Catalyst continuous reproducible low octane rating gasoline modifying method

A technology with low octane number and catalyst, which is applied in the petroleum industry, naphtha treatment, etc., can solve problems such as the decrease of the yield of modified gasoline, the reduction of the processing capacity of the device, and the complicated operation of the device. The effect of gas production rate reduction

Active Publication Date: 2008-06-04
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
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AI Technical Summary

Problems solved by technology

[0011] The above-mentioned prior art uses a fixed-bed reactor. As the reaction continues, the surface of the catalyst will be gradually covered by coke, resulting in a decrease in the activity and selectivity of the catalyst. In order to ensure product quality, it is necessary to continuously adjust the operating parameters as the reaction progresses. , the yield of modified gasoline will further decrease in the later stage of the reaction
When

Method used

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  • Catalyst continuous reproducible low octane rating gasoline modifying method
  • Catalyst continuous reproducible low octane rating gasoline modifying method
  • Catalyst continuous reproducible low octane rating gasoline modifying method

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0053] The preparation method of the modified catalyst used in the test is as follows:

[0054] (1) Prepare the carrier: get 130 grams of HZSM-5 zeolite powder (produced by Shanghai Huaheng Catalyst Factory) with a silicon-aluminum ratio of 56, 70 grams of α-alumina monohydrate powder (produced by German Condea Company), mix well, add 2 A solution prepared by milliliter of 1:1 nitric acid and an appropriate amount of water, after the raw materials are made into a sol, the ball is formed by dropping in a hot oil bath or an oil ammonia bath, then dried at 110°C for 12 hours, and calcined at 570°C for 4 hours. The particle size range of the carrier spherical particles is 1-3mm.

[0055] (2) Introduce active components: take 100 grams of the above-mentioned carrier, use 100 milliliters containing 1.35 grams of chlorinated mixed rare earth (produced by Inner Mongolia Baotou Rare Earth Industry Company, wherein lanthanum oxide is 31 weight%, cerium oxide is 51 weight%, and praseodym...

Embodiment

[0059] The reaction part of this embodiment adopts figure 1 As shown in the process flow, the regeneration of the catalyst adopts figure 2 Shown in the way of continuous regeneration. The following is a detailed description of the properties and composition of raw materials, the main reaction conditions, the properties and composition of products, and product distribution:

[0060] 1. The nature and composition of raw materials

[0061] 1) Properties and composition of low-octane gasoline raw materials

[0062] Density (25℃), kg / m 3 713

[0063] Octane number, RON (MON) 54.0 (54.8)

[0064] Impurity content

[0065] Sulfur content, mg / L 157

[0066] Nitrogen content, ppm 1.4

[0067] Arsenic content, ppb <2

[0068] quality composition

[0069] Alkanes, %58.56

[0070] Naphthenes, % 36.54

[0071] Aromatics, % 4.90

[0072] 2), the composition of light hydrocarbon feedstock

[0073] C3 alkanes, mass% 0.07

[0074] C3 olefins, mass% 0.66

[0075] C4 alkanes, ma...

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Abstract

The invention discloses a catalyst continuous regeneration low-octane gasoline upgrading method. The low-octane gasoline raw material and the light hydrocarbon raw material are mixed, then enter into a gasoline upgrading reactor, contact and react with the upgrading catalyst in the reactor, the reactant is separated to obtain dry gas, liquefied gas and upgrading gasoline products; the deactivated catalyst in the reaction system is lifted and conveyed to a regeneration system, contacts with the regeneration gas to be burned in a regenerator, the burned regeneration catalyst is lifted and conveyed to the reaction system. The method greatly improves the octane value of the gasoline, and the olefin content in the upgrading gasoline is very low; the continuous regeneration of the deactivated catalyst ensures that the activity and the selectivity of the catalyst in the reactor are both maintained at higher levels; compared with the conventional reactor switching regeneration way, the dry gas yield of the upgrading reaction is obviously decreased, the upgrading gasoline and the liquefied gas as the target products are obviously improved.

Description

technical field [0001] The invention belongs to a reforming conversion process of hydrocarbon oil in the absence of hydrogen. Background technique [0002] More than 80% of gasoline in my country is FCC gasoline. The main feature of FCC gasoline is its high olefin content, which results in high olefin content in gasoline products. With the improvement of people's environmental awareness and the increasing environmental protection regulations Strict, while the new gasoline standard strictly restricts the sulfur content in gasoline, it also puts forward higher requirements for the olefin content, which makes some refineries with relatively simple processing methods only find a suitable method to reduce the olefin content in gasoline. In order to meet the requirements of the new gasoline standard. The olefin content in gasoline can usually be reduced from the following two aspects: one is to reduce the olefin content in catalyst-cracked gasoline; the other is to increase the out...

Claims

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Application Information

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IPC IPC(8): C10G59/02
Inventor 赵志海师峰马爱增
Owner CHINA PETROLEUM & CHEM CORP
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