Supercharge Your Innovation With Domain-Expert AI Agents!

Ultralow-density polyurethane midsole or insole composite material containing recoverable waste particles and preparation method thereof

An ultra-low density, polyurethane technology, applied in the field of polyurethane, can solve the problems of mechanical properties to be improved, high molding defect rate, high cost, achieve the comprehensive advantages of excellent low density and high mechanical properties, reduce product density, adhesiveness Enhanced effect

Pending Publication Date: 2022-01-28
SHANDONG INOV POLYURETHANE
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Using recyclable waste particles as fillers for polyurethane midsoles or insoles, the main problems are the small filling amount of particles, high density, high molding defective rate, and poor mechanical properties.
Usually, if the recyclable particles account for more than 20% by weight of the product and the product density is lower than 300g / L, the molding defect rate and mechanical properties of the product will be severely attenuated, making it difficult to meet the actual use needs
CN112341588A discloses a low-density polyurethane midsole composition containing recyclable waste particles and a preparation method for the midsole, which mainly includes polyether ester polyol 1, polyester polyol 2, recyclable waste particles, and the content of waste particles is high and low Density and excellent mechanical properties, but the cost of raw materials is high, and the cost is too high to be economically feasible, and the content of waste and recyclable old particles is still low, and the mechanical properties still need to be improved

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Ultralow-density polyurethane midsole or insole composite material containing recoverable waste particles and preparation method thereof
  • Ultralow-density polyurethane midsole or insole composite material containing recoverable waste particles and preparation method thereof
  • Ultralow-density polyurethane midsole or insole composite material containing recoverable waste particles and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A component comprises the raw material of following mass percentage:

[0036]

[0037]

[0038] Component B includes the following raw materials in mass percentages:

[0039]

[0040] Other raw materials of component A that do not contain recyclable waste particles: Polyether polyol 1 uses ED-28 with a functionality of 2.0 and a molecular weight of 4000 (manufactured by Shandong Bluestar Dongda Chemical Co., Ltd.), and ethylene glycol , diethylene glycol, 1,4-butanediol and adipic acid through polycondensation reaction to obtain polyester polyol 2 with a number average molecular weight of 1800, the chain extender is ethylene glycol, and the crosslinking agent is diethanolamine. The foaming agent is B8905, the cell opening agent is IMR412T, the catalyst is a compound of Dabco XD104 and Dabco XD102 in a weight ratio of 1:1, and the foaming agent is water; put it into the reaction kettle in proportion at room temperature, and stir for 1 hour to get Other raw mate...

Embodiment 2

[0045] A component comprises the raw material of following mass percentage:

[0046]

[0047] Component B includes the following raw materials in mass percentages:

[0048]

[0049]Other raw materials of component A that do not contain recyclable waste particles: Polyether polyol 1 uses DL-3000D with a functionality of 2.0 and a molecular weight of 3000 (manufactured by Shandong Bluestar Dongda Chemical Co., Ltd.), and ethylene glycol 1. Diethylene glycol and adipic acid undergo polycondensation to obtain polyester polyol 2 with a number average molecular weight of 1500. The chain extender is ethylene glycol, the crosslinking agent is triethanolamine, the foam stabilizer is B8905, and the cell opener It is IMR412T, the catalyst is a compound of Dabco XD104 and Dabco XD102 according to the weight ratio of 1:2, and the foaming agent is water; it is put into the reaction kettle in proportion at room temperature, and after stirring for 2 hours, A that does not contain recycl...

Embodiment 3

[0054] A component comprises the raw material of following mass percentage:

[0055]

[0056] Component B includes the following raw materials in mass percentages:

[0057]

[0058] Other raw materials of component A that do not contain recyclable waste particles: polyether polyol 1 uses PPG6000 with a functionality of 2.0 and a molecular weight of 6000 (manufactured by Kumho Petrochemical Company of Korea), and ethylene glycol and diethylene glycol 1, 6-hexanediol and adipic acid undergo polycondensation reaction to obtain polyester polyol 2 with a number average molecular weight of 2000, the chain extender is ethylene glycol, the crosslinking agent is diethanolamine, and the foam stabilizer is B8905, The cell opener is IMR412T, the catalyst is a compound of Dabco XD104 and Dabco XD102 at a weight ratio of 2:1, and the foaming agent is water; put it into the reaction kettle in proportion at room temperature, and stir for 1 hour to obtain no recyclable waste Other raw m...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Particle sizeaaaaaaaaaa
Login to View More

Abstract

The invention belongs to the technical field of polyurethane, and particularly relates to a low-density polyurethane midsole composite material containing recoverable waste particles and a preparation method thereof. The composite material comprises a component A and a component B according to a mass ratio of 100: (35-45), the component A comprises 10-40% of polyether polyol 1, 60-90% of polyester polyol 2, 2-8% of a chain extender, 0.3-1.5% of a cross-linking agent, 0.3-2.0% of a foam stabilizer, 0.3-2.0% of a pore opening agent, 0.5-2.5% of a catalyst, 0.5-2.0% of a foaming agent and 10-232 of recoverable waste particles; and the component B comprises the following components in percentage by weight: 0-40% of polyether polyol 1, 10-40% of polyester polyol 3, 50-80% of isocyanate and 10ppm of a storage stabilizer. The midsole or insole prepared by the method is high in recoverable waste particle content, ultralow in density and excellent in mechanical property; meanwhile, the invention also provides the preparation method.

Description

technical field [0001] The invention belongs to the technical field of polyurethane, and specifically relates to a low-density polyurethane midsole composite material containing recyclable waste particles and a preparation method thereof. Background technique [0002] PU, EVA, PVC, PE, PP and other foamed plastic materials have been widely used due to their excellent performance, which has also led to the generation of a large amount of aging waste. Under the carbon neutral environmental protection policy of carbon peak, the above-mentioned The recycling of waste materials has become an urgent problem to be solved in recent years. The waste is crushed into fine flakes or granules as fillers by crushing, which not only recycles the waste, helps the relevant industrial chain to achieve low-carbon, circular, and sustainable development, but also effectively reduces the cost of the product. It is the current waste such as PU An important development direction of product recycli...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L75/06C08L75/08C08L27/06C08J9/08C08J9/00C08G18/66C08G18/48C08G18/42C08G18/32A43B13/04A43B17/14
CPCC08J9/08C08J9/0061C08G18/6622C08G18/4018C08G18/3206C08G18/3275A43B13/04A43B17/14C08J2375/06C08J2375/08C08J2427/06C08J2203/02Y02P20/584
Inventor 任明月甘经虎李海朝孟素青马健
Owner SHANDONG INOV POLYURETHANE
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More