Polishing liquid for CMP process and polishing method
A grinding method and technology of grinding liquid, which are applied in the fields of electrical components, semiconductor/solid-state device manufacturing, circuits, etc., can solve the problems of easy residue, deviation of grinding characteristics, and damage to the qualified product rate of device wafers.
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manufacture example 1
[0129] 1,000 g of a 0.1% sodium silicate aqueous solution was passed through a 1,000 g cation exchange resin (DIAION SKIB; manufactured by MITSUBISHI CHEMICAL CORPORATION) column, followed by stirring at a temperature of 50°C for 3 hours to obtain a silica sol, which was cooled to room temperature, and then passed through Vacuum dehydration and concentration at 35°C gave a slurry (1) with a silica concentration of 30%.
manufacture example 2
[0131] 360 ml of toluene, 10.8 g of sorbitan monooleate, 120 ml of ion-exchanged water, and 1 ml of acetic acid were charged into a glass reaction vessel with a 1 L stirrer, and vigorously stirred at a temperature of 50° C. for 10 minutes to achieve emulsification. 140 ml of tetraethoxysilane was put into a container at one time, and it was made to react at 50 degreeC temperature for 3 hours, and the silica sol was obtained. After cooling the silica sol to room temperature, it was filtered with filter paper (No. 2). The silica sol on the filter paper was washed with 1 L of methanol and ion-exchanged water in this order, and then dispersed into the ion-exchanged water. In water, a slurry (2) having a silica concentration of 30% was obtained.
manufacture example 3
[0133] Similar to Production Example 1, 1,000 g of a 0.1% sodium silicate aqueous solution was passed through a 1,000 g column of a cation exchange resin (DIAION SKIB; manufactured by MITSUBISHI CHEMICAL CORPORATION), followed by stirring at a temperature of 65°C for 5 hours to obtain a silica sol, which was It was cooled to room temperature, followed by dehydration and concentration in the same manner as in Production Example 1 to obtain a slurry (3) having a silica concentration of 30%.
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