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Superfine composite vanadium-titanium antirust coating and preparation method thereof

An anti-rust coating, vanadium-titanium technology, applied in anti-corrosion coatings, polyester coatings, coatings, etc., can solve the problems of low price, high irritation and toxicity, no anti-rust performance, etc., and achieve excellent comprehensive performance and stable storage Good performance, good anti-flash rust performance

Pending Publication Date: 2022-03-04
攀枝花荣鑫油漆有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The types of anti-rust coatings mainly include inorganic zinc-rich primers, polyurethane coatings, alkyd resin anti-rust coatings, etc. The zinc-rich coatings made of zinc-rich coatings have high zinc content, which increases the preparation cost; polyurethane coatings are made of polyurethane resin as the base material and pigments, fillers, etc. as auxiliary materials, and are more adaptable to various construction environments and objects. Strong, can be cured at low temperature, can be applied in a humid environment and on a wet substrate, and has outstanding oil resistance, but it has greater irritation and toxicity; the alkyd resin in the alkyd resin antirust coating itself has no Anti-rust performance, but the price is low. The preparation of anti-rust coatings mainly depends on anti-rust pigments, such as red lead, iron red, zinc phosphate, etc., but the performance is difficult to meet the general atmospheric anti-rust requirements. Among them, alkyd red moon anti-rust Rust paint is highly toxic, environmental protection, and construction methods are greatly restricted
[0004] With the progress of industrialization and social progress, people have higher and higher requirements for anti-rust coatings. The existing water-based anti-rust coatings dry slowly and have general salt water resistance; although acrylic emulsion coatings have good weather resistance, Water resistance and chemical resistance, but it is easy to cause hot sticking and cold brittleness, anti-sticking property and poor heat resistance. The shortcomings of the above two coatings make the coating not achieve the corresponding effect and cannot meet the needs of specific customers. create a void in the market

Method used

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  • Superfine composite vanadium-titanium antirust coating and preparation method thereof
  • Superfine composite vanadium-titanium antirust coating and preparation method thereof
  • Superfine composite vanadium-titanium antirust coating and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0027] Embodiment 1 The preparation of superfine composite vanadium-titanium antirust powder antirust powder

[0028] Prepare anti-rust powder according to the following formula: TiO 2 20-24%, CaO 25-28.5%, SiO 2 22.5~26.1%, Al 2 o 3 10.5~13.%, MgO 6~7%, V 2 o 5 0.1~0.18%, the remaining content is Fe 2 o 3 .

[0029] After mixing the above components, grind them into superfine composite vanadium-titanium antirust powder with a particle size D50 of 2.0 μm to 3.0 μm ( figure 1 ), the color is similar to cement gray, and the pH value of its aqueous solution is 7-9.

Embodiment 2

[0030] The preparation of embodiment 2 acrylic paints

[0031] Take 100 parts of the superfine composite vanadium-titanium antirust powder prepared in Example 1, 300 parts of acrylic emulsion, 20 parts of modified acrylic resin, 10 parts of dispersant styrene-butadiene copolymer, and 343 parts of water into the dispersion tank , stirred at a speed of 300r / min, added 5 parts of neutralizer, 80 parts of titanium dioxide, 100 parts of barium sulfate, 20 parts of toner, stirred at 1000r / min for 25 minutes, and ground 2 to 3 times with a sand mill until fine It is qualified if the density is less than 50 microns; finally, under the condition of stirring at 500r / min, add 20 parts of film-forming aid and 2 parts of drier, and continue stirring for 40 minutes.

Embodiment 3

[0032] The preparation of embodiment 3 alkyd paint

[0033] Get 100 parts of superfine composite vanadium-titanium antirust powders prepared in Example 1 and 280 parts of phthalic anhydride, 70 parts of maleic anhydride, 20 parts of dispersant, 325 parts of water and mix and add in the dispersing tank, with 300r Stir at a speed of 1000r / min, add 5 parts of neutralizer, 80 parts of titanium dioxide, 100 parts of barium sulfate, and 20 parts of toner, stir at a speed of 1000r / min for 25 minutes, and grind 2 to 3 times with a sand mill until fine The degree is less than 50 microns is qualified; finally, under the condition of stirring at 500r / min, add 10 parts of drier and continue stirring for 40 minutes.

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Abstract

The invention provides a superfine composite vanadium-titanium antirust coating and a preparation method thereof. The superfine composite vanadium-titanium antirust coating is prepared from the following components in parts by weight: 20-400 parts of water-based emulsion and / or water-based resin, 0-40 parts of a dispersing agent, 0.5-10 parts of a drier, 2-10 parts of a neutralizer, 5-15 parts of an additive, 80-300 parts of filler, 80-400 parts of antirust powder, 10-30 parts of toner and 300-400 parts of a solvent. The superfine composite vanadium-titanium antirust coating has good flash rust resistance, has a good corrosion inhibition effect, can assist in improving the later salt spray resistance, has good adhesion, pencil hardness, water resistance, paint film flexibility, storage stability and the like, is short in surface drying time and hard drying time, and improves the construction efficiency; the raw material cost is low.

Description

technical field [0001] The invention relates to the technical field of antirust products, in particular to an ultrafine composite vanadium-titanium antirust coating and a preparation method thereof. Background technique [0002] Oil stains and bacteria on the surface of metal products will accelerate the corrosion of metal. According to statistics, the annual economic loss caused by metal corrosion in the world is as high as 700 billion U.S. dollars, which is higher than the losses caused by any kind of natural disaster. coated or impregnated with anti-rust paint. In 2002, the total output of China's antirust coatings was 530,000 tons, of which industrial antirust coatings produced 250,000 tons, with sales of 5 billion yuan; ship coatings produced 160,000 tons, with sales of 3 billion yuan; container coatings were 120,000 tons, with sales 2.2 billion. [0003] Traditional water-based coatings have low hardness, poor salt spray resistance and aging resistance of the paint f...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/00C09D167/08C09D5/08C09D7/61
CPCC09D133/00C09D167/08C09D5/08C09D7/61C08K2003/2241C08K2003/2206C08K2003/2227C08K2003/3045C08L2205/025C08L33/00C08K3/22C08K3/30C08K3/36
Inventor 何平那萨种瑞兴
Owner 攀枝花荣鑫油漆有限责任公司