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Super capacitor electrode material prepared by doping carbon material and preparation method thereof

A technology of supercapacitors and electrode materials, applied in the manufacture of hybrid capacitor electrodes and hybrid/electric double-layer capacitors, etc., can solve the problems of increased industrialization steps, different quality structures, unstable properties, etc. , to achieve the effect of guarantee and quality stability

Active Publication Date: 2022-02-18
WENZHOU UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The doping of atoms such as boron and sulfur can also play the same role, but, one: how to prepare carbon materials with high energy density has always been a problem we have to solve, and the other: the preparation of carbon materials by existing technologies The method is more extreme, or it is prepared by using natural materials or by a high-demand method. The former is unstable and has the risk of inconsistent quality and structure, and the latter has a very high finished product, which is only suitable for small batches in the laboratory. The preparation of doped carbon materials, especially the preparation of doped carbon materials, is itself doped with a variety of elements. In this process, a variety of impurities need to be removed, which will cause problems with raw materials and lead to a substantial increase in industrialization steps.

Method used

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  • Super capacitor electrode material prepared by doping carbon material and preparation method thereof
  • Super capacitor electrode material prepared by doping carbon material and preparation method thereof
  • Super capacitor electrode material prepared by doping carbon material and preparation method thereof

Examples

Experimental program
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Embodiment 1

[0050] Embodiment 1: Preparation of boron-doped carbon material C / B-700.

[0051] ① Weigh 0.2294 grams (0.00052mol) of organic ligand

[0052] 4-(2,4,6-tricarboxylphenyl)-2,2':6',2”-terpyridine was placed in a 100ml beaker, and then 12ml of DMF was poured into it, and the beaker containing the mixture was placed on a magnetic stirrer Stir at constant temperature until the organic ligand is completely dissolved (about 0.5 hours) to obtain solution A;

[0053] ②According to the ratio of metal to organic ligand molar ratio of 1:2, weigh 0.0774 g (0.00026 mol) of zinc nitrate hexahydrate, measure 10 ml of deionized water to dissolve it completely, and dissolve the dissolved zinc nitrate hexahydrate solution, all added (slowly added dropwise) to the organic mixed solution A, and continued stirring at constant temperature for 1 hour to obtain solution Ba; weigh an appropriate amount of doping material 0.09642g (0.00156mol) H 3 BO 3 Dissolve it with 5ml of deionized water, then ad...

Embodiment 2

[0057] Example 2: Preparation of phosphorus-doped carbon material C / P-700

[0058] ① Weigh 0.2294 grams (0.00052mol) of organic ligand

[0059] Put 4-(2,4,6-tricarboxylphenyl)-2,2':6',2”-terpyridine in a 100ml beaker, then pour 12ml of DMF into it, and place the beaker containing the mixture on a magnetic stirrer Stir at constant temperature until the organic ligand is completely dissolved (about 0.5 hours) to obtain solution A.

[0060] ②According to the ratio of metal to organic ligand molar ratio of 1:2, weigh 0.0774 g (0.00026 mol) of zinc nitrate hexahydrate, measure 10 ml of deionized water to dissolve it completely, and dissolve the dissolved zinc nitrate hexahydrate solution, all added (slowly added dropwise) to the organic mixed solution A, constant temperature and continued to stir for 1 hour, to obtain solution Ba; 4 ) 2 HPO 4 Dissolve it with 10ml of deionized water, then add it dropwise to solution Ba, and then continue to stir for 1h to obtain solution Bb;

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Abstract

The invention discloses a super capacitor electrode material prepared by doping a carbon material and a preparation method thereof. The preparation method comprises the following steps: (1) mixing DMF with an organic ligand through magnetic stirring to obtain a solution A; (2) adding a coordination metal dissolved in deionized water into the solution A to obtain a solution Ba, and then adding a doped material aqueous solution to obtain a solution Bb; (3) adding a KOH deionized water solution into the solution Bb to obtain a solution C, and evaporating to dryness to obtain a fixed initial product D; (4) calcining to obtain a product E; and (5) pickling and drying to obtain a target carbon material. The specific capacitance and the energy density of the two doped carbon materials C / B-700 and C / P-700 prepared by the invention are greatly improved, and both the C / B-700 and the C / P-700 have excellent super-electrical properties. The composite material has great value in the application of the super-electrode material, and has a great practical use and a commercial application value.

Description

technical field [0001] The invention relates to the technical field of electrode materials, in particular to a supercapacitor electrode material prepared by doping carbon materials and a preparation method. Background technique [0002] As a new type of clean energy storage device, supercapacitor occupies an important position in the field of electricity storage due to its advantages of fast charging and discharging speed, high safety performance, and long service life. Carbon materials have been the research focus of supercapacitor electrode materials because of their stable chemical properties, high electrical conductivity, and high specific surface area. However, carbon materials also have the disadvantages of small specific capacitance and low energy density, and carbon materials prepared from natural materials have unstable raw material sources and low reproducibility, while carbon-based materials with high performance (such as carbon fibers, Carbon nanotubes) are extr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/86H01G11/32
CPCH01G11/86H01G11/32Y02E60/13
Inventor 李新华尹三毛林希豪
Owner WENZHOU UNIVERSITY
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