Method for preparing alpha-Al2O3 from dust powder collected by electricity
A technology of electric dust collection and dust powder, applied in the direction of alumina/hydroxide, etc., can solve the problem of reducing the quality and performance of metallurgical grade alumina, the adverse effects of the purity and particle size of finished alumina, and the comprehensive performance of the product is not suitable for production raw materials and other issues to achieve the effect of improving the level of comprehensive utilization, reducing adverse effects, and improving market competitiveness
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Embodiment 1
[0016] The electric dust collection powder is used as the raw material. It is first screened with a 60-mesh sieve to remove the large particles of impurities, and then the dust collection powder under the sieve and the additive ammonium fluoride are homogenized in a three-dimensional mixer. The time is 0.5 hours, and the amount of ammonium fluoride added is 10‰ of the mass of dust collection powder on a dry basis. Put the homogenized mixed material into a high-aluminum saggar and put it into a 0.2m 3 Calcined in a high-temperature kiln at 1350°C for 3 hours, then taken out from the sagger, crushed, milled in a 50Kg corundum porcelain-lined ball mill for 30 minutes, and passed through a 200-mesh sieve to obtain the under-sieve product Al 2 o 3 The purity is 99.8%, Na 2 O content 0.020%, true specific gravity 3.96g / cm 3 , The α-phase transformation rate is 95.5%, and the primary crystal size is 5 μm.
Embodiment 2
[0018] Electric dust collection powder is used as raw material, first sieved with a 60-mesh sieve to remove large particles of impurities, and then the dust collection powder under the sieve and the additive ammonium fluoride are homogenized in a three-dimensional mixer, and the processing time For 0.5 hours, the amount of ammonium fluoride added is 20‰ of the mass of dust collection powder on a dry basis. Put the homogenized mixed material into a high-aluminum saggar and put it into a 0.2m 3 Calcined in a high-temperature kiln at 1250°C for 4 hours, then taken out from the sagger, crushed, milled in a 50Kg corundum porcelain-lined ball mill for 30 minutes, and passed through a 200-mesh sieve to obtain the under-sieve product Al 2 o 3 The purity is 99.8%, Na 2 O content 0.019%, true specific gravity 3.95g / cm 3 , The α-phase conversion rate is 95%, and the primary crystal size is 4 μm.
Embodiment 3
[0020] The electric dust collection powder is used as the raw material. It is first screened with a 100-mesh sieve to remove the large particles of impurities, and then the dust collection powder under the sieve and the additive aluminum fluoride are homogenized in a three-dimensional mixer. The processing time For 0.5 hours, the amount of ammonium fluoride added is 5‰ of the mass of dust collection powder on a dry basis. Fill the homogenized mixed material with 20% water (mass ratio to dry basis material), and add methyl cellulose binder accounting for 5‰ of dry basis material mass ratio, use a kneading pot to mix well, after mixing Use a small vacuum mud mixer to extrude into lumps, and dry them in an oven at about 260°C. The dried materials are stacked on the silicon carbide and silicon nitride shed board kiln furniture, and placed in a 0.2m 3 Calcined in a high-temperature kiln at 1450°C for 3 hours, then ball-milled with a 50Kg corundum porcelain-lined ball mill for 30 mi...
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