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Catalytic cracking catalyst

A catalytic cracking and catalyst technology, used in catalytic cracking, cracking, petroleum industry and other directions, can solve the problems of heavy oil cracking performance, poor light oil yield and poor coking resistance, and achieve the effect of low coke and high heavy oil conversion capacity

Active Publication Date: 2007-02-21
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to provide a new catalytic cracking catalyst with better performance in view of the shortcomings of existing alumina-containing catalytic cracking catalysts, which have poor heavy oil cracking performance, light oil yield and coke resistance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Alumina hydrate, a precursor of additive-containing alumina suitable for use in the preparation of the catalysts provided by the present invention, and its preparation are described.

[0031] (1), with 1020 grams of pseudo-boehmite (produced by Shandong Aluminum Plant, the alumina content is 60%), 3600 grams of deionized water and 61 grams (by weight, the weight ratio of acid to alumina is 0.1) hydrochloric acid (concentration 36%, produced by Beijing Chemical Plant, analytically pure) mixed under stirring;

[0032] (2), aging the mixed slurry obtained in step (1) at 70° C. for 2 hours;

[0033] (3), the product that step (2) obtains and 110ml phosphoric acid (produced by Beijing Chemical Plant, concentration 85%, analytically pure) and containing magnesium chloride hexahydrate (produced by Beijing Shuanghuan Reagent Factory, analytically pure) aqueous solution 252 grams (wherein hexahydrate Magnesium chloride 132 grams) mixes, obtains the hydrated alumina C-1 gram that ...

Embodiment 2

[0035] Alumina hydrate, a precursor of additive-containing alumina suitable for use in the preparation of the catalysts provided by the present invention, and its preparation are described.

[0036] (1), 1020 grams of pseudo-boehmite (produced by Shanxi Aluminum Plant, with an alumina content of 60%), 3600 grams of deionized water and 61 grams (by weight, and calculating the weight ratio of acid to alumina to be 0.1 ) hydrochloric acid (concentration 36%, produced by Beijing Chemical Plant, analytically pure) mixed under stirring;

[0037] (2), aging the mixed slurry obtained in step (1) at 50° C. for 4 hours;

[0038] (3), the product obtained in step (2) is mixed with diboron trioxide (produced by Beijing Chemical Reagent Company, analytically pure) and water mixed solution 120 grams (wherein 56 grams of boron trioxide);

[0039] (4) Dry the product obtained in step (3) in an oven at 120°C for 6 hours to obtain manganese-containing alumina hydrate C-2 with a pseudo-boehmite...

Embodiment 3

[0041] Alumina hydrate, a precursor of additive-containing alumina suitable for use in the preparation of the catalysts provided by the present invention, and its preparation are described.

[0042] (1), with 1020 grams of pseudo-boehmite (produced by Shandong Aluminum Plant, the alumina content is 60%), 3600 grams of deionized water and 121 grams (by weight, the weight ratio of acid to alumina is 0.2) hydrochloric acid (concentration 36%, produced by Beijing Chemical Plant, analytically pure) mixed under stirring;

[0043] (2), aging the mixed slurry obtained in step (1) at 80° C. for 1 hour;

[0044] (3), the product that step (2) obtains is mixed with magnesium chloride hexahydrate (produced by Beijing Shuanghuan Reagent Factory, analytically pure) aqueous solution 252 grams (wherein 132 grams of magnesium chloride hexahydrate) and silica sol (produced by Beijing Chemical Plant, silicon oxide content 16%,) 226 grams of mixing to obtain silicon and magnesium-containing alum...

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PUM

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Abstract

This invention discloses a cracking catalyst, which comprises an appropriate amount of molecular sieve, and aluminum oxide containing 0.5-40 wt. % of additive. The cracking catalyst is prepared by: (1) mixing pseudoboehmite, water and acid by stirring to obtain mixed slurry; (2) aging the mixed slurry at room temperature to 90 deg.C for 0-24 h; (3) mixing the product of step 2 with the additive; (4) mixing the product of step 3 with the molecular sieve, drying and torrefying. The weight ratio of the acid to aluminum oxide in pseudoboehmite is 0.01-0.5. The cracking catalyst has better heavy oil reforming performance.

Description

technical field [0001] The invention relates to a catalytic cracking catalyst. Background technique [0002] Catalytic cracking is the most widely used and effective method in the existing petroleum processing technology. Among them, by adjusting the composition of the catalytic cracking catalyst, the performance of the catalytic cracking catalyst can be changed, thereby improving the distribution, composition and product properties of the cracked product, and affecting the yield of dry gas and catalyst coke. [0003] US 4283309 discloses a hydrocarbon conversion catalyst comprising (1) a crystalline aluminosilicate zeolite, (2) a catalytically active inorganic oxide colloid, (3) a 2 / g, pore size 90-200 angstroms, the pore volume is at least 0.2cm 2 / g of porous inorganic oxides, the catalyst has a pore volume of at least 0.4 cm with a pore diameter of 90-200 angstroms 2 / g. The porous inorganic oxide is alumina. [0004] The prior art shows tha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G11/04
Inventor 龙军田辉平张蔚琳达志坚张剑秋陈振宇许明德王振波张万虹
Owner CHINA PETROLEUM & CHEM CORP
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