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Method for preparing Al-Zn-Mg-Cu series aluminum alloy part by adopting powder metallurgy method

A technology of powder metallurgy and aluminum alloy, which is applied in the field of metal parts prepared by powder metallurgy, can solve the problems of difficult size and distribution control, less research on process parameters, and low mechanical properties of powder metallurgy aluminum alloys, so as to achieve easy adjustment, cost reduction effect

Pending Publication Date: 2022-03-08
UNIV OF SCI & TECH BEIJING
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  • Description
  • Claims
  • Application Information

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Problems solved by technology

The invention is characterized by the following two aspects: First, the composition range of the aluminum alloy disclosed in the invention is too wide, Cu, Mg, Si, Zn and other elements far exceed their solid solubility in aluminum, so the alloy material after sintering The interior must contain a large amount of Al with a large size 2 Cu, MgZn 2 And elemental silicon and other brittle phases, these phases cannot be eliminated by solid solution treatment, it is difficult to control the size and distribution of these coarse second phases, thus affecting the mechanical properties of the material, but can increase the wear resistance of the material; secondly, the The composition of the invention contains 0% to 10% of SiC and Al 2 o 3 , graphite and other reinforcement phases, the existence of these reinforcement phases can improve the wear resistance of the material, but due to the wide variety of reinforcement phases, the problem of interfacial bonding of the reinforcement phases cannot be solved, so the mechanical properties must not be high
[0005] In summary, the mechanical properties of powder metallurgy aluminum alloys are generally not high at present, and there are still the following main difficulties in the preparation of Al-Zn-Mg-Cu high-strength aluminum alloys by powder metallurgy: ① lack of Al-Zn-Mg that meets the sintering characteristics -Cu-based aluminum alloy composition, difficult to sinter and densify
The existing powder metallurgy Al-Zn-Mg-Cu alloys are all based on the standard composition of wrought aluminum alloys, and there is no Al-Zn-Mg-Cu alloy composition suitable for the pressing-sintering process; Dense oxide film, which will hinder the diffusion and densification process of atoms between powders during sintering, so it cannot be prepared completely according to the traditional 7-series aluminum alloy composition, and it is necessary to design an Al-Zn-Mg-Cu alloy that can be sintered and densified Element
②Different from traditional casting and forging aluminum alloys prepared by smelting process, powder metallurgy aluminum alloys rely on the instantaneous liquid phase formed during sintering, so it is necessary to strictly control the content of alloying elements in aluminum alloys; ③About powder metallurgy Al-Zn-Mg There are few studies on the process parameters of -Cu alloys, such as the influence of particle gradation, pressing pressure and sintering process on the densification of materials, etc.

Method used

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  • Method for preparing Al-Zn-Mg-Cu series aluminum alloy part by adopting powder metallurgy method
  • Method for preparing Al-Zn-Mg-Cu series aluminum alloy part by adopting powder metallurgy method
  • Method for preparing Al-Zn-Mg-Cu series aluminum alloy part by adopting powder metallurgy method

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Effect test

Embodiment 1

[0025] Example 1: Composition optimization of powder metallurgy Al-Zn-Mg-Cu based aluminum alloy system

[0026] a. Through the calculation of Thermo-Calc software, the relationship diagram between the liquid phase amount of Al-Zn-Mg-Cu aluminum alloy and the content of alloying elements is obtained;

[0027] b. Select the Al-Zn-Mg-Cu alloy composition on different liquidus lines; according to the selected alloy composition, the raw material powder used is prepared according to the element mass ratio, and the mass fraction is 1.5% of ethylene bishard Fatty amide is used as a lubricant, and then mixed on a mixer at 120r / min for 4 hours to obtain a uniformly mixed powder;

[0028] c. pressing the powder obtained in step a under a pressing pressure of 300 MPa to obtain a circular green body with a diameter of 25 mm;

[0029] d. Sinter the formed green body obtained in step b under a nitrogen atmosphere. The specific process parameters are: 10°C min -1 The heating rate is raised...

Embodiment 2

[0032] Embodiment 2: The particle size optimization of the Al-50Zn powder that is used for powder metallurgy Al-Zn-Mg-Cu series aluminum alloy, concrete steps are as follows:

[0033] a. Select Al-50Zn powder with three different particle sizes of 100, 200 and 300 mesh, and prepare the raw material powder according to the mass ratio of Al: Zn-Mg-Cu-Sn elements of 89:5:2.3:1.1:0.2, Adding mass fraction of 1.5% ethylene bis stearamide as a lubricant, then mixing on a mixer at 120r / min for 4h to obtain a uniformly mixed powder;

[0034] b. the powder obtained in step a is pressed under a pressing pressure of 300MPa to obtain a circular green body with a diameter of 25mm;

[0035] c. Sinter the formed green body obtained in step b under a nitrogen atmosphere. The specific process parameters are: 10°C min -1 The heating rate is raised from room temperature to 460°C and kept for 40min, at 10°Cmin -1 The heating rate is increased to 560°C and kept for 30min, at 10°Cmin -1 The heat...

Embodiment 3

[0038] Example 3: The impact of pressing pressure on the sintering and densification of Al-Zn-Mg-Cu aluminum alloys, the specific steps are as follows:

[0039] a. Prepare the raw material powder according to the mass ratio of Zn-Mg-Cu-Sn elements 89:5:2.3:1.1:0.2, add 1.5% ethylene bisstearamide as lubricant, and then After mixing on the mixer at 120r / min for 4 hours, a uniformly mixed powder was obtained;

[0040] b. pressing the powder obtained in step a under a pressing pressure of 100-500 MPa respectively to obtain a circular green body with a diameter of 25 mm;

[0041] c. Sinter the formed green body obtained in step b under a nitrogen atmosphere. The specific process parameters are: 10°C min -1 The heating rate is raised from room temperature to 460°C and kept for 40min, at 10°Cmin -1 The heating rate is increased to 560°C and kept for 30min, at 10°Cmin -1 The heating rate is raised to 610°C and kept for 60min, at 2°Cmin -1 After cooling to 200°C, furnace cooling; ...

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Abstract

The invention relates to a method for preparing Al-Zn-Mg-Cu series aluminum alloy parts through a powder metallurgy method, and belongs to the technical field of aluminum alloy parts prepared through the powder metallurgy method. The preparation method comprises the following steps: uniformly mixing pure Al powder and four kinds of alloy element powder or binary alloy powder of Mg, Zn, Cu and Sn according to a certain proportion, and carrying out pressing forming, sintering and heat treatment to obtain the aluminum alloy part. The Al-Zn-Mg-Cu series aluminum alloy system suitable for the pressing-sintering process is designed, the process for preparing the Al-Zn-Mg-Cu series aluminum alloy through the powder metallurgy method is optimized by controlling grain composition, pressing pressure, sintering process parameters and the like, the production efficiency is improved, and the production cost is reduced. The compactness of the Al-Zn-Mg-Cu series aluminum alloy material prepared through the method is higher than 98%, and the tensile strength of the Al-Zn-Mg-Cu series aluminum alloy material is larger than 470

Description

technical field [0001] The invention relates to a method for preparing Al-Zn-Mg-Cu aluminum alloy parts by powder metallurgy, and belongs to the technical field of metal parts prepared by powder metallurgy. Background technique [0002] In recent years, with the gradual miniaturization and lightweight development of automobiles, 3C products, 5G communications, wearable devices, and industrial robots, the demand for lightweight, high-strength, small and complex-shaped structural parts is increasing. The use of high-strength aluminum Replacing traditional iron-based materials with alloys is an important way to achieve lightweight. The preparation of small and complex aluminum alloy parts by means of machining, casting and 3D printing has problems such as high cost and unfavorable mass production. The powder metallurgy process has unique advantages in the preparation of small complex shape parts. [0003] Regarding the research on powder metallurgy aluminum alloys, the curren...

Claims

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Application Information

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IPC IPC(8): C22C21/10C22C1/04C22F1/053
CPCC22C21/10C22C1/0416C22F1/053
Inventor 吴茂徐钊李云莉曲选辉
Owner UNIV OF SCI & TECH BEIJING
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