79results about How to "Improve filtration loss reduction effect" patented technology

The invention relates to a copolymer of N-substituted acrylamide and N-vinyl caprolactam serving as a drilling fluid filtrate reducer with hydrate inhibition performance. The copolymer is made from vinyl acrylamide and N-alkyl caprolactam and is applied to a hydrate inhibitor and a filtrate reducer in the drilling fluid. The copolymer has the average molecular weight of 10000-2000000, the polymerization unit ratio is 0.1-10, the use mass concentration is 0.5-3 percent, and the use pressure is between 1MPa and 30MPa. According to the novel treatment agent disclosed by the invention, a natural gas hydrate inhibitor is combined with a filtrate reducer in a drilling fluid treatment agent, two functions are realized by virtue of one treatment agent, the cost of the drilling fluid is reduced, and the stability of the drilling fluid is guaranteed under the condition that the hydrate inhibition performance and filtrate loss reduction performance are improved.

The invention discloses white asphalt for drilling fluid and a method for preparing the white asphalt for drilling fluid. The white asphalt is prepared from the following raw materials in parts by weight: 40 parts-50 parts of paraffin, 1 part-2 parts of alkylphenol polyoxyethylene ether, 4 parts-5 parts of polyethylene glycol, 4 parts-5 parts of polyacrylamide, 20 parts-30 parts of stearic acid and 20 parts-30 parts of light calcium carbonate. The method for preparing the white asphalt comprises the following steps: adding the paraffin, alkylphenol polyoxyethylene ether, polyethylene glycol and stearic acid into a reactor proportionally; raising the temperature of the reactor to 70 DEG C-100 DEG C, and then stirring for 20-40 minutes at constant temperature; adding polyacrylamide to be stirred for 30 minutes at constant temperature; and finally, uniformly adding light calcium carbonate to be stirred for 0.5-2 hours at constant temperature and then discharging, and carrying out spray granulation to obtain the white asphalt. The white asphalt does not damage a hydrocarbon reservoir, has good lubricating performance and prevents collapse and blockage, filtration can be effectively reduced, the capacity of oil-gas wells is improved, and the technical problems of easily generated loss, collapse and the like during a drilling process when stratums with complicated conditions are drilled are solved.

The invention provides an oil-based drilling fluid filtrate reducer containing a cross-linked structure, and a preparation method. the method is carried out according to the following steps: (1) adding 0.1-30 parts by mass of a long-chain alkyl fatty acid and 1 part by mass of a polyene polyamine into a reaction vessel, stirring uniformly, driving oxygen for 20-30 min with nitrogen, heating to a temperature of 80-160 DEG C and reacting for 15 min-8 h; (2) cooling a temperature of the system to 75-85 DEG C, adding 0.5-25 parts by mass of a humic acid, stirring uniformly, driving the oxygen for 20-30 min with the nitrogen, heating to a temperature of 90-180 DEG C and reacting for 15 min-10 h; (3) adding 0.005-5 parts by mass of a binary or multiple organic acid, stirring uniformly and reacting for 15 min-16 h at a temperature of 100-200 DEG C; and (4) cooling a product obtained by the step (3) to a room temperature, smashing the product, and screening with a 50-100 mesh sieve to obtain the product.

The invention relates to the technical field of oil exploitation, and discloses a filtrate reducer and a preparation method thereof, and a water-based drilling fluid and application thereof. The filtrate reducer comprises a first polymer and a second polymer, wherein the first polymer is a natural high-molecular polymer; the second polymer is prepared by carrying out a polymerization reaction on an emulsifier and a monomer in the presence of an initiator; and the monomer is one or more selected from a group consisting of methyl-4-vinylbenzoate, dimethoxymethylvinylsilane, 1,3-divinyltetramethyldisiloxane, (2-bromovinyl)trimethylsilane, 4-vinyl-1-cyclohexene and acetic acid-1-cyano-2-propenyl ester. The water-based drilling fluid containing the filtrate reducer has salt resistance and high-temperature resistance, meets the requirement for the environmental protection properties of no toxicity and easy degradation, and also has tackifying and shear strength improving properties.

The invention relates to the field of petroleum engineering oilfield chemistry and discloses a nanometer starch microsphere filtrate reducer for a water-based drilling fluid, a preparation method thereof and the water-based drilling fluid. The nanometer starch microsphere filtrate reducer is prepared by dropwise adding a starch-containing alkaline solution into a continuous phase containing continuous phase oil and emulgator under the existence of cross-linking agent and initiator, reacting and centrifugally separating. The nanometer starch microsphere filtrate reducer is characterized by average grain diameter of 50-1000nm, swelling degree of 200-600%, total pore space volume of 0.5-4mL/g and capacity of resisting against temperature at 150 DEG C or above. According to the invention, thenanometer starch microsphere is used as a filtrate reducer, so that the leak-off of drilling fluid can be more effectively controlled, and meanwhile, temperature resistance can be obviously promoted,influence on viscosity of drilling fluid is smaller, and an excellent blocking effect to micropores and cracks on floor can be achieved. The nanometer starch microsphere has the advantages of biodegradability, environment-friendly property, extensive source and simple preparation process.

The invention discloses a filtration reducing agent for a drilling fluid and a preparation method thereof. The filtration reducing agent comprises the components in parts by weight: 200-250 parts of phenol, 50-60 parts of sodium chloroacetate, 50-60 parts of epoxy chloropropane, 380-430 parts of formaldehyde, 80-100 parts of sodium metabisulfite, 80-90 parts of anhydrous sodium sulfate, 65-78 parts of sodium hydroxide, 60-70 parts of trimethylamine, 36-45 of sodium 2-chloroethanesulfonate, 25-35 parts of carboxymethyl cellulose, 30-40 parts of acrylic amine, 28-40 parts of vinyl acetate, 30-36 parts of dimethyl diallyl ammonium chloride, and 800-1000 parts of water. The preparation method comprises the steps of firstly dissolving sodium hydroxide in water, adding phenol and sodium chloroacetate, carrying out a reaction, then adding epoxy chloropropane and trimethylamine, continuing to carry out a reaction, after the reaction, adding other components, successively carrying out reactions, and carrying out spray drying on the finally-obtained mixture to obtain the filtration reducing agent product.

The invention discloses brown coal resin for a drilling fluid and a production technology of the brown coal resin. Brown coal and sulfonated phenolic resin are used as main materials, sulfonated phenol humic acid with excellent salt resistance and high-temperature resistance is introduced, and the brown coal resin has remarkable high-temperature-resistant, filtration loss reduction and salt-resistant performance after being modified with a basifier and a sulfonating agent and has anti-collapse and viscosity control effects. A small amount of carboxymethyl cellulose is added, and the carboxymethyl cellulose has excellent stability and still has significant performance at 150 DEG C or above; meanwhile, trimethylamine and sulfomethyl sodium humate with excellent temperature resistance, salt resistance and calcium and magnesium ion resistance are introduced, the adsorption capacity of sulfonated phenolic resin and clay is enhanced, the temperature resistance and the salt resistance of theproduct are effectively improved, the value of the product is increased, the addition amount is small, the filtration loss reduction effect is significant, and excellent filtration loss reduction performance can be produced after only 1.0% of base slurry is added.

The invention provides a strongly inhibitory water-based drilling fluid, a preparation method therefor and application thereof. The drilling fluid comprises water, an amphoteric ionic polymer, anhydrous calcium chloride, a soil phase and a flow pattern modifier, wherein based on the water weight, the amphoteric ionic polymer accounts for 0.5-5 wt%, the anhydrous calcium chloride accounts for 20-70 wt%, the soil phase accounts for 0-6 wt% and the flow pattern modifier accounts for 0.1-0.4 wt%. The invention further provides a synthesis method for the water-based drilling fluid and application thereof. According to the drilling liquid provided by the invention, by virtue of a synergistic effect of the calcium chloride and the amphoteric ionic polymer, the drilling fluid has good rheological performance, filtration control performance, inhibition performance, sealing performance and lubricating performance.

The invention relates to a filtrate reducer preparation method and belongs to the field of petrochemical engineering. The filtrate reducer preparation method disclosed by the invention comprises the steps: firstly mixing, reacting and evaporating tannin and a sodium hydroxide solution to obtain dry matter; then mixing and heating substances of acrylic acid, sodium p-styrene sulfonate and the like, adding substances of the prepared dry matter and the like to react to obtain jelly and drying and smashing to obtain reactant; then mixing substances of aluminum potassium sulfate dodecahydrate, palmitic acid and the like to obtain a mixed solution and mixing and heating the mixed solution and the obtained reactant; dropwise adding an initiator to react, adding an obtained product into absolute ethyl alcohol to be separated out, filtering and drying and smashing filter residues to obtain a filtrate reducer. The temperature-resistance and salt-tolerance filtrate reducer prepared by the preparation method disclosed by the invention still has higher filtrate reduction performance under high-salinity environment and further has better temperature resistance.

The invention provides biomass synthetic base drilling fluid and a preparation method thereof and belongs to the technical field of expansion of petroleum natural gas environment-friendly type synthetic base drilling fluid. The biomass synthetic base drilling fluid provided by the invention comprises biomass base fluid, a CaCl2 water solution, organic soil, an emulsifier, a wetting agent, a fluidloss agent, CaO and barite. The biomass base fluid, the emulsifier and the wetting agent have a cooperative agent; under the cooperative effect of all components in the drilling fluid, the biomass synthetic base drilling fluid provided by the invention has relatively good performance; and all the raw materials are green and environmentally friendly and have a relatively low price and good biodegradability, and the biomass synthetic base drilling fluid is novel green synthetic base drilling fluid.

The invention provides a drilling fluid additive. The drilling fluid additive comprises a structure shown as formula I, wherein in the formula I, a is 1200-3100, q is 1-10, p is 2-10, m is 1-16, n is1-5, o is 0-4, and M is an alkali metal element. The invention further provides a preparation method of the drilling fluid additive in the technical scheme. The preparation method comprises the following steps: (1) preparing a first intermediate product from chitosan, an alkali compound and an alcohol compound through a reaction; (2) preparing a second intermediate product from the first intermediate product and chlorocarboxylic acid through a reaction; (3) preparing a third intermediate product from the second intermediate product, a chloro monobasic alcohol compound, a chloro dibasic alcoholcompound and a chloroalkyl epoxide through a reaction; (4) preparing the drilling fluid additive from the third intermediate product and organic amine through a reaction. The drilling fluid additivehas good inhibition performance, shearing increasing performance and filter loss reducing performance.

The present invention provides a highly efficient water-based drilling fluid and a synthesizing method and application therefor. The drilling fluid comprises water, a zwitterion polymer, anhydrous calcium chloride, a soil phase and a flow pattern regulator, wherein, with the weight of the water as a reference, the weight of the zwitterion polymer is 0.5-5% of that of the water, the weight of the anhydrous calcium chloride is 20-70% of that of the water, the weight of the soil phase is 0-6% of that of the water and the weight of the flow pattern regulator is 0.1-0.4% of that of the water. The present invention further provides a synthesizing method and application for the water-based drilling fluid. According to the drilling water provided by the present invention, synergy between the calcium chloride and the zwitterion polymer enables the drilling fluid to have the excellent rheological property, filtration control property and inhibiting property, plugging property and lubricating property.

The invention discloses a crosslinking fluid loss agent preparation method. The method comprises steps of: adopting acrylic ester and acrylamide as main monomers of the crosslinking fluid loss agent and glycidyl acrylate as a crosslinking monomer of the crosslinking fluid loss agent, selecting a water-soluble radical initiator, and synthesizing a copolymer in the presence of nitrogen through adopting an emulsion polymerization method. The polymerization reaction time takes 2 hours, the insulation time costs 2 hours, the pH value is set to be 6-7, and the polymerization experimental reaction temperature is 70 DEG C. The copolymer prepared by the method can crosslink at the temperature of above 130 DEG C so as to form a proper crosslinking network structure, so that the viscoelasticity and temperature resistance of cement slurry can be improved, a problem of the poor temperature resistance of an acrylamide polymer which is served as a fluid loss agent can be solved, and the fluid loss reduction performance of the fluid loss agent in deep wells and ultradeep wells is improved. The crosslinking fluid loss agent mainly serves as the fluid loss agent for the well cementation cement slurry of oil-gas wells.

The invention discloses a method for preparing a multifunctional lubricant of drilling fluid by using waste oil. The method comprises the following steps: (1) firstly, weighing the waste oil and putting into a reactor, and putting the reactor into an electrothermal constant-temperature water bath kettle; (2) then weighing liquid SO3 and putting into a dropping funnel, in order to change the liquid SO3 dripping from the dropping funnel into a gas SO3, and keeping a gas generator connected with the dropping funnel at 50-70 DEG C by a thermal cycling effect of a jacket water bath; (3) mixing with N2 before the gas SO3 enters a reactor; and (4) controlling the reaction temperature at 50 DEG C, enabling the gas SO3 to react with the waste oil for 2-4 hours, and then adding an organic alkali to the reactor, adjusting the pH to 8-9, and then adding a composite surfactant to the reactor, so as to obtain the lubricant after agitating for 3-10 minutes. Compared with the similar lubricant, the lubricant prepared by the method disclosed by the invention is simple in production technology, and low in cost, has good high-temperature extreme pressure lubricity, also has good fluid loss effect and anti-collapse performance, and is applicable to horizontal well and complicated stratum drilling.

Belonging to the technical field of chemical industry, the invention relates to a salt and high temperature resistant filtrate loss reducer for seawater-based drilling fluid and a preparation method thereof. The filtrate loss reducer is prepared from the following raw materials by mass fraction: 30%-60% of a polymer monomer, 0.05%-0.15% of a first initiator, 0.05%-0.15% of a second initiator, andthe balance water. The invention solves the problems that existing filtrate loss reducers cannot meet the requirement of maintaining good temperature resistance in an environment containing salt and calcium and the temperature and salt resistant filtrate loss reducer that can stabilize borehole walls and inhibit shale expansion and meet the drilling requirements of shallow sea areas in Peru is notdeveloped yet. The filtrate loss reducer provided by the invention has strong filtrate loss reducing properties, is suitable for various density conditions, especially for the filtrate loss reductionof high density drilling fluid, also has strong hardness resistance and strong inhibition properties, and can effectively control the filtrate loss reducing properties of drilling fluid under a hightemperature condition, improve the high temperature resistance and drilling efficiency of drilling fluid, and reduce the comprehensive cost of drilling fluid.

The invention relates to the technical field of well drilling, in particular to a high-temperature-resistant and high-salt-resistant hydrophobic blocking agent and a preparation method thereof. The high-temperature-resistant and high-salt-resistant hydrophobic blocking agent is prepared from 5 to 10 parts by mass of modified SiO2, 2 to 5 parts by mass of lauryl sodium sulfate, 10 to 20 parts by mass of acrylamide, 10 to 20 parts by mass of methacryloyloxyethyl trimethyl ammonium chloride, 2 to 6 parts by mass of octadecyl methacrylate, 0.2 to 0.5 part by mass of an initiator and a proper amount of acetone and water. According to the SiO2 graft polymer prepared through polymerization, the blocking effect is achieved through SiO2, the surface of SiO2 is hydrophobic through a long-chain alkyl chain and an ester group, and then the surface of a mud cake or a stratum pore is hydrophobic while tiny pores in the mud cake and pores in the stratum are blocked, so that invasion of water molecules is more effectively prevented, the compactness of the mud cake is improved, and the water permeability of the mud cake is improved. The filtrate loss is reduced, the filtrate loss reduction performance of the drilling fluid at high temperature and high salt is enhanced, formation pores and cracks are blocked, and the effect of efficiently stabilizing a well wall is achieved.

The invention discloses a high-temperature water-based drilling fluid. The high-temperature water-based drilling fluid comprises, by weight, 103 to 104 parts of base slurry, 1 to 1.5 parts of a filtrate reducer I, 1.5 to 2 parts of a filtrate reducer II, 2 to 2.5 parts of a filtrate reducer III, 2 parts of polyethylene glycol, 1 to 1.5 parts of aminosilanol, 3 to 5 parts of potassium chloride, 2 to 2.5 parts of a lubricant, 0.6 to 1 part of calcium carbonate powder with a size of 600 to 800 meshes, 1.2 to 1.5 parts of modified diatomite with a size of 400 to 500 meshes and barite with an addition amount that allows the high-temperature water-based drilling fluid to be weighted to 1.4-1.7 g/cm<3>. The invention also discloses a preparation method of the high-temperature water-based drillingfluid. The drilling fluid has the beneficial effects of resisting high temperature and reducing the permeability and the filter loss of the drilling fluid.

The invention relates to the field of treating agents for drilling fluids, in particular to a lubricating and plugging filtrate reducer for a drilling fluid and a preparation method of the lubricating and plugging filtrate reducer. Comprising 31 to 35 parts of a functional monomer, 0.6 to 0.8 part of graphene oxide, 80 to 100 parts of water, 70 to 80 parts of an oil phase dispersion medium, 20 to 30 parts of paraffin, 15 to 20 parts of a composite emulsifier and 1.0 to 1.5 parts of an initiator. The functional monomers comprise acrylic acid, acrylamide, 2-acrylamido-2-methylpropanesulfonic acid and styrene. The compound emulsifier is formed by mixing Span80 and Tween 80; the weight ratio of the Span80 to the Tween 80 is 1: 1. And the oil phase medium is white oil or diesel oil. The initiator is a composition of ammonium persulfate and sodium hydrogen sulfite. The preparation method of the lubricating plugging filtrate reducer for the drilling fluid is a reverse emulsion polymerization method. The lubricating plugging agent has a wide particle size distribution range, can effectively plug microcracks with different sizes to form a high-lubricity isolating membrane, has lubricating performance, plugging performance and filtrate loss reduction performance, can resist the temperature of 220 DEG C, can resist NaCl to be saturated, and has a wide application prospect.

The invention provides a filtrate loss reduction composition, a filtrate loss reducer and a preparation method and application of the filtrate loss reducer. The filtrate loss reduction composition is prepared from the following components in parts by weight: 160-320 parts of oleic acid, 50-80 parts of diethylenetriamine and 100-170 parts of humic acid. When the filtrate loss reducer formed by the high-molecular polymer is applied to drilling fluid, the filtrate loss of the drilling fluid can be controlled, and the stability of a well wall can be improved. The probability that the performance of a drilling fluid system becomes poor due to the fact that the filtrate loss reducer is decomposed in the using process of the high-temperature drilling fluid is reduced. Especially for a high-temperature-resistant gas-to-oil synthetic base drilling fluid system with relatively high requirement on the environmental protection property of a treating agent, the filtrate loss reducer is beneficial for improving the high-temperature emulsion stability and filtrate loss reduction performance of the high-temperature-resistant gas-to-oil synthetic base drilling fluid system. Therefore, the problems that the performance of a high-temperature-resistant gas-to-oil synthetic base drilling fluid system is reduced and the filtrate loss is increased are solved. The formula is simple, the raw materials are cheap and easy to obtain, and the production cost is low.