Catalyst continuous reproducible low octane rating gasoline modifying method
A technology with low octane number and catalyst, which is applied in the petroleum industry, naphtha treatment, etc., can solve problems such as the decrease of the yield of modified gasoline, the reduction of the processing capacity of the device, and the complicated operation of the device. The effect of gas production rate reduction
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preparation example Construction
[0053] The preparation method of the modified catalyst used in the test is as follows:
[0054] (1) Prepare the carrier: get 130 grams of HZSM-5 zeolite powder (produced by Shanghai Huaheng Catalyst Factory) with a silicon-aluminum ratio of 56, 70 grams of α-alumina monohydrate powder (produced by German Condea Company), mix well, add 2 A solution prepared by milliliter of 1:1 nitric acid and an appropriate amount of water, after the raw materials are made into a sol, the ball is formed by dropping in a hot oil bath or an oil ammonia bath, then dried at 110°C for 12 hours, and calcined at 570°C for 4 hours. The particle size range of the carrier spherical particles is 1-3mm.
[0055] (2) Introduce active components: take 100 grams of the above-mentioned carrier, use 100 milliliters containing 1.35 grams of chlorinated mixed rare earth (produced by Inner Mongolia Baotou Rare Earth Industry Company, wherein lanthanum oxide is 31 weight%, cerium oxide is 51 weight%, and praseodym...
Embodiment
[0059] The reaction part of this embodiment adopts figure 1 As shown in the process flow, the regeneration of the catalyst adopts figure 2 Shown in the way of continuous regeneration. The following is a detailed description of the properties and composition of raw materials, the main reaction conditions, the properties and composition of products, and product distribution:
[0060] 1. The nature and composition of raw materials
[0061] 1) Properties and composition of low-octane gasoline raw materials
[0062] Density (25℃), kg / m 3 713
[0063] Octane number, RON (MON) 54.0 (54.8)
[0064] Impurity content
[0065] Sulfur content, mg / L 157
[0066] Nitrogen content, ppm 1.4
[0067] Arsenic content, ppb <2
[0068] quality composition
[0069] Alkanes, %58.56
[0070] Naphthenes, % 36.54
[0071] Aromatics, % 4.90
[0072] 2), the composition of light hydrocarbon feedstock
[0073] C3 alkanes, mass% 0.07
[0074] C3 olefins, mass% 0.66
[0075] C4 alkanes, ma...
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