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High-strength tear-resistant conductive hydrogel suitable for friction nano-generator and preparation and application of high-strength tear-resistant conductive hydrogel

A conductive hydrogel and nanogenerator technology, applied in the direction of triboelectric generators, can solve the problems of short service life and poor mechanical properties, and achieve the effects of enhancing mechanical properties, prolonging service life, and avoiding damage.

Pending Publication Date: 2022-05-10
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] In fact, the poor mechanical properties of hydrogel materials are the main reason for the short physical lifetime of hydrogel-based triboelectric nanogenerators.

Method used

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  • High-strength tear-resistant conductive hydrogel suitable for friction nano-generator and preparation and application of high-strength tear-resistant conductive hydrogel
  • High-strength tear-resistant conductive hydrogel suitable for friction nano-generator and preparation and application of high-strength tear-resistant conductive hydrogel
  • High-strength tear-resistant conductive hydrogel suitable for friction nano-generator and preparation and application of high-strength tear-resistant conductive hydrogel

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Experimental program
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Effect test

Embodiment 1

[0048] Add 0.3g soluble starch to 3.7mL dimethyl sulfoxide, add 1mL hydroxyethyl methacrylate, 0.033g ammonium persulfate, 0.050g N,N'-methylenebisacrylcystamine, 50μN,N, N',N'-tetramethylethylenediamine, stir until completely dissolved, and obtain a uniform and transparent gel prepolymerization solution. The prepolymerization solution was injected into a pair of glass sheets containing silica gel molds, and the organic oil gel was obtained by reacting at room temperature for 24 h. The organogel was placed in a 1M sodium citrate solution for solvent replacement to obtain a high-strength tear-resistant conductive hydrogel.

[0049] like figure 1 As shown, after freeze-drying treatment of the high-strength tear-resistant conductive hydrogel sample of this embodiment, the scanning electron microscope image of the sample has a dense polymer network and uniform pore size distribution.

[0050] figure 2 Shown is the tensile curve of the high-strength tear-resistant conductive hy...

Embodiment 2

[0053] Add 0.4g soluble starch to 3.6mL dimethyl sulfoxide, add 1mL hydroxyethyl methacrylate, 0.033g ammonium persulfate, 0.050g N,N'-methylenebisacrylcystamine, 50μN,N, N',N'-tetramethylethylenediamine, stir until completely dissolved, and obtain a uniform and transparent gel prepolymerization solution. The prepolymerization solution was injected into a pair of glass sheets containing silica gel molds, and the organic oil gel was obtained by reacting at room temperature for 24 h. The organogel was placed in a 1M sodium citrate solution for solvent replacement to obtain a high-strength tear-resistant conductive hydrogel. The obtained gel had a tensile modulus of 0.67 MPa, a compressive modulus of 0.95 MPa, and an ionic conductivity of 5.53 mS / cm.

[0054] like Figure 5 As shown, the high-strength tear-resistant conductive hydrogel of this embodiment has a certain tear resistance, and the breaking energy is 7.45kJ / m 2 . When used as the electrode material of the triboelec...

Embodiment 3

[0059] Add 0.2g soluble starch to 3.8mL dimethyl sulfoxide, add 1mL hydroxyethyl methacrylate, 0.033g ammonium persulfate, 0.050g N,N'-methylenebisacrylcystamine, 50μLN,N, N',N'-tetramethylethylenediamine, stir until completely dissolved, and obtain a uniform and transparent gel prepolymerization solution. The prepolymerization solution was injected into a pair of glass sheets containing silica gel molds, and the organic oil gel was obtained by reacting at room temperature for 24 h. The organic oil gel was placed in a 1M sodium citrate solution for solvent replacement to obtain a high-strength tear-resistant conductive hydrogel. The obtained gel had a tensile modulus of 0.42 MPa, a compressive modulus of 0.52 MPa, and a fracture energy of 5.54 kJ / m 2 , the ionic conductivity is 3.61mS / cm.

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Abstract

The invention discloses high-strength tear-resistant conductive hydrogel, a preparation method thereof and application of the high-strength tear-resistant conductive hydrogel in a friction nano-generator. The preparation method comprises the following steps: adding hydroxyethyl methylacrylate, soluble starch, a cross-linking agent, an initiator and a super-accelerant into an organic solvent, stirring until complete dissolution to obtain a gel pre-polymerization solution, and standing to obtain organic gel; and placing the organic gel in an electrolyte solution, and carrying out solvent replacement to obtain the high-strength tear-resistant conductive hydrogel suitable for the friction nano-generator. The obtained high-strength tear-resistant conductive hydrogel has good mechanical properties and conductivity, can improve the external force damage resistance, effectively prolongs the service life of a friction nano-generator, and has great significance in promoting the development of the friction nano-generator.

Description

technical field [0001] The invention relates to the technical field of conductive hydrogels, in particular to a high-strength tear-resistant conductive hydrogel suitable for triboelectric nanogenerators and preparation and application thereof. Background technique [0002] Triboelectric Nanogenerator (TENG) has the advantages of simple structure, low manufacturing cost, high output voltage, and high energy conversion efficiency, and has good application prospects in the era of Internet of Things. The performance of triboelectric nanogenerators is mainly determined by its friction materials and electrode materials. Among them, according to the existence state of electrode materials, it can be divided into solid metal, solid inorganic and flexible electrode materials. Due to the rigid structure of solid-state electrode materials, they are prone to fracture under external force, and they are prone to irreversible deformation during long-term use, resulting in device damage, po...

Claims

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Application Information

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IPC IPC(8): C08J3/075C08F251/00C08F220/20C08L51/02H02N1/04
CPCC08J3/075C08F251/00H02N1/04C08F220/20
Inventor 陈涛李睿魏俊杰谷金翠
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI