Aggregate microparticles for therapy
A technology of aggregation and particles, applied in microcapsules, organic active ingredients, medical preparations of non-active ingredients, etc., can solve problems such as difficult to achieve
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[0317] VIII. Methods of Preparation of Surface-Treated Microparticles
[0318] Acronym
[0319] DCM,CH 2 Cl 2 Dichloromethane
[0320] DL drug load
[0321] DMSO Dimethyl Sulfoxide
[0322] EtOH ethanol
[0323] HA sodium hyaluronate
[0324] hr, h hour
[0325] min minutes
[0327] NSTMP non-surface treated particles
[0328] PBS Dulbecco's Phosphate Buffered Saline
[0329] PCL polycaprolactone
[0330] PEG polyethylene glycol
[0331] PLA poly(lactic acid)
[0332] PLGA poly(lactic-co-glycolic acid)
[0333] PVA polyvinyl alcohol
[0334] Rpm revolutions per minute
[0335] RT, r.t. room temperature
[0336] SD standard deviation
[0337] Particles with STMP Surface Treatment
[0338] UV ultraviolet
[0339] general method
[0340] All non-aqueous reactions were performed under an atmosphere of dry argon or nitrogen using anhydrous solvents. The structures of starting materials, intermediates and final products were conf...
Embodiment 1
[0344] Example 1. Preparation of biodegradable non-surface treated microparticles (NSTMP) comprising PLGA
[0345]Polymer particles comprising PLGA and diblock copolymers of PLGA and PEG, with or without sunitinib malate, were prepared using a single emulsion solvent evaporation method. Briefly, PLGA (560 mg) and PLGA-PEG (5.6 mg) were co-dissolved in dichloromethane (DCM) (4 mL). Sunitinib malate (90 mg) was dissolved in dimethylsulfoxide (DMSO) (2 mL). The polymer solution and the drug solution are mixed to form a homogeneous solution (organic phase). For empty NSTMP, drug-free DMSO (2 mL) was used. For drug-loaded NSTMP, the organic phase was added to 1% aqueous PVA in PBS (200 mL) and homogenized using a L5M-A laboratory mixer (SilversonMachines Inc., East Longmeadow, MA) at 5,000 rpm for 1 min to obtain an emulsion . For empty NSTMP, 1% PVA in water (200 mL) was used.
[0346] The emulsion (solvent-loaded microparticles) was then hardened by stirring at room temperat...
Embodiment 2
[0347] Example 2. Surface treatment of non-surface treated microparticles (NSTMP) using NaOH(aq) / EtOH
[0348] A pre-chilled solution containing a predetermined ratio of 0.25M NaOH (aqueous) and ethanol was added to the microparticles in a glass vial at about 4°C with stirring in an ice bath to form a 100 mg / mL suspension. The suspension is then stirred on ice for a predetermined time (e.g., 3, 6 or 10 minutes) and poured into a pre-chilled filter unit to remove the NaOH(aq) / ethanol solution. The microparticles were further rinsed with chilled water and transferred to a 50 mL centrifuge tube. The particles were then suspended in pre-cooled water and kept in the refrigerator for 30 minutes to allow the particles to settle. After removing the supernatant, the pellet was resuspended and filtered through a 40 micron cell strainer to remove large aggregates. Subsequently, the particles were washed twice with water at room temperature and lyophilized overnight. Table 1 lists the ...
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