Photocuring 3D printing silicon-based ceramic core and preparation method thereof

A 3D printing, ceramic core technology, applied in ceramic products, ceramic molding machines, cores, etc., can solve the problems of high core open porosity, poor process stability, difficult operation, etc., to improve the strength and open pores. The effect of increasing the open porosity and easy removal

Active Publication Date: 2022-02-25
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the main method is to control the degree of sintering between ceramic particles through the degreasing-sintering process, thereby controlling the strength and open porosity of the core; however, this method cannot ensure the strength of the core. High open porosity of the core
In addition, there is also a method of presetting the mandrel rod in the core, through which the coating around the mandrel rod is easily corroded, creating a gap between the mandrel and the ceramic, and enhancing the dissolution and loss of the ceramic core; however, this The process of this method is complex, the process stability is poor, and the operation is difficult

Method used

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  • Photocuring 3D printing silicon-based ceramic core and preparation method thereof
  • Photocuring 3D printing silicon-based ceramic core and preparation method thereof

Examples

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preparation example Construction

[0052] Such as figure 1 As shown, the embodiment of the present invention provides a method for preparing a light-cured 3D printing silicon-based ceramic core, which mainly includes the following steps:

[0053] Step 1) Prepare photocurable 3D printing ceramic core slurry; wherein, in parts by weight, the photocurable 3D printing ceramic core slurry includes: 30-50 parts by weight of silica skeleton powder, 20-50 parts by weight Parts by weight of filler, 10-15 parts by weight of a through-hole agent, and 15-30 parts by weight of a photocurable resin premix; wherein, the through-hole agent is an organic fiber coated with organosiloxane.

[0054] In this step: in the embodiment of the present invention, 10-15 parts by weight of a through-hole agent is added to the photocured 3D printing ceramic core slurry, and the through-hole agent is an organosiloxane-coated organic fiber; here, On the one hand, the organic fibers in the organosiloxane-coated organic fibers will be oxidized...

Embodiment 1

[0071] This example prepares a light-cured 3D printing silicon-based ceramic core, wherein the raw materials and mass fractions used in this example are: 30 parts by weight of silica skeleton powder, 35 parts by weight of filler, and 10 parts by weight of through-hole agent. parts by weight, 10 parts by weight of the pore-forming agent, and 15 parts by weight of the photocurable resin premix (the volume ratio of the photosensitive resin to the second diluent is 12:3). Among them, the silica skeleton powder is SiO with a particle size of 80 μm 2 Powder, the filler is Al with a particle size of 80nm 2 o 3 Powder and ZrO with a particle size of 20nm 2 powder (among them, Al 2 o 3 Powder and ZrO 2 The mass ratio of powder is 1:3). The through-hole agent is selected from organosiloxane-coated organic fibers with a length of 1 mm and a diameter of 10 μm. The pore forming agent is silicone fiber. The photosensitive resin is methacrylate and urethane acrylate with a volume rat...

Embodiment 2

[0083] This example prepares a light-cured 3D printing silicon-based ceramic core, wherein the raw materials and mass fractions used in this example are: 40 parts by weight of silica skeleton powder, 20 parts by weight of filler, and 10 parts by weight of through-hole agent. parts by weight, 10 parts by weight of the pore-forming agent, and 20 parts by weight of the photocurable resin premix (the volume ratio of the photosensitive resin to the second diluent is 16:4). Among them, the silica skeleton powder is SiO with a particle size of 100 μm 2 Powder, the filler is Na with a particle size of 50nm 2 O powder and K with a particle size of 30nm 2 O powder (and Na 2 O powder and K 2 The mass ratio of O powder is 2:1). The through-hole agent is selected from organosiloxane-coated organic fibers with a length of 15 mm and a diameter of 20 μm. The pore forming agent is silicone fiber. The photosensitive resin is polyurethane acrylate, and the second diluent is 1,6-hexanediol ...

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Abstract

The invention relates to a photocuring 3D printing silicon-based ceramic core and a preparation method thereof, and relates to the field of additive manufacturing ceramic materials. According to the main technical scheme, the preparation method of the photocuring 3D printing silicon-based ceramic core comprises the following steps: 1) preparing photocuring 3D printing ceramic core slurry; wherein the light-cured 3D printing ceramic core slurry is prepared from the following components in parts by weight: 30 to 50 parts of silicon dioxide skeleton powder, 20 to 50 parts of filler, 10 to 15 parts of through hole agent and 15 to 30 parts of light-cured resin premixed liquid, the through hole agent is formed by coating organic fibers with organic siloxane; 2) performing photocuring 3D printing treatment on the photocuring 3D printing ceramic slurry through photocuring 3D printing equipment to obtain a silicon-based ceramic core biscuit; and 3) degreasing and sintering the silicon-based ceramic core biscuit to obtain the photocuring 3D printing silicon-based ceramic core. The method is mainly used for improving the open porosity of the silicon-based ceramic core on the basis of ensuring that the silicon-based ceramic core has relatively high strength.

Description

technical field [0001] The invention relates to the technical field of additively manufactured ceramic materials, in particular to a light-cured 3D printing silicon-based ceramic core and a preparation method thereof. Background technique [0002] With the development of turbine blades, the preparation process of ceramic cores is also developing, and the emergence of high-efficiency air-cooled hollow blades makes the preparation of ceramic cores a key technology. As the internal cooling channels of hollow air-cooled blades become more and more complex, the wall thickness of the blades becomes thinner, the structure of the ceramic core is more complex, and the dimensional accuracy of the core is required to be higher, this poses a huge challenge to the preparation technology of the ceramic core. challenge. [0003] The preparation process of the traditional ceramic core requires a large number of molds, which makes the preparation cost high, the cycle time is long, the proce...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/14C04B35/622C04B38/06B28B1/00B22C9/10B22C9/12B33Y10/00B33Y40/20B33Y70/10
CPCC04B35/14C04B35/622C04B38/067B28B1/001B22C9/10B22C9/12B33Y10/00B33Y40/20B33Y70/10C04B2235/96C04B2235/5212C04B2235/483C04B2235/6562C04B2235/6565C04B2235/6567C04B2235/3217C04B2235/3244C04B2235/3201C04B2235/5454C04B38/0074Y02P10/25
Inventor 李金国李乔磊梁静静周亦胄孙晓峰
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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