Process for Production of a Carboxylic Acid/Diol Mixture Suitable for Use in Polyester Production

a technology of diol mixture and carboxylic acid, which is applied in the field can solve the problems of low corrosion resistance, reduced strength at high temperatures, and limited practical use of wrought magnesium alloy, and achieve excellent formability and corrosion resistance, improve elongation and anisotropy, and reduce stacking fault energy

Inactive Publication Date: 2008-12-11
PRIMOMETAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Benefits of technology

[0007]Accordingly, the present invention has been made keeping in mind the above problems occurring in the prior art, and an object of the present invention is to provide a wrought magnesium alloy which contains the intermetallic compound coherent to a matrix microstructure and which has a second phase composite microstructure, thereby improving elongation and anisotropy to assure excellent formability and corrosion resistance. In order to accomplish the above object, an alloy consisting of three or more elements is used to activate a slip plane. Additionally, in order to activate the slip plane according to increasing in temperature, IIIa and IIIb groups are added together to reduce stacking f

Problems solved by technology

However, since magnesium has a hexagonal close packed (HCP) lattice crystal structure, formability is very low, and thus, the application is limited to a field in which the forming is achieved using a casting process.
Particularly, its practical use is limited due to problems, such as severe oxidation of melts, reduction of strength at high temperatures, and low corrosion resistance.
On the other hand, it is disadvantageous in that since micropores are formed as a casting process due to the addition of Zn, it is difficult to apply the Mg—Zn alloy to a casting process, such as die-casting.
Additionally, it is difficult to desirably improve strength because it is grown as the coarse grain.
However, even though their microstructures have a single-phase solid solution and thus have excellent ductility, they are disadvantageous in that since a strain hardening ability is poor and it is difficult to prevent the grain growth, formability is poor due to anisotropy.
However, the technology is problematic in that the different heating temperatures of the different portions significantly increase the production cost of a press mold.
However, this method is disadvantageous in that the powder is expensive, and in that it is difficult to apply an electroplating process because the powder pressed material has a porous structure.
Magnesium has low corrosion resistance, and thus, it is necessary to treat a surface of magnesium, but undesirably, a gas phase plating process or an electroless plating process requires chemical and treatment costs that are much higher than the electroplating process.
However, products having high porosity and low density, such as die-casting and thixo-molding products, are difficult to apply to a wetplating process bec

Method used

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  • Process for Production of a Carboxylic Acid/Diol Mixture Suitable for Use in Polyester Production

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Embodiment Construction

[0015]The present invention is characterized in that the fine 2nd phase precipitates, which is coherent to matrix microstructure, is formed in the solid solution microstructure having excellent ductility, thereby making grains fine and improving formability. When the grains are made fine, the strength of most materials increases. The reason is that a dislocation moves along the specific slip plane in the course of plastic deformation of the metal in such a way that the dislocation does not directly move from one grain to another grain. But direction of dislocation changes its route because of the grain boundary barrier effect. Accordingly, since the grain boundaries act as barriers in the movement of the dislocation, dislocations are pile up at a grain boundary, thereby preventing deformation. The high temperature stable phase must be capable of being formed in order to make the grain fine, and desired solid solubility must be assured at high temperatures in order to be coherent to ...

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Abstract

Disclosed is a wrought magnesium alloy having excellent strength and extrusion or rolling formability, and a method of producing the same. The wrought magnesium alloy comprises 0.1-1.5 at % group IIIa, 1.0-4.0 at % group IIIb, 0.35 at % or less of one selected from the group consisting of groups IIa, IVa, VIIa, IVb, and a mixture thereof, 1.0 at % or less of group IIb, and a balance of Mg and unavoidable impurities and thus has a second phase composite microstructure. The wrought magnesium alloy of the present invention has high strength, toughness, and formability in addition to the electromagnetic wave shield ability of magnesium. Accordingly, the wrought magnesium alloy is a material useful to portable electronic goods, such as notebook personal computers, mobile phones, digital cameras, camcorders, CD players, PDA, or MP3 players, automotive parts, such as engine room hoods, oil pans, or inner panel of door, or structural parts for airplane.

Description

TECHNICAL FIELD[0001]The present invention relates to a wrought magnesium alloy, which contains a second phase consisting of an intermetallic compound, thereby having excellent strength, formability, and corrosion resistance. More particularly, the present invention pertains to a wrought magnesium alloy, which comprises 0.1-1.5 at % group IIIa. 1.0-4.0 at % group IIIb, 0.35 at % or less of one selected from the group consisting of groups IIa, IVa, VIIa, IVb, and a mixture thereof, 1.0 at % or less group IIb, and a balance of Mg and unavoidable impurities and which thus has a second phase composite microstructure consisting of an intermetallic compound, and a method of producing the same.BACKGROUND ART[0002]Having a density of 1.74-1.95 g / cm3 or so, a relatively low specific gravity that is ⅔ of that of aluminum, excellent specific strength and machinability, magnesium alloys have been developed as light structural materials for airplanes and automobiles. However, since magnesium has...

Claims

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Application Information

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IPC IPC(8): C22C23/02C22C23/04C22C23/06C22F1/06C22C23/00
CPCC22C23/02C22C23/06C22C23/00
Inventor KIM, KANG-HYUNG
Owner PRIMOMETAL CO LTD
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