Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Multifunctional treating agent for natural gas hydrate drilling fluid in sea area as well as preparation method and application of multifunctional treating agent

A technology for natural gas and drilling fluid, which is applied in the field of water-based drilling fluid organic additives for natural gas hydrate drilling in offshore areas, can solve the problems of poor filtration reduction and inhibition of natural gas hydrate decomposition, high toxicity of N-vinylpyrrolidone, and no environmental protection. requirements and other issues, to achieve the effect of excellent fluid loss reduction performance, excellent salt resistance performance, and improved hydrophilic performance.

Active Publication Date: 2022-08-09
CHINA UNIV OF PETROLEUM (EAST CHINA)
View PDF11 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent document CN113773440A discloses a dual-effect treatment agent with both hydrate decomposition inhibition and fluid loss control performance and its preparation method, but the N-vinylpyrrolidone of the inhibitor is highly toxic and does not meet the requirements of offshore drilling operations. Drilling fluid environmental protection requirements; and the minimum fluid loss of the inhibitor is about 12ml, and the fluid loss performance still needs to be improved
However, the poly-3-methylene-2-pyrrolidone and poly-N-vinylpyrrolidone used are difficult to degrade and damage the marine ecological environment; the effect of the obtained inhibitor needs to be improved; and it only has the effect of inhibiting the decomposition of natural gas hydrate, without the performance of reducing fluid loss. Single function
In general, the existing natural gas hydrate decomposition inhibitors are not good in reducing fluid loss and inhibiting the decomposition of natural gas hydrate. The development of hydrate decomposition inhibitors with good performance in reducing fluid loss and inhibiting hydrate decomposition It is of great significance to maintain the stability of the wellbore and ensure safe and smooth drilling during the drilling process.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Multifunctional treating agent for natural gas hydrate drilling fluid in sea area as well as preparation method and application of multifunctional treating agent
  • Multifunctional treating agent for natural gas hydrate drilling fluid in sea area as well as preparation method and application of multifunctional treating agent
  • Multifunctional treating agent for natural gas hydrate drilling fluid in sea area as well as preparation method and application of multifunctional treating agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] A multifunctional treatment agent for marine natural gas hydrate drilling fluid, prepared from the following raw materials: 1 g of modified cellulose, 3.10 g of dimethyl diallyl ammonium chloride (DMDAAC), 2-acrylamido-2- Methylpropanesulfonic acid (AMPS) 15.90g, initiator: ammonium persulfate 0.04g, sodium hydrogen sulfite 0.02g.

[0048] The preparation method of the modified cellulose comprises the steps:

[0049] (1) Mix 0.06 g of dimethoxymethyl vinyl silane with 6 g of distilled water uniformly, and hydrolyze for 1-2 min at room temperature to obtain a coupling agent solution. Then mix and disperse with an aqueous solution (mass concentration of 10 g / mL) containing 6 g of cellulose (weight-average molecular weight of 162.06 g / mol), and adjust pH to 4 with glacial acetic acid to obtain a synthetic solution;

[0050] (2) After placing the above synthetic solution in a three-necked flask equipped with a condenser and a mechanical stirring device, the modified cellul...

Embodiment 2

[0057] A multifunctional treatment agent for marine natural gas hydrate drilling fluid, prepared from the following raw materials: 3 g of modified cellulose, 4 g of dimethyl diallyl ammonium chloride (DMDAAC), 2-acrylamido-2-methyl 14 g of methyl propanesulfonic acid (AMPS), initiator: 0.02 g of ammonium persulfate, 0.02 g of sodium hydrogen sulfite.

[0058] The preparation method of the modified cellulose is the same as that in Example 1.

[0059] The preparation method of the above-mentioned multifunctional treatment agent for natural gas hydrate drilling fluid in the sea area comprises the following steps:

[0060] (1) Prepare 3 g of modified cellulose prepared as described above, 14 g of 2-acrylamido-2-methylpropanesulfonic acid and 4 g of dimethyldiallyl ammonium chloride and mix with 80 g of distilled water, magnetically at room temperature Stir evenly, and use a 30% NaOH aqueous solution to adjust the pH to 7 to obtain a mixed solution.

[0061] (2) A three-necked fl...

experiment example 3

[0063] A multifunctional treatment agent for marine natural gas hydrate drilling fluid, prepared from the following raw materials: 2 g of modified cellulose, 3.10 g of dimethyl diallyl ammonium chloride (DMDAAC), 2-acrylamido-2- Methylpropanesulfonic acid (AMPS) 15.90g, initiator: ammonium persulfate 0.02g, sodium hydrogen sulfite 0.02g.

[0064] The preparation method of the modified cellulose is the same as that in Example 1.

[0065] The preparation method of the above-mentioned multifunctional treatment agent for natural gas hydrate drilling fluid in the sea area comprises the following steps:

[0066] (1) Prepare 2 g of the modified cellulose prepared as described above, 15.90 g of 2-acrylamido-2-methylpropanesulfonic acid and 3.10 g of dimethyldiallyl ammonium chloride, mixed with 80 g of distilled water, at room temperature Under magnetic stirring, the pH was adjusted to 7 by using an aqueous NaOH solution with a mass concentration of 30% to obtain a mixed solution.

...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
decomposition temperatureaaaaaaaaaa
Login to View More

Abstract

The invention provides a multifunctional treating agent for natural gas hydrate drilling fluid in sea areas as well as a preparation method and application of the multifunctional treating agent. The multifunctional treating agent disclosed by the invention is prepared from the following raw materials in parts by mass: 0.1 to 10 parts of modified cellulose, 2 to 8 parts of dimethyl diallyl ammonium chloride (DMDAAC), 10 to 20 parts of 2-acrylamido-2-methylpropanesulfonic acid (AMPS) and 0.02 to 0.08 part of an initiator, the modified cellulose is cellulose modified by dimethoxy methyl vinyl silane. The multifunctional treating agent for the natural gas hydrate drilling fluid can effectively inhibit hydrate decomposition, improve the low-temperature filtration property of the drilling fluid, improve the stability of a hydrate reservoir and a wellbore and guarantee safe and smooth proceeding of hydrate drilling engineering; and the paint has salt resistance, and is environment-friendly and safe.

Description

technical field [0001] The invention relates to a multifunctional treatment agent for marine natural gas hydrate drilling fluid, a preparation method and application thereof, and belongs to the technical field of marine natural gas hydrate drilling water-based drilling fluid organic additives. Background technique [0002] Natural gas hydrate reserves are abundant and have great potential for exploitation, which is of great strategic significance for alleviating the contradiction between oil and gas supply and demand in my country and ensuring energy security. Therefore, the commercial exploitation of hydrates has become an imminent scramble for high ground in various countries, and safety and efficiency are also the primary prerequisites for hydrate exploitation. However, in the process of deepwater drilling, the hydrate formation is buried shallowly, weakly cemented, and has a high risk of leakage, and gas hydrate is easily decomposed under the action of drilling fluid, wh...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08F251/02C08F226/02C08F220/58C09K8/035C09K8/24
CPCC08F251/02C09K8/035C09K8/24C08F226/02C08F220/585
Inventor 孙金声姜海洋王金堂吕开河孙小辉王韧白英睿黎剑金家锋黄贤斌刘敬平
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products