System and method for treating polymer-containing and glue-containing wastewater through plasma combination

A plasma and wastewater technology, which is applied in mining wastewater treatment, chemical instruments and methods, multi-stage water/sewage treatment, etc., can solve problems such as difficult effective penetration, poor mud-water separation effect in subsequent processes, and large dosage of chemicals. , to achieve the effect of improving destabilization efficiency, strengthening pollutant degradation and gel breaking ability, and reducing wastewater viscosity

Pending Publication Date: 2022-04-22
CNOOC TIANJIN CHEM RES & DESIGN INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] There are many types of pollutants in polymer-containing and colloid-containing wastewater, with complex components and certain salts. This type of wastewater forms a stable heterogeneous thermodynamically stable system. At present, it is mainly treated by traditional gel-breaking combined treatment processes, including coagulation and sedimentation, Chemical oxidation method, Fenton oxidation method, etc., but the traditional gel breaking and destabilizing treatment process generally faces the following problems: ①The dosage of chemicals is large, and the gel breaking and destabilizing effect is poor: this type of wastewater contains a large amount of chemical agents and inorganic salts , the dispersion system formed is more stable, and the dosage of demulsification and gel breaking agents is doubled, some even as high as thousands of milliliters; It is difficult for the agent to penetrate and destroy effectively, and its oxidation and gel breaking generally take more than 30 minutes, or even several hours, which leads to a large area of ​​reaction equipment and increases the investment cost of equipment; In the face of process parameter adjustment, the effluent water quality fluctuates greatly; ④The wastewater treatment process is easily affected by the external environment, such as ambient temperature, which results in poor mud-water separation in the subsequent process and affects the water quality of the effluent

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  • System and method for treating polymer-containing and glue-containing wastewater through plasma combination

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Embodiment 1

[0032] A large amount of fracturing flowback fluid and production water are produced during the exploitation of a certain coalbed methane in Shanxi Province. The wastewater contains a large amount of polymers and colloids, and has a high salinity. With the increase of gas production, the volume of production water and fracturing flowback fluid is getting higher and higher, and the volume and quality of wastewater fluctuate greatly. The existing treatment process and effluent water quality are facing great challenges. In order to meet the production needs, it is planned to upgrade the existing process to improve the processing efficiency.

[0033] Adopt the plasma combined process of the present invention to carry out 480m to this polymer-containing glue-containing wastewater 3 / d engineering application, the average mass concentration of COD in wastewater is 2285mg / L, the average mass concentration of SS is 3430mg / L, the average mass concentration of oil content is 42mg / L, the...

Embodiment 2

[0035] An oil production terminal in Qinghai Province adopts a combined process of coagulation sedimentation + air flotation + precision filtration to treat oily production water. With the in-depth development of the oil field and the optimization of the production process, the produced water contains a large amount of polymers, colloids and inorganic salts. There is a large amount of dosing in the treatment process, frequent clogging of the precision filter unit, unstable operation of the treatment process and frequent load shocks to the system, large fluctuations in effluent quality, and greater pressure on environmental protection for enterprises.

[0036] The 1 m of the polymer-containing glue-containing production wastewater was carried out by adopting the plasma combined process of the present invention 3 / h pilot test, the average mass concentration of wastewater COD is 1532mg / L, NH 4 + - The average mass concentration of N is 68mg / L, the average mass concentration of ...

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Abstract

The invention discloses a system and a method for treating polymer-containing and glue-containing wastewater through plasma combination. The system comprises a buffer pool (1), a lifting pump (2), a plasma destabilization device (3), a high-voltage pulse power supply (4), an air compressor (5), an induced draft fan (6), an electro-Fenton reactor (7), a low-voltage direct-current power supply (8), a membrane separation unit (9) and a reflux pump (10). According to the method, the polymer-containing and glue-containing wastewater sequentially enters a plasma destabilization device (3), an electro-Fenton reactor (7) and a membrane separation unit (9) to be subjected to destabilization, pollutant degradation and solid-liquid separation treatment, and finally, the reinjection or reuse requirements are met. And the high-voltage pulse power supply (4) and the low-voltage direct-current power supply (8) respectively provide loading power for the plasma destabilization device (3) and the electro-Fenton reactor (7).

Description

technical field [0001] The invention belongs to the field of environmental engineering wastewater treatment, and relates to a wastewater treatment technology, in particular to a plasma combined treatment system and method for polymer- and gel-containing wastewater. Background technique [0002] Most of my country's oil fields have entered the middle and later stages of development, and various measures need to be taken for production wells, such as fracturing and acidification, polymer flooding, etc., to increase the output of oil and gas fields, and changes in the quality of crude oil have resulted in a large amount of wastewater containing polymers and gums downstream On the other hand, in order to ensure national energy security, my country has increased the exploitation of unconventional energy such as shale gas and coalbed methane at the same time, and this type of energy exploitation process will also inevitably produce a large amount of polymer-containing and rubber-con...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/08C02F103/10C02F101/30
CPCC02F9/00C02F2103/10C02F1/463C02F1/305C02F1/725C02F1/32C02F1/722C02F2305/026C02F1/44C02F2101/30
Inventor 钱光磊谢陈鑫滕厚开赵慧雷太平任春燕张程蕾周立山李旗陆彩霞
Owner CNOOC TIANJIN CHEM RES & DESIGN INST
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