Low-temperature high-pressure hydrogen storage pressure vessel and use method thereof

A pressure vessel, low-temperature and high-pressure technology, applied in the field of hydrogen storage and transportation, can solve the problems of high hydrogen storage pressure, slow hydrogen absorption and discharge process, and easy pulverization, and achieve high storage pressure, fast hydrogen charging and discharging rate, and low-temperature environment performance. The effect of low consumption

Pending Publication Date: 2022-08-09
CNOOC GAS & POWER GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This kind of storage and transportation method has high hydrogen storage pressure, high risk, and low hydrogen storage density. It is necessary to provide a high-pressure compressor at the hydrogen-rich end, and a low-pressure hydrogen storage tank at the hydrogen-demanding end.
[0005] The hydrogen storage density of liquid hydrogen has reached 70kg / m3, but the temperature of liquid hydrogen under normal pressure is -252.8°C, the cost of storage and transportation equipment is high, and hydrogen liquefaction requires a lot of energy consumption, accounting for about one-third of the required hydrogen storage. , gasification equipment is required during the use of hydrogen
[0006] Hydrogen storage in porous media is a kind of solid-state hydrogen storage, which generally includes graphene, organic metal framework materials, etc., which are commonly seen in newspapers. This method generally has a good hydrogen storage capacity at liquid nitrogen temperature, but the material manufacturing cost is high. , no industrialized devices have been seen, and the hydrogen storage technology is immature
[0007] Organic hydrogen storage is a potential available hydrogen storage method. The mass hydrogen storage density is about 6% at normal temperature and pressure. The hydrogen-rich end needs a hydrogenation device to generate hydrogen-rich organic matter, and the hydrogen-requiring end needs dehydrogenation reaction. The process requires about a quarter of the energy consumption, and this type of compound is highly toxic, and the hydrogenation and dehydrogenation process needs to be carried out in a specialized chemical park, which limits its development
[0008] Metal hydrides have high volumetric hydrogen storage density, generally greater than 40kg / m3, and low mass hydrogen storage density, but their hydrogen absorption and desorption process is slow, and the cost of metal materials is high, easy to pulverize, and it is difficult to manufacture pressure vessel equipment

Method used

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  • Low-temperature high-pressure hydrogen storage pressure vessel and use method thereof

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Effect test

Embodiment 1

[0050] like figure 1 As shown, this embodiment provides a 70MPa low temperature and high pressure hydrogen storage pressure vessel, and the low temperature and high pressure hydrogen storage pressure vessel includes a multi-layer design:

[0051](1) The metal liner 1 of the pressure vessel is made of Dewar steel material, with a hemispherical head, the bottle body is 6m long, the inner diameter is 0.53m, and the wall thickness is 10mm;

[0052] (2) The reinforced braided layer 2 of the pressure vessel is wound with 6 layers of carbon fibers and 2 layers of aramid fibers;

[0053] (3) The heat exchange pipe 3 is made of stainless steel, the inner diameter of the pipe is 10mm, and the wall thickness is 2mm. Liquid nitrogen or low-temperature nitrogen is used as the refrigerant, and normal temperature or heated nitrogen is used as the heat medium;

[0054] (4) The cold insulation layer 4 adopts three layers of aerogel felt pads, and the thickness of a single layer is 10 mm.

[...

Embodiment 2

[0061] This embodiment provides another 40MPa low temperature and high pressure hydrogen storage pressure vessel. The low temperature and high pressure hydrogen storage pressure vessel includes a multi-layer design:

[0062] (1) The metal liner 1 of the pressure vessel is made of Dewar steel material, with a hemispherical head, the bottle body is 6m long, the inner diameter is 0.53m, and the wall thickness is 10mm.

[0063] (2) The reinforced braided layer 2 of the pressure vessel is wound with 6 layers of carbon fibers.

[0064] (3) The heat exchange pipe 3 is made of stainless steel, the inner diameter of the pipe is 10mm, and the wall thickness is 2mm. Liquid CO2 is used as the refrigerant, and normal temperature or heated nitrogen is used as the heat medium.

[0065] (4) The cold insulating layer 4 adopts three layers of aerogel felt pads, and the thickness of the single layer is 10 mm.

[0066] (5) The material of the outer sheath layer 5 is made of high-density polyethy...

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Abstract

The invention relates to a low-temperature high-pressure hydrogen storage pressure vessel and a using method thereof.The pressure vessel comprises a vessel body, and the vessel body comprises a metal inner container, a reinforced braid layer, a heat exchange guide pipe, a cold insulation layer and an outer sheath layer; the metal inner container comprises a bottle body and a bottle opening formed in one end of the bottle body. The reinforced braid layer, the cold insulation layer and the outer sheath layer are sequentially arranged outside the metal liner from inside to outside in a sleeving manner and avoid the bottle opening; the heat exchange guide pipe is located between the reinforced braid layer and the cold insulation layer and surrounds the side wall and the bottom of the metal inner container, the two ends of the heat exchange guide pipe extend out of the top of the container body, and the two ends of the heat exchange guide pipe are located on the two sides of the opening of the container body.

Description

technical field [0001] The invention relates to the technical field of hydrogen storage and transportation, in particular to a low-temperature and high-pressure hydrogen storage pressure vessel and a method for using the same. Background technique [0002] Hydrogen is considered to be the ultimate energy source in the new century due to its high mass energy density and no CO2 generation from combustion. At present, under the background of "dual carbon", with the gradual maturity and widespread promotion of hydrogen fuel cell technology, hydrogen, as a key substance that can deeply decarbonize and reduce carbon emissions, has gradually become the core of energy, chemical industry, steel, and transportation fields. . [0003] However, due to the low quality and low bulk density of hydrogen, it is easy to escape and easy to embrittle, which leads to the storage and transportation of hydrogen becoming a bottleneck for the development of the industry. The current mainstream hyd...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F17C1/04F17C1/12F17C13/00F17C13/02F17C13/04
CPCF17C1/04F17C1/12F17C13/001F17C13/002F17C13/026F17C13/025F17C13/04F17C2201/0109F17C2203/012F17C2203/0325F17C2203/0304F17C2203/0366F17C2203/0631F17C2203/0643F17C2203/0663F17C2203/066F17C2205/0126F17C2205/0323F17C2205/0338F17C2209/2154F17C2221/012F17C2260/025Y02E60/50
Inventor 单彤文张超侯海龙侯建国王秀林姚辉超张瑜段品佳穆祥宇宋鹏飞隋依言周树辉张雨晴黄辉
Owner CNOOC GAS & POWER GRP
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