Environment protection type multifunction architecture adhesion agent and method for producing the same

A multi-functional, environmentally friendly technology, applied in the direction of unsaturated alcohol copolymer adhesives, monocarboxylic acid ester copolymer adhesives, adhesive types, etc., can solve the problem of poor water resistance, cold resistance and humidity resistance, Small particle size of polymer colloidal particles, shortened effective storage period, etc., to achieve the effect of not easy to mold, stable performance and fast drying speed

Active Publication Date: 2008-07-16
YANJIAN GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the development of the economy, synthetic adhesives are increasingly used in various fields. Among the currently used adhesives, many are solvent-based trialdehyde adhesives. Due to the existence of free aldehydes, they have a great impact on environmental pollution. Long-term exposure will also cause the risk of malignant tumors; and the particle size of the polymer colloidal particles prepared by traditional emulsion polymerization is generally small, and the particle size distribution is wide, which cannot meet special needs, such as the polyvinyl acetate currently used Although the emulsion has the characteristics of low price, convenient production, and non-toxicity, it has more disadvantages: when the solid content is high, the viscosity is high and it is difficult to apply; when the solid content is low, the emulsion is unstable, easy to separate, and the effective storage period Shortening; water resistance, cold resistance and humidity resistance are poor, and mechanical stability is not good; under hot and humid conditions, its bond strength is greatly reduced; film-forming creep resistance is poor

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] In the reactor, agitator, reflux condenser, dropping funnel and thermometer are installed, and various raw materials are accurately measured according to the formula. At first, in the reactor, add 4.5% of total weight (weight is 45g) Polyvinyl alcohol and account for the water of 50.2% (weight is 502g in the present embodiment) of total weight, start to stir, and make temperature rise to 80 ℃, polyvinyl alcohol is dissolved completely; Cool down to 70 ℃, will account for 15% of total weight ( Weight is 150g) vinyl acetate-ethylene copolymer emulsion in the present embodiment and the dibutyl phthalate that accounts for 0.5% (weight is 5g in the present embodiment) of total weight drops in the reactor successively, when temperature rises to 70 ℃ At this time, start to add 28% of the total weight (in this embodiment, the weight is 280g) of vinyl acetate and account for 1% of the total weight (in this embodiment, the weight is 10g) of acrylic acid monomers, and add 0.3% of t...

Embodiment 2

[0023] Install agitator, reflux condenser, dropping funnel and thermometer in the reactor, accurately measure various raw materials according to the formula, at first in the reactor, add 4% of the total weight (weight is 40g in this embodiment) Polyvinyl alcohol and account for the water of 59.2% (weight is 592g in the present embodiment) of total weight, start to stir, and make temperature rise to 78 ℃, polyvinyl alcohol is dissolved completely; Cool down to 68 ℃, will account for 10% of total weight ( In the present embodiment, the vinyl acetate-ethylene copolymer emulsion whose weight is 100g) and the dibutyl phthalate that accounts for 0.4% of the total weight (the weight is 4g in the present embodiment) are dropped into the reactor successively, and when the temperature rises to 68°C Begin to add the vinyl acetate that accounts for 25% (the weight is 250g in the present embodiment) of total weight and the acrylic acid monomer that accounts for 0.5% (the weight is 5g in the...

Embodiment 3

[0025] In the reactor, agitator, reflux condenser, dropping funnel and thermometer are installed, and various raw materials are accurately measured according to the formula. Polyvinyl alcohol and account for the water of 42% (weight is 420g in the present embodiment) of total weight, start to stir, and make temperature rise to 82 ℃, polyvinyl alcohol is completely dissolved; Cool down to 72 ℃, will account for 19.62% of total weight ( Weight is 196.2g) vinyl acetate-ethylene copolymer emulsion in the present embodiment and the dibutyl phthalate that accounts for 0.6% (weight is 6g in the present embodiment) of total weight drops into reactor successively, when temperature rises to 72 At ℃, start to add vinyl acetate accounting for 30% of the total weight (in the present embodiment, the weight is 300g) and account for 1.5% of the total weight (in the present embodiment, the weight is 15g) of acrylic acid monomer, and add 0.28% of the total weight 35% (weight is 0.98g in the pre...

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PUM

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Abstract

The invention discloses an environment friendly and multi-functional building adhesive and the preparation method thereof, and is characterized in that: 4 to 5 percent of polyvinyl alcohol and 42 to 59.2 percent of water are taken by weight percentage, stired and heated to 80 plus or minus 2 DEG C until the polyvinyl alcohol is dissolved completely, then cooled to 70 plus or minus 2 DEG C, added with 10 to 20 percent of vinyl acetate-ethylene co-polymer emulsion and 0.4 to 0.6 percent of emulsifying agent; then the mixture is heated to 70 plus or minus 2 DEG C, added with 25 to 30 percent of winyl acetic ester and 0.5 to 1.5 percent of acrylic monomer, and further added with part of 0.25 to 0.3 percent of evocating agent which accounts for 35 to 45 percent of total amount of the evocating agent to carry out emulsion polymerization; the temperature is maintained at 70 plus or minus 2 DEG C, then the residual evocating agent which accounts for 55 to 65 percent of total amount thereof is added; the temperature is kept for 1-2 hours until no nomoner reflows, then the temperature raises to 90 plus or minus 2 DEG C, kept for 30 to 40 minutes, and finally reduced to 50 plus or minus 2 DEG C; the PH value is adjusted and the product is finished after stirring evenly. The invention has the advantages of steady performance, low viscosity coefficient, convenient operation, good stickiness property, good elasticity property, excellent film forming and water-proof property, high drying speed, uneasy going moldy and high biological degradability.

Description

Technical field: [0001] The invention relates to an environment-friendly multifunctional construction adhesive and a preparation method, belonging to the technical field of adhesives. Background technique: [0002] With the development of the economy, synthetic adhesives are increasingly used in various fields. Among the currently used adhesives, many are solvent-based trialdehyde adhesives. Due to the existence of free aldehydes, they have a great impact on environmental pollution. Long-term exposure will also cause the risk of malignant tumors; and the particle size of the polymer colloidal particles prepared by traditional emulsion polymerization is generally small, and the particle size distribution is wide, which cannot meet special needs, such as the polyvinyl acetate currently used Although the emulsion has the characteristics of low price, convenient production, and non-toxicity, it has more disadvantages: when the solid content is high, the viscosity is high and it ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J131/04C09J129/04
Inventor 唐波孙国春文爱武汪俊波李琦
Owner YANJIAN GRP CO LTD
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