical property and the heat resistance of the low dielectric glass fiber cloth are enhanced.

Description

technical field [0001] The invention belongs to the technical field of glass fiber treatment agents, and in particular relates to an electronic-grade low-dielectric glass fiber cloth treatment agent and a preparation method thereof. Background technique [0002] With the rapid development of 5G technology, the requirements for PCB board materials in the field of high-frequency and high-speed applications are also getting higher and higher, which is bound to have higher requirements for electronic-grade glass fiber cloth treatment agents as one of the important constituent materials of CCL. At present, most boards are epoxy resin systems, and the requirements for dielectric constant and dielectric loss are not so high, but for some ultra-thin cloth IC packaging substrates, high-frequency and high-speed boards, etc., the existing treatment agent formula cannot meet the requirements. The performance requirements of the low-dielectric resin system match, so it is of great signif...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M13/513D06M15/227D06M13/144
CPCD06M13/5135D06M15/227D06M13/144D06M13/513C03C25/1095C03C25/26
Inventor 李伟肖华青张莹莹刘东锋李洲李冲付海波牛思齐
Owner TAISHAN FIBERGLASS ZOUCHENG
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