Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Isodewaxing catalyst, preparation method thereof and method for producing lubricant base oil

A technology of isomerization dewaxing and catalyst, which is applied in the field of lubricating oil base oil, can solve the problems of high cloud point and achieve the effect of low pour point, excellent performance and improved conversion ability

Pending Publication Date: 2022-05-13
PETROCHINA CO LTD
View PDF9 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0013] The object of the present invention is to provide a isomerization dewaxing catalyst and process method suitable for producing low cloud point lubricating oil base oil from high freezing point waxy oil, using the catalyst and the process method to produce high freezing point waxy oil Oil base oil effectively solves the problem of high cloud point in the production process of existing lubricating oil base oil

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Isodewaxing catalyst, preparation method thereof and method for producing lubricant base oil
  • Isodewaxing catalyst, preparation method thereof and method for producing lubricant base oil
  • Isodewaxing catalyst, preparation method thereof and method for producing lubricant base oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0062] The commercially available industrial application molecular sieve raw powder ZSM-5, SAPO-11, EU-1, ITQ-13, ZSM-22, MCM-22, NU-87, ZSM-23, ZSM-35, ZSM-48 were used concentration The solution of the alkali metal salt of 0.1-0.5mol / L and / or the acidic solution with a concentration of 0.1-0.5mol / L is modified (the specific modification method is to impregnate the original molecular sieve with the solution of the alkali metal salt and / or the acidic solution powder), wherein the ratio of the mass of the original molecular sieve powder to the volume of the modified solution is 100g: 50-70mL, and the modified molecular sieve is then dried and calcined at 550°C for 4-10 hours to obtain the first modified molecular sieve; Wherein, the above molecular sieves are respectively taken 100g for illustration, the Si / Al of the above molecular sieves 2 o 3 The molar ratio is 0.5-120, the average grain size is 50-100nm, and the modified products and modifying reagents are shown in Table 1...

Embodiment 2

[0069] This embodiment provides a kind of isomerization dewaxing catalyst A1, and its preparation method is as follows:

[0070] 1) Mix 70g of the first modified molecular sieve A1 prepared in Example 1 with 40g of alumina powder, and extrude to obtain a wet strip; dry the wet strip at 200°C for 5 hours and use 0.1mol / L 200ml of KCl solution was impregnated to achieve the second modification, and then dried at 100°C and calcined at 550°C for 5 hours to prepare the second modified molecular sieve, that is, the catalyst carrier;

[0071] 2) The PtCl-containing 2 and PdCl 2 solution impregnated onto the catalyst carrier (i.e. the second modified molecular sieve), then dried at 120°C and calcined at 550°C for 4 hours to prepare Catalyst A1; wherein, the Pt and Pd contents in Catalyst A1 were 0.3wt% And 0.2wt% (based on catalyst mass).

Embodiment 3

[0073] This example provides a kind of isomerization dewaxing catalyst A2, the difference between its preparation method and Example 2 is: using 100g of the first modified molecular sieve A1 prepared in Example 1 and kneading with 20g of alumina powder, The two calcination temperatures were all 450° C., and the calcination time was 10 hours. The contents of Pt and Pd in ​​the catalyst A2 were 1.0 wt % and 0.1 wt % (by catalyst mass), and the others were the same as in Example 2.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Solidifying pointaaaaaaaaaa
Login to View More

Abstract

The invention provides an isodewaxing catalyst, a preparation method thereof and a method for producing lubricant base oil. The preparation method of the isodewaxing catalyst comprises the following steps: carrying out alkali metal salt solution and / or acid solution modification on an unformed molecular sieve containing a ten-membered ring structure to obtain a molecular sieve subjected to primary modification, carrying out forming treatment, and then carrying out secondary modification by using the alkali metal salt solution and / or acid solution, and then loading a noble metal active component on the catalyst to obtain the isodewaxing catalyst. The method for producing the lubricating oil base oil comprises the following steps: sequentially carrying out isomerization and cracking reaction on a mixture containing wax oil and hydrogen and at least two isomerization dewaxing catalysts, mixing a reaction product with hydrogen, carrying out aromatic hydrocarbon saturation reaction on the mixture and a finishing catalyst, and fractionating the reaction product to obtain the lubricating oil base oil. According to the lubricating oil base oil prepared by using the isodewaxing catalyst and the method for producing the lubricating oil base oil, the cloud point is greatly reduced.

Description

technical field [0001] The invention belongs to the field of lubricating oil base oils, and in particular relates to a heterogeneous dewaxing catalyst, a preparation method thereof and a method for producing lubricating oil base oils. Background technique [0002] The conventional method of lubricating oil production is the old three sets of production processes (solvent refining-solvent dewaxing-clay refining). The saturated hydrocarbon content of the base oil produced by this method is generally less than 90%, the sulfur and nitrogen content is higher, and the color is darker. At the same time, this method is highly dependent on the quality of raw materials for producing base oils. It is difficult to produce high viscosity index base oils from intermediate base crude oils. Usually, the base oils produced are Type I base oils, which cannot produce high viscosity index and low pour point. Class II and III base oils, and it is not possible to produce lubricating oil base oils...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): B01J29/40B01J29/44B01J29/85B01J29/65B01J29/67B01J29/70B01J29/74B01J29/03B01J37/02B82Y30/00B82Y40/00C10G67/02C10M101/02C10N20/02
CPCB01J29/40B01J29/44B01J29/85B01J29/65B01J29/67B01J29/70B01J29/74B01J29/7023B01J29/703B01J29/7038B01J29/7042B01J29/7092B01J29/7446B01J29/7461B01J29/7476B01J29/7492B01J29/7484B01J37/0201B82Y30/00B82Y40/00C10G67/02C10M101/02B01J2229/186B01J2229/37B01J2229/34C10G2400/10C10G2300/70C10G2300/304C10G2300/302C10M2203/1025B01J35/23B01J35/40C10N2020/02C10G45/64C10G45/62C10G65/043C10G65/12C10G67/0454C10G9/005C10M2203/1006
Inventor 杨晓东孙发民陆雪峰张国甲倪术荣王新苗高善彬刘彦峰孟祥彬靳丽丽姜丽丽董春明张文成郭金涛马东海孙生波韩志波
Owner PETROCHINA CO LTD
Features
  • Generate Ideas
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More