Care polymers

a technology of care polymers and polymers, which is applied in the direction of disinfection, softening compositions, curling devices, etc., can solve the problems of incompatibility and stability of care polymers, and incompatible with a variety of other consumer product ingredients

Inactive Publication Date: 2011-10-06
THE PROCTER & GAMBLE COMPANY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Unfortunately, such care polymers are incompatible with a variety of other consumer product ingredients, for example, anionic surfactants, and / or are expensive due to the cost of silicone raw materials and the silicone emulsification step that is required to make such silicones useful in products.
Fortunately, Applicants recognized that the source of the incompatibility and stability issues was the charge of current care polymers and such polymers' stiffness as due to such polymers' high glass transition temperature.

Method used

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Examples

Experimental program
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Effect test

examples 1-2

[0237]The following are non-limiting examples of compositions that may be applied to keratinous tissue in accordance with the methods described herein.

Example12PHASE ADC-9040113.53.00DimethiconePolymethylsilsesquioxane27.54.00Cyclomethicone193.00KSG-21032.52.75Alkyl siloxane Polymer of Example 1-1544(mixtures thereof may also be used)Abil EM9740.50KF 601750.40Cetyl Ricinoleate0.25Fragrance0.100.10PHASE BGlycerin7.0010.00Panthenol1.000.5Pentylene Glycol3.00Propylene Glycol1.00Butylene Glycol1.00Tocopherol Acetate0.50Citric AcidSodium CitrateSodium BenzoateNiacinamide1.005.00Methylparaben0.200.25Benzyl Alcohol0.50Propyl Paraben0.10Disodium EDTA0.10Sodium Chloride0.50Titanium Dioxide Dispersion60.5Waterq.s to 100q.s to 100112.5% Dimethicone Crosspolymer in Cyclopentasiloxane. Available from Dow Corning2E.g. Tospearl ® 145A or Tospearl ® 2000. Available from GE Toshiba Silicone325% Dimethicone PEG-10 / 15 Crosspolymer in Dimethicone. Available from Shin-Etsu4Bis-PEG / PPG-14 / 14 Dimethicone....

example 1

[0349]To an addition funnel is added 15.43 g of poly(isobutene)-succinic anhydride (available from BASF Corp. of Florham Pike, N.J. under the trade name Glissopal®-SA,) in 143.7 g of toluene.

[0350]This solution is slowly added to a 1 L round-bottomed flask equipped with a water jacketed condenser and magnetic stir bar containing 48.75 g of aminopropylmethylsiloxane-dimethylsiloxane copolymers of amine equivalent 2000 g / mol (available from Shin-Etsu Silicones, Akron, Ohio under the name X-22-3908A-base) in 439.1 g of toluene at 90° C. This gives a 1:1 anhydride:amine stoichiometry. After addition, the reaction is cooled and stirred at room temperature. A 250.24 g sample is removed from the flask, precipitated into methanol, extracted with isopropanol, and dried in vacuum at 50° C. Polyamic acid copolymer (13.92 g) is obtained as a yellow material with 20% (by weight) poly(isobutene) as determined by H-1 NMR.

example 2

[0351]To an addition funnel is added 15.43 g of poly(isobutene)-succinic anhydride of number average molecular weight 1000 Da (available from BASF Corp. of Florham Pike, N.J. under the trade name Glissopal®-SA) in 143.7 g of toluene. This solution is slowly added to a 1 L round-bottomed flask equipped with a water jacketed condenser and magnetic stir bar containing 48.75 g of aminopropylmethylsiloxane-dimethylsiloxane copolymers of amine equivalent 2000 g / mol (available from Shin-Etsu Silicones, Akron, Ohio under the name X-22-3908A-base) in 439.1 g of toluene at 90° C. This gives a 1:1 anhydride:amine stoichiometry. After addition, the reaction is cooled and stirred at room temperature. After removing a 250.24 g sample, the reaction is brought to reflux to remove toluene / water. The reaction is then cooled, precipitated into methanol, extracted with isopropanol, and dried in vacuum at 50° C. Polyimide copolymer (19.84 g) is obtained as a yellow material with 22% (by weight) poly(iso...

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Abstract

The present application relates to care agents, for example care polymers, and compositions such as consumer products comprising such care agents, as well as processes for making and using such care agents and such compositions. The performance of the care polymers that Applicants teach, can be further increased by following the emulsification teaching of the present specification and/or combining such care polymers with silicone materials.

Description

CROSS-REFERENCES TO RELATED APPLICATIONS[0001]This application claims priority under 35 U.S.C. §119(e) to U.S. Provisional Application Ser. No. 61 / 320,133 filed Apr. 1, 2010; U.S. Provisional Application Ser. No. 61 / 320,141 filed Apr. 1, 2010; U.S. Provisional Application Ser. No. 61 / 366,270 filed Jul. 21, 2010; U.S. Provisional Application Ser. No. 61 / 383,770 filed Sep. 17, 2010; and U.S. Provisional Application Ser. No. 61 / 413,062 filed Nov. 12, 2010.FIELD OF INVENTION[0002]The present application relates to care agents, for example care polymers, and compositions such as consumer products comprising such care agents, as well as processes for making and using such care agents and such compositions.BACKGROUND OF THE INVENTION[0003]Care polymers, including silicones, are used in premium consumer products to provide benefits such as softness, hand, anti-wrinkle, hair conditioning / frizz control, color protection, etc. Unfortunately, such care polymers are incompatible with a variety o...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): A61K8/898C08F299/08C11D3/60C07F7/10C11D17/00C11D3/37A61Q5/02A61Q5/12A61Q19/10A61Q19/00D06L1/16B08B3/00
CPCC08G77/388C08K5/00C08L83/08C08L83/10C08L83/12C11D3/3738C11D3/373C11D3/3742D06M13/02D06M15/643C11D3/18C11D3/001C08G77/46C11D3/37A61K8/898A61K2800/10A61K2800/54A61K2800/74A61Q5/02A61Q15/00A61Q19/00A61Q19/10C08G77/26C08G77/30C08G77/38C08G77/452C11D3/0015C11D11/0017C11D17/0017
Inventor PANANDIKER, RAJAN KESHAVZANNONI, LUKE ANDREWSMITH, STEVEN DARYLMCCHAIN, ROBERT JOSEPHMENKHAUS, JULIE ANN
Owner THE PROCTER & GAMBLE COMPANY
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