Lacunaris metal carrier and manufacturing method thereof

A porous metal and carrier technology, applied in metal layered products, chemical instruments and methods, metal material coating processes, etc., can solve the problems of limiting catalyst use efficiency, poor catalyst adhesion, limited chromium and aluminum content, etc. Improve the utilization rate and effect, good adhesion, and simplify the effect of the preparation process

Active Publication Date: 2008-07-30
先进储能材料国家工程研究中心有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, metal carriers at home and abroad are generally formed by metal foil rolling, coiling, brazing, assembly and other processes, which is costly. At the same time, in order to ensure the processing performance of the foil, the content of chromium and aluminum is limited, sacrificing its high temperature oxidation resistance.
The metal carrier formed by rolling has straight channels and smooth surface, resulting in poor catalyst adhesion and small specific surface area per unit volume, thus limiting the use efficiency of the catalyst

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] The porous metal carrier of this embodiment has a continuous microporous structure formed by interconnecting polyhedral cells, the base metal layer is a nickel-iron alloy, and the metal weight is 1500g / m 2 ; On the base metal layer is a FeCrAl functional metal coating, the thickness of the coating is 30 μm, the chromium in the coating accounts for 12% of the total weight, and the aluminum accounts for 2%.

[0015] Preparation method: Firstly, the combined process of electroless nickel plating and electroplating nickel-iron alloy is used to coat the base metal layer on the polyester sponge substrate, and the metal weight is 1500g / m 2 Adopt flame thermal spraying process to spray FeCrAl functional metal coating on base metal layer again, select the FeCrAl wire that diameter is 1.6mm for use during thermal spraying, chromium accounts for 12% of total weight in the wire, and aluminum accounts for 2% of total weight , the balance is iron, the wire feeding speed is 2.0m / min, ...

Embodiment 2

[0018] The porous metal alloy material of the present embodiment, the base metal layer is a nickel-copper-iron alloy, and the metal weight is 500g / m 2 ; On the base metal layer is a NiCrAl functional metal coating, the thickness of the coating is 100 μm, the chromium accounts for 20% of the total weight, and the aluminum accounts for 4%.

[0019] Preparation method: Firstly, the combined process of electroless copper plating and electroplating nickel-iron alloy is used to plate the base metal alloy layer on the polyether sponge substrate, and the metal content is 500g / m 2 Then incinerate and remove the sponge substrate; then adopt the arc thermal spraying process to spray NiCrAl functional metal coating on the base metal layer, and the thermal spraying selects the NiCrAl wire with a diameter of 1.8mm, and the chromium accounts for 20% of the total weight in the wire, and the aluminum Accounting for 4% of the total weight, the balance is nickel, the wire feeding speed is 1.5m / m...

Embodiment 3

[0022] The porous metal carrier of the present embodiment, the base metal layer is a nickel-copper-iron alloy, and the metal weight is 150g / m 2 ; On the base metal layer is a NiCrAl-Y functional metal coating, the thickness of the coating is 250 μm, chromium accounts for 15% of the total weight in the coating, aluminum accounts for 5%, and yttrium accounts for 1%.

[0023] Preparation method: Firstly, the combined process of electroless nickel plating and electroplating nickel is used to plate the base metal nickel layer on the cotton substrate, and the metal weight is 150g / m 2 Then incinerate and remove the cotton cloth base material; then adopt the arc thermal spraying process to spray NiCrAl-Y functional metal coating on the base metal layer, and use the NiCrAl-Y wire with a diameter of 2mm during thermal spraying, and the chromium in the wire material accounts for the total weight 15%, aluminum accounts for 5% of the total weight, yttrium accounts for 1% of the total weigh...

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Abstract

The invention discloses a porous metal carrier and a preparation method thereof. The porous metal carrier has a continuous micro-porous structure formed through mutual connection of polyhedron cabinets; a first layer is a substrate metal layer which comprises one or a plurality of the compositions: nickel, iron or copper; metal quantity of the substrate metal layer is more than or equal to 100g / m<2>; a function metal coating of MCrAl or MCrAlR is arranged on the substrate metal layer and M refers to Fe, Ni and Co or alloy of Fe, Ni and Co and R is rare earth element. The preparation method includes the following steps: first, metallization pretreatment is carried out for nonmetal porous substrate to form the substrate metal layer; second, the function metal layer with chromium and aluminum are sprayed on the substrate metal layer by adopting a thermal spraying process; at last, flame remelt and induction remelt are carried out for the function coating. The material provided by the invention has high porosity, large surface area, high strength, favorable flow disturbance, excellent high temperature and oxidization resistance, simple preparation method and process and low cost.

Description

technical field [0001] The invention relates to an alloy material and a preparation method thereof, in particular to a porous metal carrier and a preparation method thereof. Background technique [0002] In motor vehicle exhaust purifiers, ceramic honeycomb materials are currently mostly used as exhaust gas purification catalyst carriers in China, while metal honeycomb materials are commonly used abroad. Compared with the ceramic carrier, the metal carrier has the following advantages: 1) small heat capacity, high thermal conductivity, rapid ignition of exhaust gas; 2) excellent mechanical strength, good shock resistance, long service life; 3) high porosity, exhaust Low gas back pressure is conducive to improving engine performance and good economy; 4) Various structures and high specific surface area can effectively improve catalytic activity and exhaust gas purification rate. As the country's requirements for motor vehicle exhaust emission standards become more and more s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B15/01B32B15/02B32B33/00C22C1/08C23C4/06C23C4/073
Inventor 陶维正贺持缓熊飞蒋素斌
Owner 先进储能材料国家工程研究中心有限责任公司
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