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Biomass castoff supercritical water fluid bed partial oxidation hydrogen-preparation device and method

A technology for biomass waste and hydrogen production device, which is applied in the fields of hydrogen production, chemical industry, bulk chemical production, etc. Low conversion efficiency and other problems, to achieve the effect of being conducive to centralized treatment and resource utilization, realizing pollution control and hydrogen production, and improving heat exchange efficiency

Active Publication Date: 2007-10-24
陕西中核交大超洁能源技术有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] (1) When the reaction is incomplete, or the flow, transfer, and reaction conditions are not coupled, and the design is unreasonable, the tube flow reactor used in the biomass supercritical water gasification process is prone to wall slagging and clogging, resulting in biomass waste failure of continuous gasification;
[0007] (2) The gasification reaction needs to absorb a large amount of heat, and it is difficult to achieve the rapid temperature rise conditions required for complete biomass gasification by using external heating methods, and at the same time, the energy conversion efficiency of the entire system is low;

Method used

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Embodiment Construction

[0034] The gasification raw material used in the present invention may be biomass model compounds (glucose, cellulose, lignin, etc.), primary biomass waste (crop straw, various wastes, etc.) or coal. The following takes agricultural biomass straw as an example for illustration.

[0035] With reference to accompanying drawing 1, the first, the second feeder (2,3), the second, the 3rd high-pressure plunger pump (16,17), stock tank 1 communicate with each other by pipeline and valve in the device of the present invention, Composition charging system; Reactor 4 is communicated with the outlet of preheater 6, the first, the second feeder (2,3) outlet respectively; Heat exchanger 5 is respectively connected with reactor 4 outlet, first high pressure plunger pump 15 outlets , the inlet of the preheater 6 and the inlet of the cooler 7 are communicated; the outlet of the cooler 7 is communicated with the inlet of the first back pressure valve 8; the high pressure separator 11 is respec...

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Abstract

The invention discloses an oxidizing and gasifying hydrogen-making device and method of hypercritical water fluid-bed part of the biological waste, which is characterized by the following: adopting hypercritical water fluid-bed reactor to prevent slagging and blocking problem in the pipe flow reactor; using high-pressure separator to generate high-pressure water to adsorb carbon dioxide in the gas product; realizing the separation of the hydrogen from the carbon dioxide; making the separated high-density carbon dioxide concentrate to be disposed and do resoursing usage conveniently; compacting the device structure; simplifying and conveniencing the operation; improving the gasifying rate of the biological waste with less pollution in the liquid product; realizing the oxidizing and gasifying fusion in the reactor; improving the biological mass transmitting rate and system energy transmitting efficiency; transmitting the biological waste into high-quality hydrogen through the method; reducing the environmental pollution; realizing the dual goals to harness pollution and make hydrogen.

Description

technical field [0001] The invention belongs to the field of energy-based clean utilization of renewable resources and waste, and in particular relates to a hydrogen production device and method for supercritical water fluidized bed partial oxidation gasification of biomass waste. technical background [0002] With the gradual consumption and depletion of fossil energy, it is imminent to find new alternative energy. Biomass, as an abundant resource on the earth, contributes to environmental CO2 during its utilization. 2 The net emission is "zero", therefore, the conversion and utilization of biomass has attracted widespread attention. [0003] Thermochemical gasification is considered to be the most commercially promising biomass utilization technology. However, the traditional biomass thermochemical gasification technology needs to dry the biomass, which consumes a lot of energy. Supercritical water gasification hydrogen production technology can ...

Claims

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Application Information

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IPC IPC(8): C01B3/02B09B3/00
CPCY02P20/10Y02P20/54
Inventor 郭烈锦吕友军张西民
Owner 陕西中核交大超洁能源技术有限公司
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