Avilamycin water-suspension nano capsule preparation and method for preparing same

A nano-capsule, abamectin technology, applied in the directions of botanical equipment and methods, biocides, animal repellents, etc., can solve the problems of waste of resources, decomposition waste, and high cost, and is beneficial to the ecological environment. Effective utilization and low surface tension

Inactive Publication Date: 2003-08-27
HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. Contains a large amount of organic solvents, such as toluene, xylene, etc., causing thousands of tons of organic solvents to be discharged into nature every year, wasting resources and seriously polluting the environment
[0004] 2. When used, it needs to be diluted with water to form an emulsion. The active ingredients are micron-scale dispersed. The dispersibility of the active ingredients is poor and the effective utilization rate is low, resulting in a large amount of pesticides, resulting in increased agricultural costs and a large number of pesticide residues, which seriously affects the quality of agricultural products.
[0005] 3. The active ingredients have poor permeability, and the active ingredients remaining on the leaves are decomposed and wasted due to environmental factors such as light and air.
[0006] 4. The colonization of biological pesticides in the soil is poor, and the special ecological environment of the soil often inhibits the efficacy of biological pesticides, which limits the large-scale promotion of biological pesticides
[0007] Compared with emulsifiable concentrate, the microemulsion of abamectin can better solve the problems of water-based and high dispersion, but it is not a long-acting dosage form, and the release cannot be controlled. More importantly, the cost is high and the effect is not ideal

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Dissolve 0.1g of ammonium persulfate in 20g of water (divided into two parts by 4:1), and set aside; dissolve 0.5g of abamectin in the mixed monomer of 7g of styrene, 8g of butyl acrylate, and 0.2g of acrylic acid; Dissolve 6g of nonylphenol polyoxyethylene ether (OP-40) and 1g of sodium lauryl sulfate in 50g of 2% polyvinyl alcohol aqueous solution, put it in a stirring container, and add the solution of a The mixed monomers of vermectin are dispersed into emulsion and put into the reaction vessel. Heat to keep the temperature at 70±2°C, add the first part of initiator, react for 6 hours, keep warm for 1 hour, and prepare the seed emulsion; add 1.5g of styrene, 1.5g of butyl acrylate, 2g of toluene diisocyanate mixed monomer and Add the second initiator dropwise for 1 hour, keep warm for 2 hours, cool down; add additives, and discharge. The content of Abamectin in the product is 0.5%.

Embodiment 2

[0058]Dissolve 0.1g of potassium persulfate in 10g of water (divided into two parts at 4:1), 1g of acrylamide in 10g of water for later use; dissolve 1g of avermectin in a mixture of 4g of ethyl acrylate and 7g of butyl acrylate In the monomer; dissolve 5g of nonylphenol polyoxyethylene ether (OP-40), 4g of sodium lauryl sulfate, and 4g of polysodium methacrylate in 60g of water, put them in a stirring container, and , add the mixed monomers dissolved in avermectin, disperse into an emulsion, and put it into a reaction vessel. Heat and keep the temperature at 70±2°C, add the first initiator and acrylamide aqueous solution, react for 6 hours, keep warm for 1 hour, and prepare the seed emulsion; add 1g ethyl acrylate, 1g butyl acrylate, 2g 4,4' - diphenylmethane diisocyanate mixed monomer, dropwise for 1 hour, keep warm for 2 hours, cool down; add additives, discharge. The content of Abamectin in the product is 0.9%.

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PUM

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Abstract

The present invention discloses an abamectin water suspension nano capsule preparation made up by enulsion polymerization process. Its capsule skin is the styrene, isocyanate, acrylic and methyl acrylic monomer copolymer, and the capsule core contains effective component biological source pesticide and abamectic new dosage form, in which abamectin content is 0.2%-5% (w / w), capsule content is 5%-30% (w / w), additive content is 10%-35% (w / w) and proper quantity of water. Said nano capsule is monodisperse spherical granules, and its average grain size less than 100 nano. It can be extensively used for controlling several pests of fruit tree, vegetable, flowers, cotton and tobacco and other crops.

Description

technical field [0001] The invention relates to a water-suspended nanocapsule of avermectin, which belongs to the formulation technology of biological source pesticides and veterinary drugs. Background technique [0002] Abamectin is a biogenic pesticide and veterinary drug produced by microbial fermentation and purification. It is used in agricultural production to prevent and control stubborn pests and mites in fruit trees, vegetables, flowers, cotton, tobacco and other plants, such as More than 80 kinds of pests such as Liriomyza sativae, diamondback moth, spider mite, cabbage caterpillar, root-knot nematode, cotton bollworm, pear psyllid, etc.; in animal husbandry, it is used to drive and kill gastrointestinal nematodes in animals and cowhide maggots in vitro, It is one of the most effective, fastest-growing and most widely used biological source pesticides in the world. Its broad-spectrum, ultra-efficient, and effective The characteristics of small amount, low residue,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N25/04A01N43/90
Inventor 尚青郑和堂
Owner HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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