Initial solids mixture for a later organic coating application

Abstract

An initial solids mixture for a later organic coating, such as pigmented coatings, films, priming coats, etc., e.g., for a coil coating method in which an initial solids mixture is applied to a substrate, e.g., broad strip, and this is thereby pre-coated, wherein the initial solids mixture includes, as additive particles, boron carbide and / or silicon carbide and / or compounds of transition elements or lanthanides, the electrical conductivity of which is selected to be in the metallic range (σ>102 1 / Ωcm and σ<107 1 / Ωcm), during the later coating, the additive particles have a continuous physical connection in at least one spatial direction.

Description

FIELD OF THE INVENTION [0001] The present invention relates to an initial solids mixture for a later organic coating application. BACKGROUND INFORMATION [0002] German Published Patent Application No. 197 48 764 describes an initial quantity for producing weldable organic coil coatings. Beside the normal organic components, which later form the matrix of the coating by curing and / or mutual cross-linking, the initial solids mixture has, as additive pigments in quantities between 40 and 70% zinc and / or aluminum and / or graphite and / or molybdenum disulfide and / or soot and / or iron phosphide. The additive pigments are used at least partially for the improvement or implementation, as the case may be, of an electrical conductivity of the initial solid mixture, with which a coil coating method first becomes possible. [0003] In this method, used particularly in the metal working industry, the initial solid mixture is deposited onto a substrate, e.g., broad strip, and cured, whereby the latter ...

AI Technical Summary

Benefits of technology

[0006] The above and other beneficial objects of the present invention are achieved by providing an initial solids mixture as described herein. By the at least partial replacement of the additive pigments by the additive particles according to the present invention, the foregoing disadvantages are at least decreased and may be eliminated.

[0007] Furthermore, the additive particles are toxicologically less risky and also have a more stable, and thus better, mostly even metallic conductivity properties. In the case of some of the additive particles, the simultaneous presence of a non-noble metal, e.g., zinc, for adjusting the corrosion protecting properties of the coating later produced from the initial solids mixture according to the present invention is of advantage, but in the case of others it is dispensable for achieving the required or at least comparable results with respect to electrical conductivity and also with respect to corrosion-protecting effect. Non-noble metal conductors tend to oxide formation, which goes along with the formation of increased contact resistance. Depending on the degree of oxide formation, this leads to a decrease in conductivity and to undefined variations in conductivity, and thus to diminished process safety during welding. It may be advantageous only to use a composition which fulfills the requirements, without adding a non-noble metallic conductor, whereby process safety is improved automatically.

[0013] A negative influence comparable to the oxide formation in the case of the less noble metallic conductors, which leads to high contact resistances and hard to control conductance fluctuations, may not be observed in the case of the electrically conducting compounds. However, to achieve a uniform coating, the additive particles may be worked well into the adhesive agent, that is, an attempt is made at a substantially complete covering of the additive particles with coating resin, the adhesive agent in general having a high-resistance character, which inevitably always goes along only with a generally clearly lower conductivity of the coating in comparison to the conductivity of the additive particles themselves. From this results the desire for as high as possible a conductivity of the additive particles used, since this property has a directly favorable effect on the feasibility of highly conductive, and therefore, for example, weldable coatings. Since electrical resistance increases in a conventional manner with increasing layer thickness, just as in the case of coatings, in the final analysis, by using highly conductive additive particles, greater layer thicknesses are possible with a predefined maximum resistance limiting value. The possibility of increasing the layer thickness may then, for example, have a favorable effect on the corrosion protection achievable with the coating, or on the possibility of reductions in other method steps.

[0014] Correspondingly, it may have a favorable effect if the adhesive agent used does not act insulating because of high resistance, but has an intrinsic electrical conductivity.

Problems solved by technology

However, in the case of an initial solids mixture, the addition of iron phosphide carries with it the danger of phosphane (PH3) development, in the case of hydrolysis and combustion, which does not have an inconsiderable toxicity, and also that iron phosphide has a not inconsiderable cost price.

Furthermore, in the case of environmentally friendly water being used as solvent, the risk of hydrolysis always exists.

Depending on the degree of oxide formation, this leads to a decrease in conductivity and to undefined variations in conductivity, and thus to diminished process safety during welding.

A negative influence comparable to the oxide formation in the case of the less noble metallic conductors, which leads to high contact resistances and hard to control conductance fluctuations, may not be observed in the case of the electrically conducting compounds.

Percolation then occurs earlier, while settling of additive particles at equal particle size may set in with delay.

The conventional coating solutions for coil coating applications probably work only in adhesive agent systems which can hardly be developed aqueously.