Gene recombination spider's thread protein high polymer organizational engineering porous stent material
A porous scaffold and gene recombination technology, applied in the field of biomedical materials, can solve the problems of collagen variability, insufficient mechanical strength, and strong antigenicity of collagen, and achieve the effects of simple processing technology, improved mechanical properties, and low cost
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Embodiment 1
[0026] 1. Preparation of scaffold preparation solution: Dissolve 2.25g gene recombinant spidroin protein powder in 7.5ml 98% formic acid to obtain 30% (w / v) protein solution, then add 0.45g polyvinyl alcohol, mix well, and obtain gene recombination Scaffold preparation solution of spidroin and polyvinyl alcohol.
[0027] 2. Add porogen: add 1.5g porogen sodium chloride and mix well.
[0028] 3. Mold pouring and heating: Pour the stent preparation solution added with porogen into a cylindrical mold (R=2cm), and put it in an oven at 70°C for 30 minutes.
[0029] 4. Denaturation and immersion in distilled water: soak the stent in ethanol for 15 hours for denaturation and distilled water for 10 hours.
[0030] 5. Freeze-drying: The denatured scaffold is frozen at -70°C for 2 hours to obtain a porous scaffold material.
Embodiment 2
[0032] 1. Preparation of scaffold preparation solution: Dissolve 2.5g of recombinant spidroin protein powder in 10ml98% formic acid to obtain a 25% (w / v) protein solution, add 1.25g of chitosan, and mix well to obtain recombinant spidroin protein containing gene and chitosan scaffold preparation solution.
[0033] 2. Add porogen: Add 2.0g porogen sodium chloride and mix well.
[0034] 3. Molding and heating: Pour the stent preparation solution added with the porogen into a rectangular mold (4cm×3cm×3cm), and put it in an oven at 60°C for 20 minutes.
[0035] 4. Denaturation and immersion in distilled water: soak the stent in ethanol for 10 hours for denaturation, and soak in distilled water for 8 hours.
[0036] 5. Freeze-drying: The denatured scaffold is frozen at -70°C for 4 hours to obtain a porous scaffold material.
Embodiment 3
[0038] 1. Preparation of scaffold preparation solution: get 2g gene recombinant spidroin protein powder and dissolve it in 6ml98% formic acid to obtain 33% (w / v) protein solution, then add 1.0g chitosan and 0.25g polyvinyl alcohol, mix well to obtain Scaffold preparation solution containing gene recombinant spidroin, chitosan and polyvinyl alcohol.
[0039] 2. Add porogen: Add 1.0g porogen sodium chloride and mix well.
[0040] 3. Mold pouring and heating: Pour the stent preparation solution added with the porogen into a rectangular mold (4cm×3cm×3cm), and put it in an oven at 65°C for 30 minutes.
[0041] 4. Denaturation and immersion in distilled water: soak the stent in ethanol for 13 hours and in distilled water for 12 hours.
[0042] 5. Freeze-drying: The denatured scaffold is frozen at -70°C for 3 hours to obtain a porous scaffold material.
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