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Polymeric membrane fuel cell stack

A fuel cell and battery technology, applied in the direction of fuel cells, fuel cell groups, fuel cell additives, etc., can solve problems such as excessive requirements and impossibility of implementation

Inactive Publication Date: 2003-03-12
NUVERA FUEL CELLS EURO SRL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This last factor in turn creates two serious drawbacks: first, a substantial fraction of the two half-reactions will proceed at undesirably low temperatures for catalyst activity and membrane ion conductivity; second, for Circulating the coolant at temperatures that are too low would be excessively demanding and even impractical for some types of applications (e.g. for automotive towing) for the overall economics of the system

Method used

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  • Polymeric membrane fuel cell stack
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  • Polymeric membrane fuel cell stack

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] assembly corresponding to Figure 5 The design of the device, the device includes an active area of ​​0.1m 2 25 fuel cells connected in series, and 5 wetting pools at one end of the filter press array forming a single wetting zone; the filter press array is set up so that all 5 wetting pools are used to wet the supply to The same reagent as the device. The fuel cell included a 2 mm thick gasket as shown in Figure 2, and a filler material made of 2 mm thick 50% porosity nickel-chromium foam. The same filler material was used for the gasket in the wetted area, also 2 mm thick.

[0037] Pure hydrogen supplied to the dead-end (i.e. without any recirculation, wherein the amount of hydrogen consumed by the reaction is continuously replenished by pressure equalization; only periodic purges are used to remove accumulated inert gases during operation) and filtered and Compressed ambient air was used to run the stack obtained above. The air flow is twice the stoichiometric re...

Embodiment 2

[0039] The generator of the above embodiment was connected to the apparatus shown in FIG. 6 . The experiment of the above example was repeated with two changes: compressed air was not previously saturated in the sparger tank, but was fed to the wetted zone of the device together with a water flow of 30 l / h. In addition, no cooling circuit is used. Under such conditions, the device was able to generate 200mA / cm in a stable manner 2 The current density; increasing the water flow in the wetting area can also increase the current density in parallel, up to 380mA / cm 2 , at this time the water flow rate is 72l / h. Above this current density level, increasing the water flow had no appreciable effect and the test was terminated due to a sharp drop in the voltage of several of the device's fuel cells.

Embodiment 3

[0041] Repeat the test of Example 3, the only change is that the cooling circuit is put into operation, using 4m 3 / h of demineralized water at a constant flow rate of 50°C. Supply 72l / h of water to the wet area, and maintain 1050mA / cm in 9 hours of continuous operation 2 The stable current density, the average cell voltage is 0.42V, and the minimum single cell voltage is 0.4V.

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Abstract

An improved design of gas fed polymeric membrane fuel cell stack is herein described. The stack is provided with a humidifying device which takes advantage of the atomisation of a water stream over a high specific surface metallic material, and with a cooling circuit withdrawing the heat generated therein by thermal exchange on a peripheral region, external to the single cell active area. The device is particularly suited for high temperature and high current density operation.

Description

Background of the invention [0001] The present invention relates to a polymer membrane stack fuel cell. Fuel cells are direct generators of electrochemical electrical energy; in other words, they convert the free energy of the reaction of a fuel (such as a gaseous mixture containing hydrogen, or a light alcohol such as methanol or ethanol) with an oxidizing agent (such as air or oxygen) without using This free energy degenerates completely into thermal energy and thus avoids being limited by the Carnot cycle. This conversion is achieved by electrochemical oxidation of the fuel at the cathode of the cell, where the electrochemical oxidation reaction releases H + ions, while the oxidant is reduced at the anode, and the reduction reaction consumes H + Ions; said ions migrate from the cathode region of the battery to the anode region of the battery through a suitable electrolyte. In polymer film batteries, such an electrolyte is composed of a cation exchange membrane that simul...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/02H01M8/04H01M8/10H01M8/24
CPCH01M8/04029H01M8/04119Y02E60/50H01M8/2485H01M8/241H01M8/2483H01M8/242H01M8/0267H01M8/04
Inventor M·布兰比拉G·马祖切利G·P·弗雷巴A·马吉奥尔
Owner NUVERA FUEL CELLS EURO SRL