High transparent polyester film and process for producing the same

A polyester film, transparent technology, used in the field of polymer compounds, can solve the problems of poor winding and slitting performance, small diameter, etc.

Inactive Publication Date: 2004-03-17
SHANGHAI ZIDONG FILM MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The film of the present invention can be applied to fields such as laser anti-counterfeiting trademarks, card protection films, decorations, etc. The present invention is compared with the prior art, because introducing nano-scale silicon dioxide particles into the polymer not only makes the strength of the polymer, The mechanical and physical properties such as rigidity and toughness have been significantly improved, and because of the small particle diameter and good light transmittance, the density of the plastic has been increased, and the light transmittance, water resistance, barrier property, heat resistance and aging resistance of the plastic have been improved. At the same time, due to the introduction of micron-sized silica, the problem of poor winding and slitting performance of the polyester film in the prior art is solved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] A kind of high-transparency polyester film of the present invention, wherein said high-transparency polyester film comprises nano-scale silicon dioxide and micron-scale silicon dioxide, and described nano-scale silicon dioxide is purchased from German Degussa company, instituted The particle size of the nano-scale silicon dioxide is between 20-50nm, and the content of the nano-scale silicon dioxide in the total weight percentage of the polyester film is between 50-2000ppm, preferably between Between 100-1000ppm, the diameter of the micron-sized silicon dioxide is between 1.2-2.0μm, and the content of the micron-sized silicon dioxide accounts for the percentage of the total weight of the polyester film in the range of 1-300ppm between, preferably between 5 and 200ppm, the polyester can be formed by condensation of one or more dibasic carboxylic acids and one or more dibasic alcohols, the preferred polyester of the present invention It is polyethylene terephthalate formed...

Embodiment 2

[0013] A method for preparing such a high-transparency polyester film of the present invention includes firstly preparing a silica suspension, and then producing a polyester film according to a conventional production method, wherein the method for preparing the silica suspension is as follows : the surface of nano-scale silicon dioxide with an average particle size of 40nm is treated by using the organosilane coupling agent in the prior art, specifically utilizing the gas phase spray method to spray the silane coupling agent in a gaseous state in a vacuum chamber Coating nano-scale silica, adding the coated silica and ethylene glycol into the sand mill, and then adding silica with an average particle size of 1.6 μm, the micron-scale silica The content of silicon oxide accounts for 2 to 15% by mass of the nano-scale silicon dioxide, and is dispersed at a high speed for at least 6 hours to form a suspension of silicon dioxide, wherein the silicon dioxide particles account for th...

Embodiment 3

[0015] The preparation method of the polyester film is the same as that in Example 2, and the polyester film of 30 μm is obtained. The content of silicon dioxide in the polyester film is 400 ppm, the coefficient of static friction of the film is 0.39, the coefficient of dynamic friction is 0.31, and the haze of the film is 1.0%.

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PUM

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Abstract

The high transparency polyester film contains nano level silica of grain size 20-50 nm and micron level silica of grain size 1.2-2.0 microns. The nano level silica accounts for 50-2000 ppm of total polyester film weight, and the micron level silica 1-300 ppm. The production process of the high transparency polyester film includes the first preparation of silica suspension, the subsequent conventional polymer producing course to produce polyester slice, and final conventional melting extrusion of the slice and bi-directional stretching. The product of the present invention has high transparency, waterproof property, blocking property, heat resistance and antiaging property.

Description

Technical field: [0001] The invention relates to a polymer compound, in particular to a polyester film, especially a highly transparent polyester film and a production method thereof. Background technique: [0002] Due to its excellent physical and mechanical properties, electrical insulation and heat resistance, good transparency and toughness, polyester film is widely used in packaging, tapes, electrical insulation, printing, drawing, photosensitive, labels and other fields. [0003] The slippage of the film surface has a great influence on the processing of polyester films, especially thin films, so controlling the slippage of the film surface is a basic requirement for film production. The slippage of the film surface is usually controlled by adding additives to increase the roughness of the film surface. The additives are usually inert particles such as silicon dioxide, clay, aluminum silicate, calcium phosphate and glass balls. However, while the addition of these add...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J5/18C08K9/04C08L67/03
Inventor 吴斌付鹏程
Owner SHANGHAI ZIDONG FILM MATERIAL CO LTD
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