Photocuring 3D printing ceramic composite material as well as preparation method and application thereof

A ceramic composite material, 3D printing technology, applied in the direction of additive processing, etc., can solve the problems of high brittleness, low strength, limited application, etc., and achieve the effect of improving toughness, good mechanical strength and toughness, and excellent bone repair effect

Pending Publication Date: 2022-06-17
佛山仙湖实验室
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, although the 3D printing of bioceramics (calcium phosphate, calcium silicate-based, etc.) materials has been extensively studied, due to their inherent brittleness and low strength, their application in craniofacial and other load-bearing parts is limited. application

Method used

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  • Photocuring 3D printing ceramic composite material as well as preparation method and application thereof
  • Photocuring 3D printing ceramic composite material as well as preparation method and application thereof
  • Photocuring 3D printing ceramic composite material as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0065] A light-curing 3D printing ceramic composite material, the preparation raw materials of which include hydroxyapatite ceramic powder, light-curing resin, alumina powder and additives; wherein: the light-curing resin comprises 1,6-hexanediol diacrylate and Benzyl alcohol acrylate; auxiliary agents include dispersant phosphoric acid ester and polyamide, photoinitiator 1-hydroxy-cyclohexyl-phenyl ketone, defoamer polyoxypropylene glyceryl ether and polymerization inhibitor phenothiazine.

[0066] A preparation method of a photocuring 3D printing ceramic composite material, comprising the following steps:

[0067] (1) Preparation of ceramic slurry

[0068] Dry the hydroxyapatite ceramic powder and alumina powder for use;

[0069] To 1,6-hexanediol diacrylate and biphenylmethanol acrylate in a volume ratio of 7:3, first add 3 g of dispersant phosphate and 1 g of polyamide, and then add 0.2 g of photoinitiator 1-hydroxy- Cyclohexyl-phenyl ketones, 0.1 g of polymerization inh...

Embodiment 2

[0082] A light-cured 3D printing ceramic composite material, the preparation raw materials of which include tricalcium phosphate ceramic powder, light-cured resin, zirconia powder and additives; wherein: the light-cured resin includes 1,6-hexanediol diacrylate and biphenyl Methanol acrylate; additives include dispersant phosphoric acid ester and polyacrylate, photoinitiator 2,4,6 (trimethylbenzoyl) diphenylphosphine oxide, defoamer polyoxypropylene glyceryl ether and polymerization inhibitor Emulsified silicone oil.

[0083] A preparation method of a photocuring 3D printing ceramic composite material, comprising the following steps:

[0084] (1) Preparation of ceramic slurry

[0085] Drying tricalcium phosphate ceramic powder and zirconia powder for use;

[0086] In 1,6-hexanediol diacrylate and biphenylmethanol acrylate in a volume ratio of 5:5, first add 3 grams of dispersant phosphate and 1 gram of polyamide, and then add 0.2 grams of photoinitiator 2,4, 6 (trimethylbenz...

Embodiment 3

[0099] A light-curing 3D printing ceramic composite material, the preparation raw materials of which include hydroxyapatite ceramic powder, light-curing resin, zirconia powder and additives; wherein: the light-curing resin comprises 1,6-hexanediol diacrylate and ortho Phenylphenoxyethyl acrylate; additives include dispersant phosphate ester, photoinitiator 2,4,6(trimethylbenzoyl)diphenylphosphine oxide, defoamer polyoxypropylene glyceryl ether and paraben Hydroxyanisole inhibitor.

[0100] A preparation method of a photocuring 3D printing ceramic composite material, comprising the following steps:

[0101] (1) Preparation of ceramic slurry

[0102] Dry the hydroxyapatite ceramic powder and zirconia powder for use;

[0103] In the mixed resin of 1,6-hexanediol diacrylate and o-phenylphenoxyethylacrylate with a volume ratio of 6:4, first add 4 grams of dispersant phosphate, and then add 0.2 grams of photoinitiator 2,4 , 6 (trimethylbenzoyl) diphenylphosphine oxides, 0.1 gram ...

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Abstract

The invention belongs to the technical field of biological ceramic materials and additive manufacturing, and particularly discloses a photocuring 3D printing ceramic composite material and a preparation method and application thereof. The light-cured 3D printing ceramic composite material is prepared from the following raw materials: basic ceramic powder, light-cured resin, an inorganic toughening agent and an auxiliary agent, the light-cured resin comprises first light-cured resin and second light-cured resin, the refractive index of the first light-cured resin is 1.42-1.52, and the refractive index of the second light-cured resin is 1.60-1.70; the volume ratio of the first light-cured resin to the second light-cured resin is (9: 1)-(2: 8). According to the preparation method disclosed by the invention, the biological ceramic, especially a fine complex pore structure with highly communicated interior, can be prepared through photocuring, the toughness of the biological ceramic implant for craniomaxillofacial is remarkably improved, the fracture toughness can reach 0.769-0.869 MPa.m < 1/2 >, and the bending strength is 6.18-7.84 MPa.

Description

technical field [0001] The invention belongs to the technical field of bioceramic materials and additive manufacturing, and in particular relates to a light-curing 3D printing ceramic composite material and a preparation method and application thereof. Background technique [0002] Bone defect is a common clinical disease, and its causes are often comminuted fractures caused by trauma and traffic accidents, or bone defects caused by surgical resection of tumors, as well as fractures and bone defects caused by various traumas and accidents. Among them, the repair of craniomaxillofacial bone defects has the highest requirements on implant materials. At present, the repair materials for craniomaxillofacial bone defects mainly include autologous bone, allogeneic bone, metal materials and bioceramic materials. Compared with bioceramic materials, other repair materials are more or less limited in their application in bone repair due to problems such as material selection, rejecti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/447C04B35/22C04B35/10C04B35/48C04B35/622B33Y70/10
CPCC04B35/447C04B35/22C04B35/10C04B35/48C04B35/622B33Y70/10C04B2235/3418C04B2235/3272C04B2235/6562C04B2235/6567C04B2235/6565C04B2235/96
Inventor 戴红莲刘珂伍小沛杨鹤韩颖超
Owner 佛山仙湖实验室
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