The invention belongs to the technical field of soil pollution remediation. The invention relates to a method for removing organochlorine compounds in soil through cooperation of chelating agent enhanced advanced oxidation and electric remediation. The method comprises the following steps: 1) transferring the contaminated soil to an electric remediation device, adding an oxidant and glutamic acidN, N-diacetic acid into the soil, and meanwhile, arranging nano zero-valent iron near an anode of the electric remediation device; and 2) adjusting the pH value of an electrolyte, and starting the electric remediation device to remove the organochlorine compounds in the soil, wherein the oxidant is at least one of persulfate, hydrogen peroxide, permanganate and hypochlorite. According to the method, the organochlorine pollutants in the soil are synergistically removed based on a combined treatment mode of electric remediation, the nanoscale zero-valent iron, the oxidant and the glutamic acid N, N-diacetic acid, the removal rate of the organochlorine pollutants in the soil can be greatly increased, and meanwhile in-situ removal of the organochlorine pollutants can be achieved.